0000000001298813

AUTHOR

Alexander N. Chernyshev

showing 33 related works from this author

Weak intermolecular interactions promote blue luminescence of protonated 2,2′-dipyridylamine salts

2014

In this work we demonstrate that protonation and π-stacking can be exploited to convert non-luminescent 2,2′-dipyridylamine into blue-emitting derivatives. We have synthesized a series of luminescent 2,2′-dipyridylamine (dpa) salts, i.e., (dpaH)X·nSolv (dpa = 2,2′-dipyridylamine, X = HF2, n = 0.5, Solv = H2O 1; X = Cl, n = 2, Solv = H2O 2; X = Br, n = 2, Solv = H2O 3; X = I n = 1, Solv = H2O 4a; X = I n = 1, Solv = CHCl34b), (dpaH)2[SiF6]·H2O 5 and (dpaH)X (X = I36; SbF67; BF48) and characterized their emission properties, both in the solid-state and in solution. To rationalize our observations and relate the luminescence properties to the structure in the solid state and in solution, we ha…

Steric effectsChemistryHydrogen bondIntermolecular forceSolid-stateProtonationGeneral ChemistryConical intersectionCrystallographyComputational chemistryMaterials ChemistryAb initio computationsLuminescenceta116J. Mater. Chem. C
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Two complexes of Pt(IV) and Au(III) with 2,2'-dipyridylamine and 2,2'-dipyridylaminide ligands

2014

Two noble metal complexes involving ancillary chloride ligands and chelating 2,2′-bipyridylamine (Hdpa) or its deprotonated derivative (dpa), namely [bis(pyridin-2-yl-κN)amine]tetrachloridoplatinum(IV), [PtCl4(C10H9N3)], and [bis(pyridin-2-yl-κN)aminido]dichloridogold(III), [AuCl2(C10H8N3)], are presented and structurally characterized. The metal atom in the former has a slightly distorted octahedral coordination environment, formed by four chloride ligands and two pyridyl N atoms of Hdpa, while the metal atom in the latter has a slightly distorted square-planar coordination environment, formed by two chloride ligands and two pyridyl N atoms of dpa. The difference in conjugation between the…

StereochemistrySupramolecular chemistryCrystal structureCondensed Matter PhysicsChlorideInorganic Chemistrychemistry.chemical_compoundCrystallographyDeprotonationchemistryOctahedronPyridineMaterials ChemistrymedicineChelationPhysical and Theoretical Chemistryta116Derivative (chemistry)medicine.drugActa Crystallographica. Section C: Structural Chemistry
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Reactions of platinum(iv)-bound nitriles with isomeric nitroanilines: addition vs. substitution

2012

The platinum(IV) complex trans-[PtCl(4)(EtCN)(2)] reacts smoothly and under mild conditions with isomeric o-, m- and p-nitroanilines (NAs) yielding two different types of products depending on the NA isomer, viz. the nitroaniline complexes cis/trans-[PtCl(4)(NA)(2)] (cis/trans-1-3) and the amidine species trans-[PtCl(4){NH=C(Et)NHC(6)H(4)NO(2)-m}(EtCN)] (4), trans-[PtCl(4){NH=C(Et)NHC(6)H(4)NO(2)-m}(2)] (5) and trans-[PtCl(4){NH=C(Et)NHC(6)H(4)NO(2)-p}(EtCN)] (6). Complexes 4 and 5 undergo cyclometalation, furnishing mer-[PtCl(3){NH=C(Et)NHC(6)H(3)NO(2)-m}(EtCN)] (7) and mer-[PtCl(3){NH=C(Et)NHC(6)H(4)NO(2)-m}{NH=C(Et)NHC(6)H(3)NO(2)-m}] (8), respectively. Moreover, 8 both in the solid stat…

Aniline CompoundsNucleophilic additionOrganoplatinum CompoundsNitrileLigandStereochemistrySolid-statechemistry.chemical_elementMedicinal chemistryNitroanilineInorganic ChemistryAmidinechemistry.chemical_compoundIsomerismchemistryNitrilesMethanolPlatinumta116PlatinumDalton Transactions
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Intermolecular hydrogen bonding H···Cl− in the solid palladium(II)-diaminocarbene complexes

2017

Abstract Weak intermolecular non-covalent H···Cl− interactions in the solid chelated palladium(II)-diaminocarbene complex cis-[PdCl(CNXyl){C(NHXyl)=NHC6H2Me2 NH2}]Cl (3; Xyl=2,6-Me2C6H3) were studied by XRD followed by appropriate DFT calculations. The N–H···Cl contacts for both NH groups in the carbene moiety are different (N1–H···Cl2 3.5258(19), N2–H···Cl2 3.0797(17) Å). The DFT calculations and topological analysis of the electron density distribution within the formalism of Bader’s theory (QTAIM method) were performed for a model cluster of the carbene complex 3. The theoretical data confirmed that the strength of intermolecular HB H···Cl− is different for two NH-protons of the carbene …

Materials science010405 organic chemistryHydrogen bondIntermolecular forcechemistry.chemical_element010402 general chemistryCondensed Matter PhysicsPhotochemistry01 natural sciences0104 chemical sciencesInorganic ChemistrychemistryGeneral Materials SciencePalladiumZeitschrift für Kristallographie - Crystalline Materials
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Weak aurophilic interactions in a series of Au(III) double salts.

