0000000001055288
AUTHOR
Weize Yuan
Concise Chemistry Modulation of the SMM Behavior within a Family of Mononuclear Dy(III) Complexes.
By means of the facile chemistry, structural assembly, and transformation of four mononuclear Dy(III) complexes, Dy(bpad)3·CH3OH·H2O (1), Dy(bpad)2(H2O)2·NO3 (2), [Dy(bpad)2(tmhd)] (3), and [Dy(bpad)2(btfa)] (4) (Hbpad = N3-benzoylpyridine-2-carboxamidrazone, tmhd = 2,2,6,6-tetramethylheptane-3,5-dione, btfa = 3-benzoyl-1,1,1-trifluoroacetone), with distinct architectures and local symmetries were established. The disparity of the coordination geometries around the Dy(III) ion among these complexes impacts the strength of the crystal field and the local tensor of anisotropy ( D) of each Dy site and their relative orientations, therefore giving rise to diverse SIM behaviors with distinguishi…
CCDC 1845918: Experimental Crystal Structure Determination
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CCDC 1845917: Experimental Crystal Structure Determination
Related Article: Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jes��s Ferrando-Soria, Gang Xie, Sanping Chen, and Emilio Pardo|2018|Inorg.Chem.|57|14843|doi:10.1021/acs.inorgchem.8b02602
CCDC 1845915: Experimental Crystal Structure Determination
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CCDC 1478583: Experimental Crystal Structure Determination
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