0000000001226493
AUTHOR
M. El Azhari
5-Acetyl-6-methyl-4-phenyl-1-(prop-2-ynyl)-3,4-dihydropyrimidin-2(1H)-one
The 4-dihydropyrimidin-2(1H)-one moiety of the title molecule, C16H16N2O2, displays a half-chair conformation. The least-squares mean plane through this heterocycle is almost perpendicular to the aromatic ring [dihedral angle = 89.52 (8)°] and to the prop-2-ynyl chain [C—C—N—C torsion angle of −73.2 (2)°]. The mean plane through the acetyl group makes a dihedral angle of 30.93 (10)° with the mean plane of the heterocycle. There is an intramolecular C—H...O hydrogen bond forming anS(6) ring motif. In the crystal, molecules are linked by pairs of N—H...O hydrogen bonds forming inversion dimers.
CCDC 1812012: Experimental Crystal Structure Determination
Related Article: H. Kaoukabi, M. Taourirte, H.B. Lazrek, M. El Azhari, M. Saadi, L. El Ammari|2017|IUCrData|2|x171802|doi:10.1107/S2414314617018028