0000000001080476
AUTHOR
G. Calestani
Band filling effect on polaron localization in La$_{1-x}($Ca$_y$Sr$_{1-y}$)$_{x}$MnO$_3$ manganites
We report on an a $\mu$SR and $^{55}$Mn NMR investigation of the magnetic order parameter as a function of temperature in the optimally doped La$_{5/8}$(Ca$_y$Sr$_{1-y}$)$_{3/8}$MnO$_3$ and in the underdoped La$_{1-x}$Sr$_{x}$MnO$_3$ and La$_{1-x}$Ca$_{x}$MnO$_3$ metallic manganite families. The study is aimed at unraveling the effect of lattice distortions, implicitly controlled by the Ca-Sr isoelectronic substitution, from that of hole doping $x$ on the Curie temperature $T_c$ and the order of the magnetic transition. At optimal doping, the transitions are second order at all $y$ values, including the $y=1$ (La$_{5/8}$Ca$_{3/8}$MnO$_3$) end member. In contrast, they are first order in the…
Internal-strain mediated coupling between polar Bi and magnetic Mn ions in the defect-free quadruple-perovskite BiMn$_3$Mn$_4$O$_{12}$
By means of neutron powder diffraction, we investigated the effect of the polar Bi$^{3+}$ ion on the magnetic ordering of the Mn$^{3+}$ ions in BiMn$_3$Mn$_4$O$_{12}$, the counterpart with \textit{quadruple} perovskite structure of the \textit{simple} perovskite BiMnO$_3$. The data are consistent with a \textit{noncentrosymmetric} spacegroup $Im$ which contrasts the \textit{centrosymmetric} one $I2/m$ previously reported for the isovalent and isomorphic compound LaMn$_3$Mn$_4$O$_{12}$, which gives evidence of a Bi$^{3+}$-induced polarization of the lattice. At low temperature, the two Mn$^{3+}$ sublattices of the $A'$ and $B$ sites order antiferromagnetically (AFM) in an independent manner …
CCDC 1038087: Experimental Crystal Structure Determination
Related Article: A. Airoldi, P. Bettoni, M. Donnola, G. Calestani, C. Rizzoli|2015|Acta Crystallogr.,Sect.E:Cryst.Commun.|71|51|doi:10.1107/S2056989014026863