0000000001091510

AUTHOR

Marcis Lielbardis

showing 2 related works from this author

Synthesis and investigation of charge transport properties in adducts of hole transporting carbazole derivatives and push-pull azobenzenes

2019

Abstract In order to investigate the viability of a material design for bulk heterojunction (BHJ) organic solar cells, where hole transporting group is bound to the donor moiety, we report the synthesis and charge transport characteristics of 3-(diphenylamino)carbazolyl-functionalized derivatives of 2-(4-((4-(dimethylamino)phenyl)diazenyl)benzylidene)-1H-indene-1,3-dione (DMAAzi) chromophore. Three different bounding configurations were examined in these adducts. Additionally, a trityl-functionalized derivative of DMAAzi was prepared and used for comparison purposes. All of the synthesized materials form thin amorphous films from volatile organic solvents and exhibit glass transition temper…

Materials scienceOrganic solar cellCarbazole02 engineering and technologyGeneral ChemistryChromophore010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsPhotochemistry01 natural sciencesPolymer solar cell0104 chemical sciencesAmorphous solidchemistry.chemical_compoundchemistryElectron affinityGeneral Materials ScienceCharge carrier0210 nano-technologyGlass transitionJournal of Physics and Chemistry of Solids
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3,3'-Bicarbazole structural derivatives as charge transporting materials for use in OLED devices

2018

In this study we report novel 3,3′-bicarbazole based charge transporting materials mainly designed for a use in systems containing phosphorescent iridium (III) complex emitters. A low-cost oxidative coupling reaction using FeCl3 was employed in the synthesis of 3,3′-bicarbazole compounds. Different derivatives of 3,3′-bicarbazole with 4-ethoxyphenyland ethyl- substituents at 9,9′- positions and (2,2-diphenylhydrazono)methyl- and 4-(dimethylamino)styryl- substituents at 6,6′- positions were synthesized. Obtained (2,2-diphenylhydrazono)methyl- derivatives exhibit glass transition temperatures that are sufficient for applications in electronic devices. Thin amorphous films of good optical qual…

chemistry.chemical_classificationMaterials sciencechemistryElectron affinityOLEDPhysical chemistrychemistry.chemical_elementMoleculeIridiumElectron acceptorGlass transitionPhosphorescenceAmorphous solidOrganic Electronics and Photonics: Fundamentals and Devices
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