0000000001136106

AUTHOR

Peter D. Southon

showing 5 related works from this author

Exploiting Pressure To Induce a "Guest-Blocked" Spin Transition in a Framework Material.

2016

A new functionalized 1,2,4-triazole ligand, 4-[(E)-2-(5-methyl-2-thienyl)vinyl]-1,2,4-triazole (thiome), was prepared to assess the broad applicability of strategically producing multistep spin transitions in two-dimensional Hofmann-type materials of the type [FeIIPd(CN)4(R-1,2,4-trz)2]·nH2O (R-1,2,4-trz = a 4-functionalized 1,2,4-triazole ligand). A variety of structural and magnetic investigations on the resultant framework material [FeIIPd(CN)4(thiome)2]·2H2O (A·2H2O) reveal that a high-spin (HS) to low-spin (LS) transition is inhibited in A·2H2O due to a combination of guest and ligand steric bulk effects. The water molecules can be reversibly removed with retention of the porous host f…

Steric effects010405 organic chemistryLigandChemistryStereochemistryHydrostatic pressureSpin transitionInternal pressure010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographyMoleculePhysical and Theoretical ChemistryPorositySpin-½Inorganic chemistry
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CCDC 1480120: Experimental Crystal Structure Determination

2016

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tetrakis(mu-cyano)-bis(1-(5-methyl-2-thienyl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium]Cell ParametersExperimental 3D Coordinates
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CCDC 1480121: Experimental Crystal Structure Determination

2016

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu-cyano)-bis(1-(5-methyl-2-thienyl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate]Experimental 3D Coordinates
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CCDC 1480123: Experimental Crystal Structure Determination

2016

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tetrakis(mu-cyano)-bis(1-(5-methyl-2-thienyl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium]Cell ParametersExperimental 3D Coordinates
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CCDC 1480122: Experimental Crystal Structure Determination

2016

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tetrakis(mu-cyano)-bis(1-(5-methyl-2-thienyl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium]Cell ParametersExperimental 3D Coordinates
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