0000000001184318

AUTHOR

Subrata Jana

0000-0002-4261-0531

showing 3 related works from this author

Synthesis, characterization and magnetic study of two new octahedral iron(III) complexes with pendant zwitterionic Schiff bases

2016

Two Schiff bases, HL1 [2-((3-(dimethylamino)propylimino)methyl)-5-bromophenol] and HL2 [2-((2-(diethylamino)ethylimino)methyl)-6-methoxyphenol], have been employed to prepare two new octahedral iron(III) complexes, [Fe(HL1)2(N3)2]ClO4·2H2O (1) and [Fe(HL2)2(NCS)2]ClO4·H2O (2). Both complexes are characterized by spectral and elemental analyses. Single crystal X-ray diffraction studies confirm their structures. In both complexes, Schiff bases are trapped in their zwitterionic forms and coordinated to iron(III) only through the imine nitrogen and phenoxo oxygen, i.e., they behave as bi-dentate ligands, keeping the remaining potential donor sites pendant. The measurement of χM vs. T for both c…

crystal structurevariable temperature magnetic susceptibilityIminechemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciencesOxygenzwiterionicInorganic Chemistrypendantchemistry.chemical_compoundMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryMagnetic studyta116010405 organic chemistryNitrogen0104 chemical sciencesCrystallographychemistryOctahedronPotential donorSingle crystaliron(III)Inorganica Chimica Acta
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CCDC 1406302: Experimental Crystal Structure Determination

2016

Related Article: Subrata Jana, Anik Bhattacharyya, Biswa Nath Ghosh, Kari Rissanen, Santiago Herrero, Reyes Jiménez-Aparicio, Shouvik Chattopadhyay|2016|Inorg.Chim.Acta|453|715|doi:10.1016/j.ica.2016.09.005

Space GroupCrystallographybis(NN-diethyl-2-((2-oxy-3-methoxybenzylidene)amino)ethanaminiumato)-bis(isothiocyanato)-iron(iii) perchlorate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1406301: Experimental Crystal Structure Determination

2016

Related Article: Subrata Jana, Anik Bhattacharyya, Biswa Nath Ghosh, Kari Rissanen, Santiago Herrero, Reyes Jiménez-Aparicio, Shouvik Chattopadhyay|2016|Inorg.Chim.Acta|453|715|doi:10.1016/j.ica.2016.09.005

Space GroupCrystallographydiazido-bis(3-((5-bromo-2-oxybenzylidene)amino)-NN-dimethylpropan-1-aminium)-iron(iii) perchlorate dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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