0000000001250196
AUTHOR
Pallab Bhowmik
Synthesis, crystal structure and magnetic properties of two alternating double μ1,1 and μ1,3 azido bridged Cu(ii) and Ni(ii) chains
Two new alternating μ1,1- and μ1,3-azido bridged chains, [Cu(N3)2(mtn)]n (1) and [Ni(N3)2(mtn)]n (2) where mtn = N-methyl-1,3-propanediamine, have been synthesized and characterized by single crystal X-ray diffraction. In both complexes, each metal atom is coordinated to six nitrogen atoms from four azide anions and one N-methyl-1,3-propanediamine molecule in a distorted octahedral geometry. In 1, the basal-apical double μ1,1-azido bridged Cu(ii)-dimers are connected through two asymmetric μ1,3-N3 bridges to form a 1D chain in which one of the azide acts as a μ1,1,3 bridge while the other one is terminal. The structure of 2 is very similar but one of the azide ions acts as μ1,1 and the othe…
CCDC 984094: Experimental Crystal Structure Determination
Related Article: Pallab Bhowmik, Saptarshi Biswas, Shouvik Chattopadhyay, Carmen Diaz, Carlos J. Gómez-García, Ashutosh Ghosh|2014|Dalton Trans.|43|12414|doi:10.1039/C4DT00328D
CCDC 984093: Experimental Crystal Structure Determination
Related Article: Pallab Bhowmik, Saptarshi Biswas, Shouvik Chattopadhyay, Carmen Diaz, Carlos J. Gómez-García, Ashutosh Ghosh|2014|Dalton Trans.|43|12414|doi:10.1039/C4DT00328D