0000000001298870

AUTHOR

Carsten Bolm

showing 71 related works from this author

5-Carbonyl-1,3-oxazine-2,4-diones from N-Cyanosulfoximines and Meldrum’s Acid Derivatives

2020

At elevated temperatures, N-cyanosulfoximines react with Meldrum's acid derivatives to give sulfoximines with N-bound 5-carbonyl-1,3-oxazine-2,4-dione groups. A representative product was characterized by single-crystal X-ray structure analysis. The product formation involves an unexpected molecular reorientation requiring several sequential bond-forming and -cleaving processes.

Structure analysis010405 organic chemistryOrganic Chemistry010402 general chemistryMeldrum's acid01 natural sciencesBiochemistry0104 chemical scienceschemistry.chemical_compoundchemistryProduct (mathematics)Organic chemistryProduct formationPhysical and Theoretical ChemistryOrganic Letters
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N-(2,3,5,6-Tetrafluoropyridyl)sulfoximines: synthesis, X-ray crystallography, and halogen bonding

2020

In the presence of KOH, NH-sulfoximines react with pentafluoropyridine to give N-(tetrafluoropyridyl)sulfoximines (NTFP-sulfoximines) in moderate to excellent yields. Either a solution-based or a superior solvent-free mechanochemical protocol can be followed. X-Ray diffraction analyses of 26 products provided insight into the bond parameters and conformational rigidity of the molecular scaffold. In solid-state structures, sulfoximines with halo substituents on the S-bound arene are intermolecularly linked by C–X⋯OS (X = Cl, Br) halogen bonds. Hirshfeld surface analysis is used to assess the type of non-covalent contacts present in molecules. For mixtures of three different S-pyridyl-substit…

1h nmr spectroscopyHalogen bond010405 organic chemistryChemistryOrganic Chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesNitrogenOxygen0104 chemical sciencesCrystallographyHalogenX-ray crystallographyMoleculeOrganic Chemistry Frontiers
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Regio- and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light

2021

Advanced synthesis & catalysis 2552-2556 (2021). doi:10.1002/adsc.202100162

copper catalysisvinyl sulfoximine660StereochemistryAryldifunctionalizationchemistry.chemical_elementGeneral Chemistryalkyne additionCoppervisible-light photoredox catalysisCatalysischemistry.chemical_compoundTerminal (electronics)chemistryddc:660StereoselectivityVisible spectrum
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1,2,6-Thiadiazine 1-Oxides: Unsaturated Three-Dimensional S,N-Heterocycles from Sulfonimidamides.

2020

Unprecedented three-dimensional 1,2,6-thiadiazine 1-oxides have been prepared by an aza-Michael-addition/cyclization/condensation reaction sequence starting from sulfonimidamides and propargyl ketones. The products have been further functionalized by standard cross-coupling reactions, selective bromination of the heterocyclic ring, and conversion into a β-hydroxy substituted derivative. A representative product was characterized by single-crystal X-ray structure analysis. peerReviewed

sulfonimidamidessingle-crystal X-raybioaktiiviset yhdisteet010405 organic chemistryStereochemistryChemistryOrganic ChemistryOxideHalogenation010402 general chemistryCondensation reaction01 natural sciencesBiochemistryCoupling reaction0104 chemical scienceschemistry.chemical_compoundPropargylPhysical and Theoretical ChemistrySequence (medicine)Organic letters
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The Preparation of Diaryl Sulfoxonium Triflates and Their Application in Palladium‐Catalyzed Cross‐Coupling Reactions

2022

Chemistry 17(19), e202200828 (2022). doi:10.1002/asia.202200828

sulfoxinium660Molecular StructuresulfoximinekemiaOrganic ChemistryGeneral ChemistryBiochemistryCatalysisonium salttriflateddc:660SaltsPalladiumcoupling reaction
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A copper-catalyzed interrupted domino reaction for the synthesis of fused triazolyl benzothiadiazine-1-oxides

