0000000001293385

AUTHOR

Antonin Jaillet

showing 20 related works from this author

Design of P-Chirogenic Aminophosphine-Phosphinite Ligands at Both Phosphorus Centers: Origin of Enantioselectivities in Pd-Catalyzed Allylic Reaction…

2020

International audience; We have recently patented an unprecedented stereospecific N→O phosphinyl migration process which transforms P-chirogenic aminophosphines into phosphinites. A fine design of aminophosphine phosphinite ligands (AMPP*) derived from ephedrine and bearing a P-chirogenic center either at the aminophosphine or phosphinite moiety, was performed. The synthesis of AMPP* ligands with P-chirogenic aminophosphine moiety was based on the well-established stereospecific reaction of oxazaphospholidine-borane with organolithium reagents, followed by trapping with a chlorophosphine and borane decomplexation. Concurrently, the preparation of AMPP* ligands with P-chirogenic phosphinite …

Allylic rearrangementPhosphinite010405 organic chemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryOrganic ChemistryDABCOBorane010402 general chemistry01 natural sciencesMedicinal chemistry0104 chemical scienceschemistry.chemical_compoundStereospecificityNucleophilechemistryMoiety[CHIM]Chemical SciencesConformational isomerismThe Journal of organic chemistry
researchProduct

CCDC 1982653: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(t-butyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982657: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(p-tolyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982651: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographydichloro-{2-[(diphenylphosphino)(methyl)amino]-1-phenylpropyl naphthalen-1-yl(phenyl)phosphinite}-palladium unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982662: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-((naphthalenyl)(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982660: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(o-tolyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982650: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-(2-{[ferrocenyl(phenyl)phosphino](methyl)amino}-1-phenylpropyl diphenylphosphinite)-palladium dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1982668: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

N-Methyl((1S2R)-(2-hydroxy-1-methyl-2-phenyl)ethyl)amino-t-butyl(phenyl)phosphineboraneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982669: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

N-Methyl((2-hydroxy-1-methyl-2-phenyl)ethyl)amino-(11'-binaphthalen-2-yl)(phenyl)phosphineboraneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982665: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-((biphenyl-2-yl)phenyl(trihydridoborato)phosphonio)-O-((trihydridoborato)diphenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982667: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesN-methyl((1R2S)-(2-hydroxy-1-methyl-2-phenyl)ethyl)amino-phenyl(p-tolyl)phosphineborane
researchProduct

CCDC 1982663: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-((biphenyl-2-yl)phenyl(trihydridoborato)phosphonio)-O-((trihydridoborato)diphenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982654: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal Structure(2-{[([11'-biphenyl]-2-yl)(phenyl)phosphino](methyl)amino}-1-phenylpropyl diphenylphosphinite)-dichloro-palladiumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982658: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyN-(diphenyl(trihydridoborato)phosphonio)-O-((biphenyl-2-yl)(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982659: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyN-(diphenyl(trihydridoborato)phosphonio)-O-((naphthalen-2-yl)(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolate cyclohexane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982666: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyN-((ferrocenyl)phenyl(trihydridoborato)phosphonio)-O-((trihydridoborato)diphenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982661: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyN-(diphenyl(trihydridoborato)phosphonio)-O-((2-methoxyphenyl)(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982664: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureN-((2-methoxyphenyl)phenyl(trihydridoborato)phosphonio)-O-((trihydridoborato)(2-methoxyphenyl)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1982656: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(diphenyl(trihydridoborato)phosphonio)-O-(o-tolyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateExperimental 3D Coordinates
researchProduct

CCDC 1982652: Experimental Crystal Structure Determination

2023

Related Article: Antonin Jaillet, Christophe Darcel, Jérôme Bayardon, Adrien Schlachter, Christine Salomon, Yoann Rousselin, Pierre Harvey, Sylvain Jugé|2020|J.Org.Chem.|85|14391|doi:10.1021/acs.joc.0c00536

Space GroupCrystallographyCrystal SystemN-(diphenyl(trihydridoborato)phosphonio)-O-(ferrocenyl(trihydridoborato)phenylphosphonio)-N-methyl-2-amino-1-phenylpropanolateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct