0000000001165842

AUTHOR

I. Rodriguez

showing 2 related works from this author

Protection of high-density polyethylene-silicon composites from ultraviolet-visible photodegradation

2017

[EN] The extent of the ultraviolet¿visible (UV¿vis) photoirradiation effect on high-density polyethylene (HDPE) and HDPE¿sili-con (Si) composites is reported in terms of the addition of Si microparticles at contents of 0.1, 1, and 5 wt %. A standard acceleratedUV-vis exposure was applied over 2750 h, corresponding to 22 months in Florida. Thermogravimetry, differential scanning calorimetry,and Fourier transform infrared spectroscopy were used as reliable techniques for monitoring the quality of the HDPE-Si composites. Theincreasing addition of Si microparticles delayed the photodegradation of the HDPE¿Si composites. Because of their strong light-scattering effects, Si microparticles blocked…

Materials scienceThermal propertiesPolymers and PlasticsSiliconComposite numberDifferential scanning calorimetry (DSC)chemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesElectron Microscopy Service of the UPVchemistry.chemical_compoundDegradationDifferential scanning calorimetryMaterials ChemistryFourier transform infrared spectroscopyComposite materialPhotodegradationMaterials compostosThermogravimetric analysis (TGA)TermoplàsticsGeneral ChemistryPolyolefinsPolyethylene021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsThermogravimetrychemistryMAQUINAS Y MOTORES TERMICOSHigh-density polyethylene0210 nano-technology
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Novel silicon microparticles to improve sunlight stability of raw polypropylene

2015

Oxidation of polyolefins by ultraviolet/visible irradiation is a significant limitation for their use in several technological applications. The use of high-tech additives such as silicon microparticles becomes a compositing strategy that can improve the performance of these materials at long-term service conditions. Silicon particles were added to non-additivated raw polypropylene (PP) prepared by hot melt extrusion and subjected to accelerated sunlight irradiation tests. The stability of thermal properties, mechanical performance and thermal decomposition behaviour of composites was evaluated by differential scanning calorimetry, dynamic mechanical thermal analysis and thermogravimetry. T…

Silicon microparticlesSunlight irradiationNear-IR reflective pigmentSolucions polimèriquesMaterials sciencePolymers and PlasticsSiliconGeneral Physics and Astronomychemistry.chemical_elementCompositechemistry.chemical_compoundCIENCIA DE LOS MATERIALES E INGENIERIA METALURGICAMaterials ChemistryThermal stabilityThermal analysisComposite materialPhotodegradationThermal analysisPhoto-degradationPlastic additivesPolypropyleneTermoplàsticsOrganic ChemistryThermal decompositionPolyolefinPolyolefinThermogravimetrychemistryMAQUINAS Y MOTORES TERMICOSPolypropyleneEuropean Polymer Journal
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