0000000001098734
AUTHOR
S. V. Fokin
A black-box approach to the construction of metal-radical multispin systems and analysis of their magnetic properties
An interaction of M(hfac)2 (M = Mn or Ni) with N-(bis(4,4,5,5-tetramethyl-3-oxido-1-oxyl-4,5-dihydro-1H-imidazol-2-yl)methylene)-2-methyl-propan-2-amine oxide (a nitronyl nitroxide diradical with theC[double bond, length as m-dash]N(O)-tert-Bu coupler) was investigated under various conditions. It was found that prolongation of reaction time caused transformation of the initial diradical into new diradicals with the uniqueC[double bond, length as m-dash]N-OH coupling unit and formation of binuclear Mn(ii) and Ni(ii) complexes, which were characterized by X-ray diffraction analysis. The resulting binuclear heterospin complexes have a complicated magnetic structure with six paramagnetic cente…
CCDC 1988289: Experimental Crystal Structure Determination
Related Article: E. M. Kadilenko, N. P. Gritsan, E. V. Tretyakov, S. V. Fokin, G. V. Romanenko, A. S. Bogomyakov, D. E. Gorbunov, D. Schollmeyer, M. Baumgarten, V. I. Ovcharenko|2020|Dalton Trans.|49|16916|doi:10.1039/D0DT03184D
CCDC 1922230: Experimental Crystal Structure Determination
Related Article: E. M. Kadilenko, N. P. Gritsan, E. V. Tretyakov, S. V. Fokin, G. V. Romanenko, A. S. Bogomyakov, D. E. Gorbunov, D. Schollmeyer, M. Baumgarten, V. I. Ovcharenko|2020|Dalton Trans.|49|16916|doi:10.1039/D0DT03184D
CCDC 1988288: Experimental Crystal Structure Determination
Related Article: E. M. Kadilenko, N. P. Gritsan, E. V. Tretyakov, S. V. Fokin, G. V. Romanenko, A. S. Bogomyakov, D. E. Gorbunov, D. Schollmeyer, M. Baumgarten, V. I. Ovcharenko|2020|Dalton Trans.|49|16916|doi:10.1039/D0DT03184D
CCDC 1922229: Experimental Crystal Structure Determination
Related Article: E. M. Kadilenko, N. P. Gritsan, E. V. Tretyakov, S. V. Fokin, G. V. Romanenko, A. S. Bogomyakov, D. E. Gorbunov, D. Schollmeyer, M. Baumgarten, V. I. Ovcharenko|2020|Dalton Trans.|49|16916|doi:10.1039/D0DT03184D
CCDC 1988287: Experimental Crystal Structure Determination
Related Article: E. M. Kadilenko, N. P. Gritsan, E. V. Tretyakov, S. V. Fokin, G. V. Romanenko, A. S. Bogomyakov, D. E. Gorbunov, D. Schollmeyer, M. Baumgarten, V. I. Ovcharenko|2020|Dalton Trans.|49|16916|doi:10.1039/D0DT03184D