Author: Anton A. Yakimanskiy

0000000001297480

AUTHOR

Anton A. Yakimanskiy

showing 8 related works from this author

Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Stru…

2016

Coupling of the palladium-bis(isocyanide) complexes cis-[PdCl2(CNR)2] (R = 2,6-Me2C6H3 1, 2-Cl-6-MeC6H3 2) with benzene-1,3-diamine (BDA1) leads to the diaminocarbene species cis-[PdCl2(CNR){C(NHR)═NH(1,3-C6H4NH2)}] (5 and 6, respectively). In this reaction, BDA1 behaves as a monofunctional nucleophile that adds to one of the RNC ligands by one amino group. By contrast, the reaction of 1 and 2 with benzene-1,4-diamine (BDA2) involves both amino functionalities of the diamine and leads to the binuclear species [cis-PdCl2(CNR){μ-C(NHR)═NH(1,4-C6H4)NH═C(NHR)}-(cis)-PdCl2(CNR)] (6 and 7) featuring two 1,4-bifunctional diaminocarbene ligands. The reaction of cis-[PdCl2(CNR)2] (R = cyclohexyl 3) …

benzenediamines010405 organic chemistryStereochemistryIsocyanideOrganic Chemistrychemistry.chemical_elementdiaminocarbenespalladium complexes010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryNucleophileDiamineisomersPhysical and Theoretical ChemistryCarbeneta116PalladiumOrganometallics

researchProduct

CCDC 1435501: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis((2-Amino-45-dimethylphenylamino)(2-chloro-6-methylphenylamino)methylidene-CN)-palladium(ii) dichloride acetonitrile solvateExperimental 3D Coordinates

researchProduct

CCDC 1435504: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates((2-Amino-45-dimethylphenylamino)(2-chloro-6-methylphenylamino)methylidene-CN)-chloro-(N-(2-chloro-6-methylphenyl)cyano)-palladium(ii) chloride dichloromethane solvate

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CCDC 1435506: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-((3-aminophenyl)(26-dimethylphenylamino)methylidene)-(N-(26-dimethylphenyl)cyano)-palladium(ii)Experimental 3D Coordinates

researchProduct

CCDC 1435500: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal System(mu2-NN'-bis(((2-Chloro-6-methylphenyl)amino)methylidene)benzene-14-diamine)-tetrachloro-bis((2-chloro-6-methylphenyl)isocyano)-di-palladium(ii) chloroform solvateCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1435503: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NN'-bis(((2-Chloro-6-methylphenyl)amino)methylidene)-45-dichlorobenzene-12-diamine)-dichloro-palladium(ii) acetonitrile solvateExperimental 3D Coordinates

researchProduct

CCDC 1435502: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

(NN'-bis(((2-Chloro-6-methylphenyl)amino)methylidene)-45-dimethylbenzene-12-diamine)-dichloro-palladium(ii) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1435505: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters((2-Amino-45-dichlorophenylamino)(2-chloro-6-methylphenylamino)methylidene-CN)-chloro-((2-chloro-6-methylphenyl)isocyano)-palladium(ii) chloride dichloromethane solvateExperimental 3D Coordinates

researchProduct

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  - SH7_3Population dynamics: households, family and fertility
  - SH7_5Sustainability sciences, environment and resources, ecosystem services
  - SH7_4Social aspects of health, ageing and society
  - SH7_6Environmental and climate change, societal impact and policy
  - SH7_7Cities; urban, regional and rural studies
  - SH7_8Land use and planning
  - SH7_10GIS, spatial analysis; digital geography
  - SH7_9Energy, transportation and mobility
- SH8Studies of Cultures and Arts
  - SH8_1Kinship; diversity and identities, gender, interethnic relations
  - SH8_2Religious studies, ritual; symbolic representation
  - SH8_3Cultural studies and theory, cultural identities and memories, cultural heritage
  - SH8_4Museums, exhibitions, conservation and restoration
  - SH8_5History of art and of architecture
  - SH8_6Architecture, design, craft, creative industries
  - SH8_7Music and musicology; history of music
  - SH8_8Visual and performing arts, screen, arts-based research
  - SH8_9Digital approaches to anthropology, cultural studies and art