2023

Chemistry - a European journal 29(13), e202203729 (2023). doi:10.1002/chem.202203729

kemiallinen synteesikatalyysiddc:540Organic ChemistrykupariGeneral Chemistryheterosykliset yhdisteet540Catalysis
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1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Condit…

2021

Advanced synthesis & catalysis (2021). doi:10.1002/adsc.202001505 special issue: "Hot Topic: C-H Activation"

Annulationkemiallinen synteesiSolvent free660iridium catalysisChemistrysulfonimidamideGeneral ChemistryBenzothiazine12-benzothiazineC−H activationCatalysisMetalchemistry.chemical_compoundMechanochemistryvisual_artkatalyysirikkiyhdisteetddc:660visual_art.visual_art_mediumrhodium catalysisOrganic chemistrymechanochemistryorgaaniset yhdisteet
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2,3-Dihydro-1,2,6-thiadiazine 1-Oxides by Biginelli-Type Reactions with Sulfonimidamides under Mechanochemical Conditions.

2021

Biginelli-type multicomponent reactions (MCRs) with NH-free sulfonimidamides provide 2,3-dihydro-1,2,6-thiadiazine 1-oxides in high yields. The couplings are performed in a planetary ball mill under solvent-free mechanochemical conditions. Acetic acid or ytterbium triflate are used as catalysts. A representative product was characterized by X-ray single crystal structure analysis revealing molecular details of the highly functionalized three-dimensional heterocycle. Further product modifications lead to additional structural scaffolds.

YtterbiumStructure analysis010405 organic chemistryChemistryOrganic Chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesBiochemistryCombinatorial chemistry0104 chemical sciencesCatalysisAcetic acidchemistry.chemical_compoundPhysical and Theoretical ChemistrySingle crystalBall millTrifluoromethanesulfonateOrganic letters
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Synthesis of trifluoromethyl-substituted 1,2,6-thiadiazine 1-oxides from sulfonimidamides under mechanochemical conditions

2021

TBS-protected or NH-sulfonimidamides react with β-alkoxyvinyl trifluoromethylketones under solvent-free mechanochemical conditions to give 3-trifluoromethyl-substituted three-dimensional 1,2,6-thiadiazine 1-oxides. C4-Functionalized products can be obtained by starting from cyclic enones and brominations of the initially formed heterocycles. The stability of the products was investigated by varying the pH value and storage under aerobic conditions.

chemistry.chemical_compoundTrifluoromethylChemistryOrganic ChemistryOrganic chemistryPhysical and Theoretical ChemistryBiochemistryValue (mathematics)Organic & Biomolecular Chemistry
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From One-Pot NH-Sulfoximidations of Thiophene Derivatives to Dithienylethene-Type Photoswitches

2019

Thiophene NH-sulfoximines have been synthesized using a one-pot NH-sulfoximidation reaction of thiophenes. The reactivity of the products was investigated, and the developed protocols were used for the synthesis of a new class of dithienylethene-type photoswitches containing a sulfoximidoyl group.

chemistry.chemical_compoundchemistry010405 organic chemistryOrganic ChemistryThiopheneOrganic chemistryReactivity (chemistry)Physical and Theoretical Chemistry010402 general chemistry01 natural sciencesBiochemistryThiophene derivatives0104 chemical sciencesOrganic Letters
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Mechanochemical Syntheses of N-Containing Heterocycles with TosMIC

2021

A mechanochemical van Leusen pyrrole synthesis with a base leads to 3,4-disubstitued pyrroles in moderate to excellent yields. The developed protocol is compatible with a range of electron-withdrawing groups and can also be applied to the synthesis of oxazoles. Attempts to mechanochemically convert the resulting pyrroles into porphyrins proved to be difficult.

chemistry.chemical_compoundchemistryOrganic ChemistryTosMICCombinatorial chemistryPyrroleThe Journal of Organic Chemistry
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Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur

