Interdiffusion in blends of polystyrene and polymethylstyrene studied by light scattering after temperature jumps across the phase boundary

1992

Abstract We describe a simple light scattering set-up for measuring interdiffusion coefficients D in polymer blends by generating spinodal decomposition and subsequent dissolution after temperature jumps across the phase boundary. In blends of polystyrene and polymethylstyrene (random copolymer of 60% m-methylstyrene and 40% p-methylstyrene) D values were obtained between 10−11 and 10−15 cm2s−1 at temperatures up to 50 K above the upper critical solution temperature. The results are discussed in relation to tracer diffusion in the same system.