0000000001101013

AUTHOR

C. Masalles

showing 2 related works from this author

The [3,3′-Co(1,2-C2B9H11)2]– anion as a platform for new materials: synthesis of its functionalized monosubstituted derivatives incorporating synthon…

2003

[3,3′-Co(8-C5H10O-1,2-C2B9H10)(1′,2′-C2B9H11)] (2) was synthesized by reaction of the caesium salt of [Co(C2B9H11)2]− with dimethyl sulfate in the presence of sulfuric acid as catalyst and tetrahydropyrane as solvent; the zwitterionic compound (2) yielded [3,3′-Co(8-C4H4N-(CH2)5-O-1,2-C2B9H10)(1′,2′-C2B9H11)]− (6), [3,3′-Co(8-C8H6N-(CH2)5-O-1,2-C2B9H10)(1′,2′-C2B9H11)]− (7), and [3,3′-Co(8-C12H8N-(CH2)5-O-1,2-C2B9H10)(1′,2′-C2B9H11)]− (8) through the nucleophilic addition of potassium pyrrolyl, indolyl and carbazolyl, respectively. The nucleophilic addition of the same salts on [3,3′-Co(8-C4H8O2-1,2-C2B9H10)(1′,2′-C2B9H11)] (1) yielded, respectively, [3,3′-Co(8-C4H4N-(CH2)2-O-(CH2)2-O-1,2-C…

chemistry.chemical_classificationNucleophilic additionStereochemistryChemistrySynthonSalt (chemistry)Medicinal chemistryInorganic ChemistrySolventDimethyl sulfatechemistry.chemical_compoundNucleophileIntramolecular forceMoleculeDalton Transactions
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CCDC 168258: Experimental Crystal Structure Determination

2003

Related Article: J.Llop, C.Masalles, C.Vinas, F.Teixidor, R.Sillanpaa, R.Kivekas|2003|Dalton Trans.||556|doi:10.1039/b211860m

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~3~-eta^5^-8-(Pyrrolylethoxyethoxy)-33'-commo-bis(3-cobalta-12-dicarba-closo-dodecaborane))-potassium]Experimental 3D Coordinates
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