0000000001187137
AUTHOR
Martin Kapuscinski
Crystal Structures and Polymorphism of Nickel and Copper Coordination Polymers with Pyridine Ligands
The crystal structures of a series of pyridine coordination polymers [MIICl2(C5H5N)x]n (M = Ni, Cu), prepared via thermal decomposition are reported. [NiCl2(C5H5N)4] (1) decomposes stepwise via [NiCl2(C5H5N)2]n (2), [NiCl2(C5H5N)]n (3), and [NiCl2(C5H5N)2/3]n (4), to NiCl2 with increasing temperature. The thermal decomposition of [CuCl2(C5H5N)2]n (5), progresses via two polymorphs of [CuCl2(C5H5N)]n (6a and 6b), and [CuCl2(C5H5N)2/3]n (7), to CuCl2. The compounds 3, 4, and 7 were prepared as pure phases. All crystal structures were determined by X-ray powder diffraction. Notably, the crystal structures of the polymorphs 6a and 6b were determined from powder diffraction data of a mixture of …
CCDC 1503642: Experimental Crystal Structure Determination
Related Article: Yaşar Krysiak, Lothar Fink, Thomas Bernert, Jürgen Glinnemann, Martin Kapuscinski, Haishuang Zhao, Edith Alig, Martin U. Schmidt|2014|Z.Anorg.Allg.Chem.|640|3190|doi:10.1002/zaac.201400505
CCDC 1503641: Experimental Crystal Structure Determination
Related Article: Yaşar Krysiak, Lothar Fink, Thomas Bernert, Jürgen Glinnemann, Martin Kapuscinski, Haishuang Zhao, Edith Alig, Martin U. Schmidt|2014|Z.Anorg.Allg.Chem.|640|3190|doi:10.1002/zaac.201400505
CCDC 1503643: Experimental Crystal Structure Determination
Related Article: Yaşar Krysiak, Lothar Fink, Thomas Bernert, Jürgen Glinnemann, Martin Kapuscinski, Haishuang Zhao, Edith Alig, Martin U. Schmidt|2014|Z.Anorg.Allg.Chem.|640|3190|doi:10.1002/zaac.201400505
CCDC 1503639: Experimental Crystal Structure Determination
Related Article: Yaşar Krysiak, Lothar Fink, Thomas Bernert, Jürgen Glinnemann, Martin Kapuscinski, Haishuang Zhao, Edith Alig, Martin U. Schmidt|2014|Z.Anorg.Allg.Chem.|640|3190|doi:10.1002/zaac.201400505
CCDC 1503640: Experimental Crystal Structure Determination
Related Article: Yaşar Krysiak, Lothar Fink, Thomas Bernert, Jürgen Glinnemann, Martin Kapuscinski, Haishuang Zhao, Edith Alig, Martin U. Schmidt|2014|Z.Anorg.Allg.Chem.|640|3190|doi:10.1002/zaac.201400505