0000000001085912

AUTHOR

J. Lasri

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Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate

2017

The title complex, [PdCl2(C8H14N2O)2]2H2O, was obtained by N–O bond cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl- 5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1 )]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two trans-arranged chloride anions and a nitrogen atom from each of the two neutral organic ligands. In the crystal, N—HO, O—HO and O—HCl hydrogen bonds link complex molecules into double layers parallel to the bc plane. peerReviewed

nitronecrystal structurenitrileN—O bond cleavagecyclo­additionpalladium
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CCDC 1537327: Experimental Crystal Structure Determination

2017

Related Article: J. Lasri, N.E. Eltayeb, M. Haukka, B.A. Babgi|2017|Acta Crystallogr.,Sect.E:Cryst.Commun.|73|528|doi:10.1107/S2056989017003929

Space GroupCrystallographydichloro-bis(N-(22-dimethyl-34-dihydro-2H-pyrrol-5-yl)acetamide)-palladium(ii) dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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