0000000001298911

AUTHOR

M.a. Broda

Vibrational dephasing of νs(OH) in 2,6-dichloro-4-nitrophenol

Abstract A detailed analysis of the infrared bandshape of ν s (OH) in intramolecularly hydrogen-bonded 2,6-dichloro-4-nitrophenol in a series of solvents is presented. A distinct dependence of the bandshape and relaxation parameters on the polarity of solvent molecules has been found. The band shifts to lower wavenumbers, broadens and becomes more Gaussian with increasing solvent polarity; correspondingly, the correlation function decays faster and the correlation time decreases. The results are compared with those of previously studied systems. Factors determing the bandshape are discussed.

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CCDC 201795: Experimental Crystal Structure Determination

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CCDC 631807: Experimental Crystal Structure Determination

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CCDC 156947: Experimental Crystal Structure Determination

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CCDC 192133: Experimental Crystal Structure Determination

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CCDC 202883: Experimental Crystal Structure Determination

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