0000000001189496

AUTHOR

Bethany Ross

showing 2 related works from this author

Isolated Fe(III)-O Sites Catalyze the Hydrogenation of Acetylene in Ethylene Flows under Front-End Industrial Conditions

2018

[EN] The search for simple, earth-abundant, cheap, and nontoxic metal catalysts able to perform industrial hydrogenations is a topic of interest, transversal to many catalytic processes. Here, we show that isolated FeIII¿O sites on solids are able to dissociate and chemoselectively transfer H2 to acetylene in an industrial process. For that, a novel, robust, and highly crystalline metal¿organic framework (MOF), embedding FeIII¿OH2 single sites within its pores, was prepared in multigram scale and used as an efficient catalyst for the hydrogenation of 1% acetylene in ethylene streams under front-end conditions. Cutting-edge X-ray crystallography allowed the resolution of the crystal structur…

EthylenebiologyChemistryActive site02 engineering and technologyGeneral ChemistryCrystal structure010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistryCatalysis0104 chemical sciencesCatalysischemistry.chemical_compoundColloid and Surface ChemistryQUIMICA ORGANICAAcetyleneChemical engineeringbiology.proteinCubic zirconiaMetal catalyst0210 nano-technologyEfficient catalyst
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CCDC 1835021: Experimental Crystal Structure Determination

2018

Related Article: María Tejeda-Serrano, Marta Mon, Bethany Ross, Francisco Gonell, Jesus Ferrando-Soria, Avelino Corma, Antonio Leyva-Perez, Donatella Armentano, Emilio Pardo|2018|J.Am.Chem.Soc.|140|8827|doi:10.1021/jacs.8b04669

catena-(hexa-aqua-iron(iii) hemikis(bis(mu-oxo)-hexa-aqua-di-iron(iii)) bis(tris(mu-22'-[(246-trimethyl-13-phenylene)diazanediyl]bis(oxoacetato))-triaqua-tri-copper(ii)-di-nickel(ii)) hexahexacontahydrate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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