Comparison of the Photoelectronic and Photocatalytic Activities of Various Anatase and Rutile Forms of Titania in Pure Liquid Organic Phases and in Aqueous Solutions

Various titania samples of industrial origin (Degussa and Tioxide) have been characterized by electrical photoconductance measurements and tested as photocatalysts in various liquid media (either pure organic liquids or aqueous solutions) as a function of their structure (anatase versus rutile). Anatase was constantly found more active than rutile, whatever the reaction chosen (mild oxidation of pure cyclohexane and 2-propanol; total degradation of phenol and nitrophenol isomers in water). In identical conditions, Degussa was found more active, but the intrinsic activity, expressed in moles converted per hour and per square meter of active surface, was found slightly higher for anatase Tiox…