0000000001287449
AUTHOR
T. Beweries
Intermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt)
In the crystal structure of the isostructural title compounds, namely {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridopalladium(II), [Pd(C22H39O3P2)Cl], 1, and {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridoplatinum(II), [Pt(C22H39O3P2)Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an interaction of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand. © 2019.
CCDC 1435030: Experimental Crystal Structure Determination
Related Article: C. Godemann, A. Spannenberg, T. Beweries|2015|Acta Crystallogr.,Sect.E:Cryst.Commun.|71|o921|doi:10.1107/S2056989015020897
CCDC 1033917: Experimental Crystal Structure Determination
Related Article: L. Dura, A. Spannenberg, T. Beweries|2014|Acta Crystallogr.,Sect.E:Struct.Rep.Online|70|533|doi:10.1107/S1600536814024908