0000000001047109

AUTHOR

Tatiyana V. Serebryanskaya

showing 10 related works from this author

Identification and H(D)-bond energies of C-H(D)Cl interactions in chloride-haloalkane clusters: a combined X-ray crystallographic, spectroscopic, and…

2016

The cationic (1,3,5-triazapentadiene)Pt(II) complex [Pt{NH[double bond, length as m-dash]C(N(CH2)5)N(Ph)C(NH2)[double bond, length as m-dash]NPh}2]Cl2 ([]Cl2) was crystallized from four haloalkane solvents giving [][Cl2(CDCl3)4], [][Cl2(CHBr3)4], [][Cl2(CH2Cl2)2], and [][Cl2(C2H4Cl2)2] solvates that were studied by X-ray diffraction. In the crystal structures of [][Cl2(CDCl3)4] and [][Cl2(CHBr3)4], the Cl(-) ion interacts with two haloform molecules via C-DCl(-) and C-HCl(-) contacts, thus forming the negatively charged isostructural clusters [Cl(CDCl3)2](-) and [Cl(CHBr3)2](-). In the structures of [][Cl2(CH2Cl2)2] and [][Cl2(C2H4Cl2)2], cations [](2+) are linked to a 3D-network by a syste…

010405 organic chemistryChemistryHydrogen bondGeneral Physics and Astronomychloride-haloalkane clustersCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesIonCrystalCrystallographyhydrogen bondsCluster (physics)MoleculePhysical and Theoretical ChemistryBond energyIsostructuralta116Physical chemistry chemical physics : PCCP
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Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies

2018

Well-defined diazotates are scarce. Here we report the synthesis of unprecedented homoleptic palladium(II) diazotate complexes. The palladium(II)-mediated nitrosylation of 2-aminopyridines with NaNO2 results in the formation of metal-stabilized diazotates, which were found to be cytotoxic to human ovarian cancer cells.

Models Molecularinorganic chemicalsCell SurvivalPyridinesPyrazine Diazohydroxidechemistry.chemical_elementAntineoplastic AgentsorganometalliyhdisteetCrystallography X-Ray010402 general chemistry01 natural sciencesInorganic ChemistryStructure-Activity Relationshipchemistry.chemical_compoundCoordination ComplexesCell Line Tumororganometallic compoundsPyridineHumansCytotoxic T cellsytotoksisuusPhysical and Theoretical ChemistryHomolepticCytotoxicityta116Cell ProliferationDose-Response Relationship DrugMolecular Structure010405 organic chemistryNitrosylationCombinatorial chemistry0104 chemical sciencesHEK293 Cellssyöpäsolutchemistrycancer cellsOvarian cancer cellscytotoxicityDrug Screening Assays AntitumorAzo CompoundsPalladiumPalladiumInorganic Chemistry
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CCDC 1577120: Experimental Crystal Structure Determination

2018

Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis{methyl 6-[(nitroso)amino]pyridine-3-carboxylatato}-palladium(ii)Experimental 3D Coordinates
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CCDC 1577119: Experimental Crystal Structure Determination

2018

Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072

Space GroupCrystallographybis[5-methyl-N-(nitroso)pyridin-2-aminato]-palladium(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1401548: Experimental Crystal Structure Determination

2016

Related Article: Tatiyana V. Serebryanskaya, Alexander S. Novikov, Pavel V. Gushchin, Matti Haukka, Ruslan E. Asfin, Peter M. Tolstoy, Vadim Yu. Kukushkin|2016|Phys.Chem.Chem.Phys.(PCCP)|18|14104|doi:10.1039/C6CP00861E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(N-Phenyl-N-(N'-phenylcarbamimidoyl)piperidine-1-carboximidamide)-platinum(ii) dichloride dichloromethane solvateExperimental 3D Coordinates
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CCDC 1401547: Experimental Crystal Structure Determination

2016

Related Article: Tatiyana V. Serebryanskaya, Alexander S. Novikov, Pavel V. Gushchin, Matti Haukka, Ruslan E. Asfin, Peter M. Tolstoy, Vadim Yu. Kukushkin|2016|Phys.Chem.Chem.Phys.(PCCP)|18|14104|doi:10.1039/C6CP00861E

Space GroupCrystallographyCrystal SystemCrystal Structure(N-Phenyl-N-(N'-phenylcarbamimidoyl)piperidine-1-carboximidamide)-platinum(ii) dichloride 12-dichloroethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1577118: Experimental Crystal Structure Determination

2018

Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[N-(nitroso)pyridin-2-aminato]-palladium(ii)Experimental 3D Coordinates
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CCDC 1401550: Experimental Crystal Structure Determination

2016

Related Article: Tatiyana V. Serebryanskaya, Alexander S. Novikov, Pavel V. Gushchin, Matti Haukka, Ruslan E. Asfin, Peter M. Tolstoy, Vadim Yu. Kukushkin|2016|Phys.Chem.Chem.Phys.(PCCP)|18|14104|doi:10.1039/C6CP00861E

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(N-Phenyl-N-(N'-phenylcarbamimidoyl)piperidine-1-carboximidamide)-platinum(ii) dichloride chloroform solvate
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CCDC 1577121: Experimental Crystal Structure Determination

2018

Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis{methyl 6-[(nitroso)amino]pyridine-3-carboxylatato}-palladium(ii)Experimental 3D Coordinates
researchProduct

CCDC 1401549: Experimental Crystal Structure Determination

2016

Related Article: Tatiyana V. Serebryanskaya, Alexander S. Novikov, Pavel V. Gushchin, Matti Haukka, Ruslan E. Asfin, Peter M. Tolstoy, Vadim Yu. Kukushkin|2016|Phys.Chem.Chem.Phys.(PCCP)|18|14104|doi:10.1039/C6CP00861E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(N-Phenyl-N-(N'-phenylcarbamimidoyl)piperidine-1-carboximidamide)-platinum(ii) dichloride bromoform solvateExperimental 3D Coordinates
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