0000000001075102
AUTHOR
Chengcheng C. Zhang
Enhanced Sieving of C2‐Hydrocarbon from Methane by Fluoro‐Functionalization of In‐MOF with Robust Stability
Developing efficient adsorbent materials is crucial for adsorption and separation to realize the purification of energy source and raw chemicals. Here, we report a novel and robust 3D In-based MOF built up with fluorine-functionalized ligands, QMOF-2F, with improved separation properties of C2-light hydrocarbons over methane at room temperature respect isoreticular non-fluorinated MOF. QMOF-2F shows a remarkable chemical stability in different solvents, including water, and pH (2-12). DFT calculations support the key role of fluorine-functionalization on the improved performance of QMOF-2F.
CCDC 2095771: Experimental Crystal Structure Determination
Related Article: Yan Guo, Chen Liang, Chengcheng C. Zhang, Jesús Ferrando‐Soria, Yu Gao, Jiahui H. Yang, Xiangyu Y. Liu, Emilio Pardo|2022|Chem.Asian J.|17|e202101220|doi:10.1002/asia.202101220
CCDC 2098781: Experimental Crystal Structure Determination
Related Article: Yan Guo, Chen Liang, Chengcheng C. Zhang, Jesús Ferrando‐Soria, Yu Gao, Jiahui H. Yang, Xiangyu Y. Liu, Emilio Pardo|2022|Chem.Asian J.|17|e202101220|doi:10.1002/asia.202101220