0000000001119927

AUTHOR

Sergey V. Baykov

0000-0002-8912-5816

showing 2 related works from this author

Intermolecular hydrogen bonding H···Cl in crystal structure of palladium(II)-bis(diaminocarbene) complex

2018

Abstract The reaction of bis(isocyanide)palladium complex cis-[PdCl2(CNXyl)2] (Xyl=2,6-Me2C6H3) with excess of 4,5-dichlorobenzene-1,2-amine in a C2H4Cl2/MeOH mixture affords monocationic bis(diaminocarbene) complex cis-[PdClC{(NHXyl)=NHC6H2Cl2 NH2}{C(NHXyl)=NHC6H2Cl2NH2}]Cl (3) in moderate yield (42%). Complex 3 exists in the solid phase in the H-bonded dimeric associate of two single charged organometallic cations and two chloride anions according to X-ray diffraction data. The Hirshfeld surface analysis for the X-ray structure of 3 reveals that the crystal packing is determined primarily by intermolecular contacts H–Cl, H–H, and H–C. The intermolecular hydrogen bonds N–H···Cl and C–H···C…

chemistry.chemical_classificationMaterials science010405 organic chemistryHydrogen bondIntermolecular forcechemistry.chemical_elementCrystal structure010402 general chemistryCondensed Matter Physics01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographychemistryNon-covalent interactionsGeneral Materials SciencePalladiumZeitschrift für Kristallographie - Crystalline Materials
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CCDC 1825193: Experimental Crystal Structure Determination

2019

Related Article: Mikhail A. Kinzhalov, Sergey V. Baykov, Alexander S. Novikov, Matti Haukka, Vadim P. Boyarskiy|2019|Z.Krist.Cryst.Mater.|234|155|doi:10.1515/zkri-2018-2100

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis{[(2-amino-45-dichlorophenyl)amino][(26-dimethylphenyl)amino]methylidene}-(chloro)-palladium(ii) chlorideExperimental 3D Coordinates
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