0000000001095175

AUTHOR

Markus D. Kärkäs

0000-0002-6089-5454

showing 2 related works from this author

Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework.

2016

The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the di-nucleating ligand 2,2-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant [Ru(bpy)(3)](3+). Funding Agencies|Knut and Alice Wallenberg Foundation; Swedish Research Council [621-2013-4872]; Carl Trygger Foundation; DFG (Metal Sites in Biomolecules: Structures, Regulation and Mechanisms) [IRTG 1422]; Swedish Energy Agency

Organisk kemiElectrolysis of water010405 organic chemistryChemistryLigandOrganic ChemistryInorganic chemistry010402 general chemistry01 natural sciences0104 chemical sciencesCatalysisInorganic Chemistryiron complexesligand frameworkFe complexes; ligand frameworkwater oxidationPolymer chemistryIron complexta116Dalton transactions (Cambridge, England : 2003)
researchProduct

CCDC 966406: Experimental Crystal Structure Determination

2016

Related Article: Biswanath Das, Bao-Lin Lee, Erik A. Karlsson, Torbjörn Åkermark, Andrey Shatskiy, Serhiy Demeshko, Rong-Zhen Liao, Tanja M. Laine, Matti Haukka, Erica Zeglio, Ahmed F. Abdel-Magied, Per E. M. Siegbahn, Franc Meyer, Markus D. Kärkäs, Eric V. Johnston, Ebbe Nordlander, Björn Åkermark|2016|Dalton Trans.|45|13289|doi:10.1039/C6DT01554A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu-2-[3-(7-carboxylato-1H-benzimidazol-2-yl)-2-oxy-5-methylphenyl]-1H-benzimidazole-4-carboxylato)-nonakis(mu-oxo)-nona-iron acetonitrile dimethyl sulfoxide unknown solvate tetrahydrateExperimental 3D Coordinates
researchProduct