0000000001030169
AUTHOR
Ingrid Sanz
Supramolecular assemblies and photophysical properties of ionic homo- and heteronuclear metallophilic complexes
Abstract The synthesis of two dinuclear ionic complexes with chemical formula [Au(PR 3 ) 2 ][Au(C ≡ CC 5 H 4 N-4) 2 ] that contain the water soluble phosphines, PR 3 , PTA (1, 3,5-triaza-7-phosphaadamantane, 1 ) and DAPTA (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, 2 ) is herein described. The differences on their intermolecular reorganization have been analyzed and compared with the previously reported for the neutral complexes [Au(PR 3 )(C ≡ CC 5 H 4 N-4)]. It has been evidenced that the reorganization of the ligands giving rise to the dinuclear ionic complexes produces a complete change in the properties giving rise to Au⋯Au intermolecular assemblies. These aurophilic conta…
CCDC 1914062: Experimental Crystal Structure Determination
Related Article: Noora Svahn, Ingrid Sanz, Kari Rissanen, Laura Rodríguez|2019|J.Organomet.Chem.|897|170|doi:10.1016/j.jorganchem.2019.07.001