0000000001298911
AUTHOR
M.a. Broda
Vibrational dephasing of νs(OH) in 2,6-dichloro-4-nitrophenol
Abstract A detailed analysis of the infrared bandshape of ν s (OH) in intramolecularly hydrogen-bonded 2,6-dichloro-4-nitrophenol in a series of solvents is presented. A distinct dependence of the bandshape and relaxation parameters on the polarity of solvent molecules has been found. The band shifts to lower wavenumbers, broadens and becomes more Gaussian with increasing solvent polarity; correspondingly, the correlation function decays faster and the correlation time decreases. The results are compared with those of previously studied systems. Factors determing the bandshape are discussed.
CCDC 201795: Experimental Crystal Structure Determination
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CCDC 192134: Experimental Crystal Structure Determination
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CCDC 201796: Experimental Crystal Structure Determination
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CCDC 275068: Experimental Crystal Structure Determination
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CCDC 631807: Experimental Crystal Structure Determination
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CCDC 808030: Experimental Crystal Structure Determination
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CCDC 156947: Experimental Crystal Structure Determination
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CCDC 192133: Experimental Crystal Structure Determination
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CCDC 631805: Experimental Crystal Structure Determination
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CCDC 275069: Experimental Crystal Structure Determination
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CCDC 202882: Experimental Crystal Structure Determination
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CCDC 631806: Experimental Crystal Structure Determination
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CCDC 192132: Experimental Crystal Structure Determination
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CCDC 808031: Experimental Crystal Structure Determination
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CCDC 202883: Experimental Crystal Structure Determination
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CCDC 201794: Experimental Crystal Structure Determination
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