Author: Zhijuan Zhao

0000000001265700

AUTHOR

Zhijuan Zhao

Tailoring polymers through interplay of ligands within precatalysts: 8-(Nitro/benzhydryl-arylimino)-7,7-dimethyl-5,6-dihydroquinolylnickel halides in ethylene polymerization

A series of 8-(nitro/benzhydryl-substituted arylimino)-7,7-dimethyl-5,6-dihydroquinolines and the corresponding nickel halide complexes were synthesized and characterized. Molecular structures of representative nickel complexes were determined by single crystal X-ray diffraction, showing the dinuclear dimers with distorted square-pyramidal geometry around the nickel center. The binding energies determined by X-ray photoelectron spectroscopy (XPS) indicate the effective coordination between the sp2-nitrogen and nickel atoms as well as the influence of both the halogen ligands and the substituents within dihydroquinolines on the strength of the NiN bond. Ethylene polymerization with the nicke…

research product

CCDC 1530049: Experimental Crystal Structure Determination

Related Article: Chaunbing Huang, Yanning Zeng, Zygmunt Flisak, Zhijuan Zhao, Tongling Liang, Wen-Hua Sun|2017|J.Polym.Sci.,Part A:Polym.Chem.|55|2071|doi:10.1002/pola.28595

research product

CCDC 1530048: Experimental Crystal Structure Determination

Related Article: Chaunbing Huang, Yanning Zeng, Zygmunt Flisak, Zhijuan Zhao, Tongling Liang, Wen-Hua Sun|2017|J.Polym.Sci.,Part A:Polym.Chem.|55|2071|doi:10.1002/pola.28595

research product

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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LSLife Sciences
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