Experimental constraints on pre-eruptive conditions of a chemically-zoned peralkaline ignimbrite: the Green Tuff eruption at Pantelleria Island (Italy)

Pantelleria island is the type locality for pantellerite, an iron and alkali-rich rhyolite. The eruptive products outcropping in the island fall in a mafic end member (mildly alkaline basalt) and a felsic end member (metaluminous trachytes and pantellerites). A key event in the volcanological history of the island is the Green Tuff eruption the sole ignimbrite at Pantelleria compositionally zoned from crystal-poor pantellerite at the base to crystal-rich trachyte at the top. We experimentally investigated the phase relations of the pantelleritic end member AI = 1.8 (agpaitic index = molar ratio Na2O+K2O/Al2O3) and trachyte end member AI = 1.05 of the Green Tuff eruption. The intensive varia…