2023

Copper-catalyzed cross-coupling reactions of α-bromoaryl NH-sulfoximines with elemental sulfur lead to benzo[d][1,3,2]dithiazole-1-oxides, which represent a new class of three-dimensional heterocycles. The reactions proceed under mild conditions showing good functional group and heterocycle tolerance. By imination/oxidation, the initial cross-coupling products can be converted to unprecedented cyclic sulfonimidamides derivatives. Furthermore, a seven-membered heterocycle was obtained by a ruthenium-catalyzed ring-expansion with ethyl propiolate. peerReviewed

kemiallinen synteesicopper catalysissulfonimidamideskatalyytitcross-coupling reactionssulfoximineskatalyysirikkiyhdisteetkupariGeneral Chemistryheterosykliset yhdisteetrikkielemental sulfurAdvanced Synthesis & Catalysis
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Syntheses of Trifluoroethylated N-Heterocycles from Vinyl Azides and Togni’s Reagent Involving 1,n-Hydrogen-Atom Transfer Reactions

2020

2,2,2-Trifluoroethyl-substituted 3-oxazolines, 3-thiazolines, and 5,6-dihydro-2H-1,3-oxazines have been obtained by reacting substituted vinyl azides with a combination of Togni’s reagent and substoichiometric amounts of iron(II) chloride. The results of density functional theory calculations support the proposed mechanism involving 1,n-hydrogen-atom transfer reactions. peerReviewed

eetteritenergia010405 organic chemistryChemistryOrganic ChemistryreagentsHydrogen atom010402 general chemistry01 natural sciencesBiochemistryChloride0104 chemical sciencesetherssubstituentsReagentredox reactionsPolymer chemistryreagenssitmedicineDensity functional theoryPhysical and Theoretical Chemistryenergymedicine.drugOrganic Letters
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Synthesis of N‐Monosubstituted Sulfondiimines by Metal‐free Iminations of Sulfiliminium Salts

2023

Sulfondiimines are marginalized entities among nitrogencontaining organosulfur compounds, despite offering promising properties for applications in various fields including medicinal and agrochemical. Herein, we present a metal-free and rapid synthetic procedure for the synthesis of N-monosubstituted sulfondiimines that overcomes current limitations in their synthetic accessibility. Particularly, S,S-dialkyl substrates, which are commonly difficult to convert by existing methods, react well with a combination of iodine, 1,8-diazabicyclo[5.4.0]undec-7-en (DBU), and iminoiodanes (PhINR) in acetonitrile (MeCN) to furnish the corresponding sulfondiimines in yields up to 85% (25 examples). Valua…

kemiallinen synteesiiodineGeneral MedicineGeneral ChemistryrikkiCatalysisjodilääkekemiamedicinal chemistrysulfuriminationtyppiyhdisteetnitrenesulfondiimineorgaaniset yhdisteet
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2-Sulfoximidoyl Acetic Acids from Multicomponent Petasis Reactions and Their Use as Building Blocks in Syntheses of Sulfoximine Benzodiazepine Analog…

2021

Upon application of a multicomponent Petasis reaction, a broad range of NH-sulfoximines and boronic acids react with glyoxalic acid to afford the corresponding 2-substituted acetic acids with N-bound sulfoximidoyl groups. The protocol features excellent yields under ambient, metal-free conditions and short reaction times. Furthermore, the applicability of 2-sulfoximidoyl acetic acids as building blocks for synthesizing sulfoximine-based benzodiazepine analogues was demonstrated.

