0000000001169684
AUTHOR
Nitis Chandra Saha
Synthesis, characterization, X-ray crystallography, and antimicrobial activities of Ni(II) and Cu(II) complexes with a salicylaldehyde-based thiosemicarbazone ligand
A new salicylaldehyde-based ‘ONS’ tridentate salicylaldehyde-N(4)-diethylthiosemicarbazone (H2SANEt2) has been synthesized and characterized by elemental analyses, mass, IR, and 1H NMR spectral parameters. The coordination mode of the synthesized ligand is reported by solid state isolation and physico-chemical identification of Ni(II) and Cu(II) complexes, [Ni(SANEt2)]2 (1) and [Cu(SANEt2)]2 (2). Both complexes are neutral and oxygen-bridged dinuclear species. The ligand is bideprotonated ‘ONS’ tridentate in both complexes. IR spectral data indicate that coordination of each metal of the two complexes occurs through phenolic oxygen, azomethine nitrogen, and thiolato sulfur. X-ray crystallog…
CCDC 903324: Experimental Crystal Structure Determination
Related Article: Nitis Chandra Saha, Rajesh Pradhan, Mousumi Das, Nasima Khatun, Debmalya Mitra, Amalesh Samanta, Alexandra M.Z. Slawin, Atish Dipankar Jana, Julia Klanke, Eva Rentschler|2014|J.Coord.Chem.|67|286|doi:10.1080/00958972.2014.880426
CCDC 903325: Experimental Crystal Structure Determination
Related Article: Nitis Chandra Saha, Rajesh Pradhan, Mousumi Das, Nasima Khatun, Debmalya Mitra, Amalesh Samanta, Alexandra M.Z. Slawin, Atish Dipankar Jana, Julia Klanke, Eva Rentschler|2014|J.Coord.Chem.|67|286|doi:10.1080/00958972.2014.880426