0000000001107588
AUTHOR
Marco T. Passia
Synthesis of N‐Monosubstituted Sulfondiimines by Metal‐free Iminations of Sulfiliminium Salts
Sulfondiimines are marginalized entities among nitrogencontaining organosulfur compounds, despite offering promising properties for applications in various fields including medicinal and agrochemical. Herein, we present a metal-free and rapid synthetic procedure for the synthesis of N-monosubstituted sulfondiimines that overcomes current limitations in their synthetic accessibility. Particularly, S,S-dialkyl substrates, which are commonly difficult to convert by existing methods, react well with a combination of iodine, 1,8-diazabicyclo[5.4.0]undec-7-en (DBU), and iminoiodanes (PhINR) in acetonitrile (MeCN) to furnish the corresponding sulfondiimines in yields up to 85% (25 examples). Valua…
CCDC 2242257: Experimental Crystal Structure Determination
Related Article: Marco T. Passia, Niklas Bormann, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202305703
CCDC 2242258: Experimental Crystal Structure Determination
Related Article: Marco T. Passia, Niklas Bormann, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202305703