BenzodiazepinePetasis reaction010405 organic chemistrymedicine.drug_classChemistryOrganic ChemistrymedicinePhysical and Theoretical Chemistry010402 general chemistry01 natural sciencesBiochemistryCombinatorial chemistry0104 chemical sciencesOrganic letters
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[3+2]‐Cycloadditions of N ‐Cyano Sulfoximines with 1,3‐Dipoles

2020

Involving the cyano group of N‐cyano sulfoximines in [3+2]‐cycloaddition reactions with 1,3‐dipoles provides practical routes for the construction of 5‐membered heterocycles bearing sulfoximinoyl moieties. An ytterbium‐catalyzed cycloaddition utilizing hydrazonoyl chlorides was developed, as well as a reaction involving imidoyl chlorides proceeding without the aid of a catalyst. Following these protocols, a range of sulfoximines with N‐1,2,4‐triazolyl and N‐1,2,4‐oxadiazolyl substituents was prepared. peerReviewed

betaiinisulfoximinebioaktiiviset yhdisteetOrganic ChemistryTriazoleOxadiazoleCycloadditiontriazolechemistry.chemical_compoundDipolechemistryPolymer chemistrybetaine13-dipolePhysical and Theoretical Chemistry13-dipolecycloadditionoxadiazoleorgaaniset yhdisteetEuropean Journal of Organic Chemistry
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Three-Dimensional Heterocycles by 5-exo-dig Cyclizations of S-Methyl-N-ynonylsulfoximines

2021

Upon treatment with Cs2CO3, S-methyl-N-ynonylsulfoximines undergo 5-exo-dig cyclizations to give three-dimensional heterocycles. The reactions proceed at ambient temperature with a wide range of substrates affording the corresponding products in good to excellent yields.

Range (particle radiation)ChemistryDigOrganic ChemistryPhysical and Theoretical ChemistryBiochemistryMedicinal chemistryOrganic Letters
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Revisiting the bromination of 3β-hydroxycholest-5-ene with CBr4/PPh3 and the subsequent azidolysis of the resulting bromide, disparity in stereochemi…

2023

Cholesterol reacts under Appel conditions (CBr4/PPh3) to give 3,5-cholestadiene (elimination) and 3β-bromocholest-5-ene (substitution with retention of configuration). Thus, the bromination of cholesterol deviates from the stereochemistry of the standard Appel mechanism due to participation of the Δ5 π-electrons. In contrast, the subsequent azidolysis (NaN3/DMF) of 3β-bromocholest-5-ene proceeds predominantly by Walden inversion (SN2) affording 3α-azidocholest-5-ene. The structures of all relevant products were revealed by X-ray single crystal structure analyses, and the NMR data are in agreement to the reported ones. In light of these findings, we herein correct the previous stereochemical…

crystal structurelääkkeetazidolysisAppel reactionkolesterolilääkehoitocholesterolWalden inversion
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5-Carbonyl-1,3-oxazine-2,4-diones from N-Cyanosulfoximines and Meldrum’s Acid Derivatives

2020

At elevated temperatures, N-cyanosulfoximines react with Meldrum’s acid derivatives to give sulfoximines with N-bound 5-carbonyl-1,3-oxazine-2,4-dione groups. A representative product was characterized by single-crystal X-ray structure analysis. The product formation involves an unexpected molecular reorientation requiring several sequential bond-forming and -cleaving processes. peerReviewed

crystal structurekemiallinen synteesicyclizationaddition reactionskemialliset reaktiotreaction productsrikkiyhdisteetchemical reactionstyppiyhdisteetorgaaniset yhdisteet
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N-(2,3,5,6-Tetrafluoropyridyl)sulfoximines : synthesis, X-ray crystallography, and halogen bonding

2020

In the presence of KOH, NH-sulfoximines react with pentafluoropyridine to give N-(tetrafluoropyridyl)sulfoximines (NTFP-sulfoximines) in moderate to excellent yields. Either a solution-based or a superior solvent-free mechanochemical protocol can be followed. X-Ray diffraction analyses of 26 products provided insight into the bond parameters and conformational rigidity of the molecular scaffold. In solid-state structures, sulfoximines with halo substituents on the S-bound arene are intermolecularly linked by C–X⋯O[double bond, length as m-dash]S (X = Cl, Br) halogen bonds. Hirshfeld surface analysis is used to assess the type of non-covalent contacts present in molecules. For mixtures of th…

kemiallinen synteesikemialliset sidoksetrikkiyhdisteettyppiyhdisteetorgaaniset yhdisteetröntgenkristallografia
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CCDC 2069302: Experimental Crystal Structure Determination

