0000000001062179

AUTHOR

Salah Ammar

showing 5 related works from this author

Electrochemical treatment of paper mill wastewater by electro-Fenton process

2019

Abstract The electrochemical oxidation of organics in paper mill wastewater belonging to Halfa industries (Tunisia) was performed by galvanostatic electrolyses using electro-Fenton (EF) process. The effect of several operating parameters, such as applied current density, electrodes material, air pressure and the presence of sodium chloride (NaCl) was evaluated. In particular, carbon felt (CF), modified carbon felt (MCF) and gas diffusion electrode (GDE) were used as cathode while Ti/IrO2-Ta2O5 and Boron Doped Diamond (BDD) as anode. Total Organic Carbon (TOC) measure was chosen as reference parameter to assess the extent of the treatment. The experimental results show that, by adopting the …

ElectrolysisAtmospheric pressureGas diffusion electrodeChemistryGeneral Chemical EngineeringElectro-Fenton Paper mill wastewater Modified carbon felt Pressurized electro-Fenton Electrochemical oxidation AOP02 engineering and technologySettore ING-IND/27 - Chimica Industriale E Tecnologica010402 general chemistry021001 nanoscience & nanotechnologyElectrochemistry01 natural sciencesCathode0104 chemical sciencesAnalytical Chemistrylaw.inventionAnodeWastewaterChemical engineeringlawElectrodeElectrochemistry0210 nano-technologyJournal of Electroanalytical Chemistry
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Electrochemical treatment of aqueous solutions of catechol by various electrochemical advanced oxidation processes: Effect of the process and of oper…

2017

Abstract Catechol, one of the most abundant compounds in olive mills wastewaters, which is generated in the Fenton degradation of various aromatic compounds, is a toxic, possible carcinogen, persistent pollutant and it is not readily biodegradable. Hence, its degradation requires the utilization of advanced oxidation processes (AOPs). Here, the electrochemical treatment of aqueous solutions of catechol was investigated. The utilization of various electrochemical processes, such as electro-Fenton (EF), direct anodic oxidation (AO), indirect oxidation by electro-generated active chlorine and coupled processes was investigated. Furthermore, the effect of various operating conditions (including…

CatecholAqueous solutionChemistryGeneral Chemical EngineeringAdvanced oxidation processInorganic chemistrychemistry.chemical_element02 engineering and technology010501 environmental sciences021001 nanoscience & nanotechnologyElectrochemistry01 natural sciencesCatechol; Advanced oxidation process electro-Fenton anodic oxidation; BDDAnalytical ChemistryAnodeCatalysischemistry.chemical_compoundCatecholElectrochemistryChlorineDegradation (geology)Advanced oxidation process electro-Fenton anodic oxidation0210 nano-technologyBDD0105 earth and related environmental sciences
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Effective Removal and Mineralization of 8-Hydroxyquinoline-5-sulfonic Acid through a Pressurized Electro-Fenton-like Process with Ni−Cu−Al Layered Do…

2020

Ni−Cu−Al layered double hydroxide (Ni−Cu−Al LDH) was proposed as an electro‐Fenton‐like catalyst for 8‐hydroxyquinoline‐5‐sulfonic acid (8‐HQS) removal in water. The properties of the prepared catalysts were characterized by using X‐ray, SEM and EDAX analyses. The effect of numerous operative parameters on the removal of 8‐HQS and total organic carbon (TOC) was studied. Very high level removal of both 8‐HQS and TOC (87 and 79 %, respectively) were obtained by using a pressurized electro‐Fenton‐like process (PrEFL‐LDH) at P=10 bars, using a Ti/IrO2‐Ta2O5 anode for 6 h. The process presented good performances in a large range of pH (3–10) and gave better removals of 8‐HQS and TOC with respect…

chemistry.chemical_classificationchemistry.chemical_compoundChemistry8-hydroxyquinoline-5-sulfonic acid heterogeneous catalysis Ni−Cu−Al layered double hydroxide nitrogen heterocycles pressurized-electro-FentonElectrochemistryHydroxide8-HydroxyquinolineMineralization (soil science)Sulfonic acidSettore ING-IND/27 - Chimica Industriale E TecnologicaHeterogeneous catalysisCatalysisNuclear chemistry
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Electrochemical treatment of aqueous solutions of organic pollutants by electro-Fenton with natural heterogeneous catalysts under pressure using Ti/I…

2018

The treatment of toxic organic pollutants by electro-Fenton (EF) presents some drawbacks such as the necessity to work at low pH and the low solubility of oxygen in water contacted with air or oxygen at room pressure that results often in slow and relatively low abatements. Here, the coupled adoption of natural heterogeneous catalysts and of relatively high pressure was proposed in order to improve the performances of EF for the treatment of organic pollutants. Caffeic acid (CA) and 3-chlorophenol were used as model resistant organic pollutants. EF process was performed using both conventional homogeneous FeSO4 and natural heterogeneous catalysts (pyrite, chalcopyrite, Fe2O3 and Fe3O4) as i…

Environmental EngineeringMaterials scienceHealth Toxicology and MutagenesisElectro-Fenton Organic pollutants Natural heterogeneous catalysts Pressurized electro-Fentonchemistry.chemical_elementPortable water purification02 engineering and technology010501 environmental sciencesHeterogeneous catalysis01 natural sciencesOxygenCatalysisEnvironmental ChemistrySolubility0105 earth and related environmental sciencesPollutantAqueous solutionPublic Health Environmental and Occupational HealthGeneral MedicineGeneral Chemistry021001 nanoscience & nanotechnologyPollutionAnodechemistryChemical engineering0210 nano-technology
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Electrochemical Abatement of Organic Pollutants in Water by Electro- Fenton with Natural Heterogeneous Catalysts Under Pressure

2020

In recent decades, electrochemical advanced oxidation processes (EAOPs) have proved as alternative technologies to conventional processes. Indeed, EAOPs can often allow to treat wastewater containing toxic and POPs. Among them, electro-Fenton (EF) is considered particularly promising for the treatment of recalcitrant organics, since it presents various advantages, including high abatements for many organic pollutants, simplicity of equipment and operations, relatively low cost and low consumption of chemicals. Recently, the utilization of some natural heterogeneous catalysts was proposed in order to avoid some disadvantages of the conventional EF process. In this frame, in this work EF proc…

Pressure electrochemical advanced oxidation processes EAOPs Electro-Fenton natural heterogeneous catalyst
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