Optical, thermal, electrical, damage, and phase-matching properties of lithium selenoindate

Lithium selenoindate (LiInSe2) is a new nonlinear chalcogenide biaxial crystal, related to LiInS2 and transparent from 0.54 to 10 μm at the 50% level (10 mm thickness), which has been successfully grown in large sizes and with good optical quality. We report on what we believe to be new physical properties that are relevant for laser and nonlinear optical applications and summarize all relevant characteristics, both from the literature and as measured in the present work. With respect to AgGaS(e)2 ternary chalcopyrite materials, LiInSe2 displays a nearly isotropic thermal expansion behavior with three- to five-times-larger thermal conductivities associated with high optical damage threshold…