0000000001254713

AUTHOR

Erkam Cebi

Endohedral Mixed Aggregates: Sodium Alkoxide Cages with Organic or Inorganic Central Anions and Variable Hull.

Abstract Alkali metal alkoxides are widely used in chemistry due to their Brønsted basic and nucleophilic properties. Potassium alkoxides assist alkyllithium in the metalation of hydrocarbons in Lochmann‐Schlosser‐bases. Both compounds form mixed aggregates, which enhance the thermal stability, solubility, and the basic reactivity of these mixtures. A very unusual spherical mixed alkoxy aggregate was discovered by Grützmacher et al., where a central dihydrogen phosphide anion is surrounded by a highly dynamic shell of thirteen sodium atoms and a hull of twelve tert‐butoxide groups. This structural motif can be reproduced by a reaction of trimethylsilyl compounds of methane, halogens, or pse…

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CCDC 2061409: Experimental Crystal Structure Determination

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

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CCDC 2061412: Experimental Crystal Structure Determination

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

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CCDC 2061408: Experimental Crystal Structure Determination

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

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CCDC 2061410: Experimental Crystal Structure Determination

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

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CCDC 2061407: Experimental Crystal Structure Determination

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

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CCDC 2061411: Experimental Crystal Structure Determination

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

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