Author: Jens Oberkofler

0000000001288441

AUTHOR

Jens Oberkofler

showing 6 related works from this author

Exploring the Reactivity and Biological Effects of Heteroleptic N-Heterocyclic Carbene Gold(I)- Alkynyl Complexes

2020

With the aim to explore the effects of different organometallic ligands on the reactivity and biological properties of a series of twelve heteroleptic AuI complexes, of general formula [Au(NHC)(alkynyl)] (NHC = benzimidazolylidene or 1,3-dihydroimidazolylidene) were synthesized and characterized by 1H and 13C NMR and elemental analysis, and in some cases also by X-ray diffraction. The compounds were all stable in H2O/DMSO as established by NMR spectroscopy, while they could react with model thiols (EtSH) in the presence of water to undergo ligand-substitution reactions. 1H NMR experiments showed that dissociation of the more labile alkynyl ligand was possible for all compounds, while in the…

Antitumor agentsAlkyne ligands010405 organic chemistryNuclear magnetic resonance spectroscopy010402 general chemistryG-quadruplexG-quadruplexes01 natural sciencesMedicinal chemistryddc:0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundThiolschemistryReactivity (chemistry)GoldN-heterocyclic carbenesCarbeneDNAEuropean Journal of Inorganic Chemistry

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CCDC 1955879: Experimental Crystal Structure Determination

2020

Related Article: Jens Oberkofler, Brech Aikman, Riccardo Bonsignore, Alexander Pöthig, James Platts, Angela Casini, Fritz E. Kühn|2020|Eur.J.Inorg.Chem.|2020|1040|doi:10.1002/ejic.201901043

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(33-dimethylbut-1-yn-1-yl)-[13-di-isopropylbenzimidazol-2-ylidene]-gold(i)Experimental 3D Coordinates

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CCDC 1955877: Experimental Crystal Structure Determination

2020

Related Article: Jens Oberkofler, Brech Aikman, Riccardo Bonsignore, Alexander Pöthig, James Platts, Angela Casini, Fritz E. Kühn|2020|Eur.J.Inorg.Chem.|2020|1040|doi:10.1002/ejic.201901043

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[13-di-isopropylbenzimidazol-2-ylidene]-[naphthalen-1-ylethynyl]-gold(i)Experimental 3D Coordinates

researchProduct

CCDC 1955875: Experimental Crystal Structure Determination

2020

Related Article: Jens Oberkofler, Brech Aikman, Riccardo Bonsignore, Alexander Pöthig, James Platts, Angela Casini, Fritz E. Kühn|2020|Eur.J.Inorg.Chem.|2020|1040|doi:10.1002/ejic.201901043

Space GroupCrystallographyCrystal System(13-dimethylbenzimidazol-2-ylidene)-[(naphthalen-1-yl)ethynyl]-gold(i)Crystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1955876: Experimental Crystal Structure Determination

2020

Related Article: Jens Oberkofler, Brech Aikman, Riccardo Bonsignore, Alexander Pöthig, James Platts, Angela Casini, Fritz E. Kühn|2020|Eur.J.Inorg.Chem.|2020|1040|doi:10.1002/ejic.201901043

Space GroupCrystallography[13-dimesitylimidazol-2-ylidene]-[(naphthalen-1-yl)ethynyl]-gold(i)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1955878: Experimental Crystal Structure Determination

2020

Related Article: Jens Oberkofler, Brech Aikman, Riccardo Bonsignore, Alexander Pöthig, James Platts, Angela Casini, Fritz E. Kühn|2020|Eur.J.Inorg.Chem.|2020|1040|doi:10.1002/ejic.201901043

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[13-dimesitylimidazol-2-ylidene]-(33-dimethylbut-1-yn-1-yl)-gold benzene solvateExperimental 3D Coordinates

researchProduct

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