Author: Kay Ansorg

0000000001046307

AUTHOR

Kay Ansorg

showing 9 related works from this author

Vinyl sulfone building blocks in covalently reversible reactions with thiols

2015

In the present study we use quantum-chemical calculations to investigate how the reactivity of vinyl sulfone-based compounds can be modified from an irreversible to a reversible reaction with thiols. Based on the predictions from theory, an array of nine different vinyl sulfones with systematically varying substitution pattern was synthesized and their crystal structures were determined. Subsequent Hirshfeld surface analyses employing the principle of electrostatic complementarity aid the understanding of the crystal packing of the synthesized compounds. Reactivity studies against the nucleophile 2-phenylethanethiol mirror the properties predicted by the quantum-chemical computations in sol…

010405 organic chemistryChemistrytechnology industry and agricultureGeneral ChemistryCrystal structureVinyl sulfone010402 general chemistry01 natural sciencesCombinatorial chemistryCatalysisReversible reaction0104 chemical sciencesCrystalNucleophileCovalent bondPolymer chemistryMaterials ChemistryReactivity (chemistry)New Journal of Chemistry

researchProduct

CCDC 897063: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

Space GroupCrystallography3-anilino-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 897056: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

Space GroupCrystallographyCrystal System3-(ethylamino)-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 897057: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

3-((4-methylphenyl)amino)-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 897062: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

3-((4-iodophenyl)amino)-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 897061: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

Space GroupCrystallographyCrystal SystemCrystal Structure3-((4-methoxyphenyl)amino)-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 897060: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

Space GroupCrystallography3-(methylsulfanyl)-3-((4-nitrophenyl)amino)-2-(phenylsulfonyl)acrylonitrile hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 897059: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters3-((4-fluorophenyl)amino)-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileExperimental 3D Coordinates

researchProduct

CCDC 897058: Experimental Crystal Structure Determination

2015

Related Article: Thomas H. Schneider, Max Rieger, Kay Ansorg, Alexandre N. Sobolev, Tanja Schirmeister, Bernd Engels, Simon Grabowsky|2015|New J.Chem.|39|5841|doi:10.1039/C5NJ00368G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters3-(benzylamino)-3-(methylsulfanyl)-2-(phenylsulfonyl)acrylonitrileExperimental 3D Coordinates

researchProduct

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