2021

Related Article: Renè Hommelsheim, Heliana Michaela Núñez Ponce, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2021|Org.Lett.|23|3415|doi:10.1021/acs.orglett.1c00874

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates[(5-oxo-5H-5-dibenzo[bd]thiophen-5-ylidene)amino](phenyl)acetic acid monohydrate
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CCDC 2169530: Experimental Crystal Structure Determination

2023

Related Article: Renè Hommelsheim, Sandra Bausch, Arjuna Selvakumar, Mostafa Amer, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2023|Chem.-Eur.J.|29|e202203729|doi:10.1002/chem.202203729

Space GroupCrystallography1-azido-2-(S-methanesulfonimidoyl)benzeneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2027290: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[methyl(oxo)(pyridin-2-yl)-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2069303: Experimental Crystal Structure Determination

2021

Related Article: Renè Hommelsheim, Heliana Michaela Núñez Ponce, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2021|Org.Lett.|23|3415|doi:10.1021/acs.orglett.1c00874

Space GroupCrystallographyCrystal System13-diphenyl-35-dihydro-4H-125-benzothiadiazepine-14-dioneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2027281: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography4-{[(2-bromophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2027279: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[(2-chlorophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
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CCDC 2169531: Experimental Crystal Structure Determination

2023

Related Article: Renè Hommelsheim, Sandra Bausch, Arjuna Selvakumar, Mostafa Amer, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2023|Chem.-Eur.J.|29|e202203729|doi:10.1002/chem.202203729

Space GroupCrystallography35-diphenyl-[123]triazolo[51-c][124]benzothiadiazin-5-oneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2242257: Experimental Crystal Structure Determination

2023

Related Article: Marco T. Passia, Niklas Bormann, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202305703

Space GroupCrystallographyCrystal SystemCrystal StructureN-[diethyl(imino)-sulfanylidene]-4-nitrobenzene-1-sulfonamideeCell ParametersExperimental 3D Coordinates
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CCDC 2027299: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates44'-{[S-benzene-N-(2356-tetrafluoropyridine-4-)sulfonimidoyl]methylene}bis(tetrafluoropyridine)
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CCDC 2027288: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2356-tetrafluoro-4-{[methyl(4-methylphenyl)oxo-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
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CCDC 2225023: Experimental Crystal Structure Determination

2023

Related Article: Peng Wu, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Adv.Synth.Catal.|365|522|doi:10.1002/adsc.202201408

Space GroupCrystallographyCrystal SystemCrystal Structure1-methyl-1lambda632-benzodithiazol-1-oneCell ParametersExperimental 3D Coordinates
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CCDC 2027300: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System4-[S-methane-N-(2356-tetrafluoropyridine-4-)sulfonimidoyl]-1lambda5-pyridine N-oxideCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2027289: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2356-tetrafluoro-4-{[methyl(4-nitrophenyl)oxo-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
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CCDC 2109381: Experimental Crystal Structure Determination

2021

Related Article: Marco Thomas Passia, Jan-Hendrik Sch��bel, Niklas Julian Lentelink, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2021|Org.Biomol.Chem.|19|9470|doi:10.1039/D1OB01912K

Space GroupCrystallographyCrystal System4-bromo-1-(4-methylphenyl)-3-(trifluoromethyl)-12-dihydro-1lambda626-thiadiazin-1-oneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2069304: Experimental Crystal Structure Determination