2015

In this work, several new examples of rare AuIII⋯AuIII aurophilic contacts are reported. A series of gold(III) double salts and complexes, viz. [AuX2(L)][AuX4] (L = 2,2′-bipyridyl, X = Cl 1, Br 2; L = 2,2′-bipyrimidine, X = Cl 3, Br 4; L = 2,2′-dipyridylamine, X = Cl 5, Br 6), [AuX3(biq)] (biq = 2,2′-biquinoline, X = Cl 7, Br 8), [LH][AuX4] (L = 2,2′-bipyridyl, X = Cl 9; L = 2,2′-bipyrimidine, X = Cl 12; L = 2,2′-dipyridylamine, X = Cl 14, Br 15; L = 2,2′-biquinoline, X = Cl 17, Br 18), [AuBr2(bpy)]2[AuBr4][AuBr2] 10, [AuCl2(bpm)][AuCl2] 11, (bpmH)2[AuBr4][AuBr2] 13, and (dpaH)[AuBr2] 16 (1, 2, and 7 were reported earlier) was synthesized by coordination of a particular ligand to the AuIII …

Series (mathematics)ChemistryLigandAtoms in moleculesstructural dataAurophilicityInorganic ChemistryMetalsymbols.namesakeCrystallographygold complexesComputational chemistryvisual_artDensity analysisvisual_art.visual_art_mediumsymbolsMoleculeVan der Waals radiusgold double saltsta116aurophilic interactionsDalton transactions (Cambridge, England : 2003)
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CCDC 1029115: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal Structure(22'-bipyrimidine)-dichloro-gold dichloro-goldCell ParametersExperimental 3D Coordinates
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CCDC 1029120: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemN-(pyridin-2-yl)pyridin-2-aminium dibromo-gold(i)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1004968: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates2-(pyridin-1-ylamino)pyridinium chloride dihydrate
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CCDC 1029124: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal System(22'-bipyrimidine)-dichloro-gold tetrachloro-goldCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1029116: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

2-(pyrimidin-2-yl)pyrimidin-1-ium tetrachloro-gold(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1513981: Experimental Crystal Structure Determination

2018

Related Article: Mikhail A. Kinzhalov, Alexander S. Novikov, Alexander N. Chernyshev and Vitalii V. Suslonov|2017|Z.Kristallogr.|232|299|doi:10.1515/zkri-2016-2018

Space GroupCrystallographyCrystal System((2-amino-45-dimethylanilino)(26-dimethylanilino)methylidene)-(2-isocyano-13-dimethylbenzene)-chloro-palladium(ii) chloride dichloromethane solvate monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1029121: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal System2-(quinolin-2-yl)quinolinium tetrachloro-gold(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1004967: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-(pyridin-1-ylamino)pyridinium hydrogen difluoride hemihydrateExperimental 3D Coordinates
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CCDC 1029126: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographydichloro-(N-(pyridin-2-yl)pyridin-2-amine)-gold tetrachloro-gold acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1004972: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallography2-(pyridin-1-ylamino)pyridinium iodide chloroform solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1029123: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(22'-bipyrimidine)-dichloro-gold dichloro-(2-(pyrazin-2-yl)pyrimidine)-gold tetrachloro-goldExperimental 3D Coordinates
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CCDC 1029114: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal Structurebis((22'-bipyridine)-dibromo-gold) dibromo-gold tetrabromo-goldCell ParametersExperimental 3D Coordinates
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CCDC 1004969: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-(pyridin-1-ylamino)pyridinium bromide dihydrateExperimental 3D Coordinates
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CCDC 1004974: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(2-(pyridin-1-ylamino)pyridinium) hexafluorosilicate dihydrateExperimental 3D Coordinates
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CCDC 1029122: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

2-(quinolin-2-yl)quinolinium tetrabromo-gold(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1004971: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallography2-(pyridin-1-ylamino)pyridinium iodide chloroform solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1004975: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal Structure2-(pyridin-1-ylamino)pyridinium triiodideCell ParametersExperimental 3D Coordinates
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CCDC 1407541: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdibromo-(N-(pyridin-2-yl)pyridin-2-amine)-gold tetrabromo-goldExperimental 3D Coordinates
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CCDC 1029128: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(22'-biquinoline)-trichloro-gold(iii)Experimental 3D Coordinates
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CCDC 1029117: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(2-(pyrimidin-2-yl)pyrimidin-1-ium) tetra-bromo-gold dibromo-goldExperimental 3D Coordinates
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CCDC 1004970: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-(pyridin-1-ylamino)pyridinium iodide monohydrateExperimental 3D Coordinates
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CCDC 1029119: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(pyridin-2-yl)pyridin-2-aminium tetrabromo-(iii)Experimental 3D Coordinates
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CCDC 1004973: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(2-(pyridin-1-ylamino)pyridinium) hexafluorosilicate dihydrateExperimental 3D Coordinates
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CCDC 1029113: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(22'-bipyridine)-dichloro-gold tetrachloro-goldExperimental 3D Coordinates
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CCDC 1029118: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyN-(pyridin-2-yl)pyridin-2-aminium tetrachloro-gold(iii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1004976: Experimental Crystal Structure Determination

2014

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

2-(pyridin-1-ylamino)pyridinium tetrafluoroborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1029125: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

(22'-bipyrimidine)-dibromo-gold tetrabromo-goldSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1029127: Experimental Crystal Structure Determination

2015

Related Article: Alexander N. Chernyshev, Maria V. Chernysheva, Pipsa Hirva, Vadim Yu. Kukushkin, Matti Haukka|2015|Dalton Trans.|44|14523|doi:10.1039/C4DT03167A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(22'-biquinoline)-trichloro-goldExperimental 3D Coordinates
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