Author: Liang Tongling

0000000001043761

AUTHOR

Liang Tongling

2-(N,N-Diethylaminomethyl)-6,7-trihydroquinolinyl-8-ylideneamine-Ni(ii) chlorides: application in ethylene dimerization and trimerization

A series of Ni(II) complexes with the general formula [2-((NEt2)Me)-8-{N(Ar)}C9H8N]NiCl2, where Ar = 2,6-Me2C6H3 in Ni1, 2,6-Et2C6H3 in Ni2, 2,6-i-Pr2C6H3 in Ni3, 2,4,6-Me3C6H2 in Ni4, 2,6-Et2-4-MeC6H2 in Ni5, and 2,4,6-t-Bu3C6H2 in Ni6, has been prepared using a one-pot reaction of 2-(N,N-diethylaminomethyl)-6,7-dihydroquinolin-8(5H)-one with the corresponding aniline and nickel dichloride hexahydrate. The resultant complexes were characterized using elemental analysis and FT-IR spectroscopy, while the mononuclear Ni1 and Ni3 were also the subject of single-crystal X-ray diffraction study. On activation with MMAO, the complexes Ni1–Ni6 displayed good activity in ethylene oligomerization, f…

research product

CCDC 2005997: Experimental Crystal Structure Determination

Related Article: Jiaxin Li, Yanping Ma, Xinquan Hu, Zygmunt Flisak, Liang Tongling, Wen-Hua Sun|2020|New J.Chem.|44|17047|doi:10.1039/D0NJ04003G

research product

CCDC 2005998: Experimental Crystal Structure Determination

Related Article: Jiaxin Li, Yanping Ma, Xinquan Hu, Zygmunt Flisak, Liang Tongling, Wen-Hua Sun|2020|New J.Chem.|44|17047|doi:10.1039/D0NJ04003G

research product

PEPhysical Sciences and Engineering
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