2021

Related Article: Renè Hommelsheim, Heliana Michaela Núñez Ponce, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2021|Org.Lett.|23|3415|doi:10.1021/acs.orglett.1c00874

Space GroupCrystallographyCrystal System13-diphenyl-35-dihydro-4H-125-benzothiadiazepine-14-dioneCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1985011: Experimental Crystal Structure Determination

2020

Related Article: Jan-Hendrik Schöbel, Marco Thomas Passia, Nadja Anna Wolter, Rakesh Puttreddy, Kari Rissanen, Carsten Bolm|2020|Org.Lett.|22|2702|doi:10.1021/acs.orglett.0c00666

Space GroupCrystallographyCrystal System3-t-butyl-1-(4-methylphenyl)-5-phenyl-12-dihydro-1lambda626-thiadiazin-1-oneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2027291: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography2356-tetrafluoro-4-{[methyl(oxo)(pyridin-3-yl)-lambda6-sulfanylidene]amino}pyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2242258: Experimental Crystal Structure Determination

2023

Related Article: Marco T. Passia, Niklas Bormann, Jas S. Ward, Kari Rissanen, Carsten Bolm|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202305703

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(234678910-octahydro-1H-pyrimido[12-a]azepin-5-ium) iodide triiodide iodineExperimental 3D Coordinates
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CCDC 2027295: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[benzyl(oxo)phenyl-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
researchProduct

CCDC 2027286: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[(2-methoxyphenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2034819: Experimental Crystal Structure Determination

2021

Related Article: Peng Shi, Yongliang Tu, Duo Zhang, Chenyang Wang, Khai‐Nghi Truong, Kari Rissanen, Carsten Bolm|2021|Adv.Synth.Catal.|363|2552|doi:10.1002/adsc.202100162

N-{[2-(4-t-butylphenyl)-2-chloroethenyl](oxo)phenyl-lambda6-sulfanyl}-4-methylbenzene-1-sulfonamideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2092466: Experimental Crystal Structure Determination

2021

Related Article: Christian Schumacher, Claude Molitor, Sabrina Smid, Khai-Nghi Truong, Kari Rissanen, Carsten Bolm|2021|J.Org.Chem.|86|14213|doi:10.1021/acs.joc.1c01529

Space GroupCrystallographyN-[(4-methylbenzene-1-sulfonyl)methyl]formamideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1894289: Experimental Crystal Structure Determination

2019

Related Article: Bram Verbelen, Eric Siemes, Andreas Ehnbom, Christoph Räuber, Kari Rissanen, Dominik Wöll, Carsten Bolm|2019|Org.Lett.|21|4293|doi:10.1021/acs.orglett.9b01475

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-amino-2-ethyl-3-[2-(2-ethyl-1-benzothiophen-3-yl)-334455-hexafluorocyclopent-1-en-1-yl]-1H-1-benzothiophen-1-oneExperimental 3D Coordinates
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CCDC 2027297: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[cyclopropyl(oxo)phenyl-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
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CCDC 2027322: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[cyclohexyl(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
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CCDC 2027278: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography2356-tetrafluoro-4-{[(4-fluorophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027296: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

4-{[ethyl(oxo)phenyl-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027285: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[(2-methoxyphenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027298: Experimental Crystal Structure Determination

2020

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CCDC 2027277: Experimental Crystal Structure Determination

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CCDC 1983428: Experimental Crystal Structure Determination

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CCDC 2027287: Experimental Crystal Structure Determination

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CCDC 2027282: Experimental Crystal Structure Determination

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CCDC 2027280: Experimental Crystal Structure Determination

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CCDC 2027294: Experimental Crystal Structure Determination

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CCDC 2062891: Experimental Crystal Structure Determination

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CCDC 2027276: Experimental Crystal Structure Determination

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CCDC 1993374: Experimental Crystal Structure Determination

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CCDC 2027283: Experimental Crystal Structure Determination

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CCDC 2169532: Experimental Crystal Structure Determination

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