Author: Heike Hausmann

0000000001298993

AUTHOR

Heike Hausmann

showing 7 related works from this author

Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines

2016

International audience; Direct unequal C-H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phosphines. The prepared primary diamantyl phosphines are quite air stable compared to their adamantyl and especially alkyl or aryl analogues. This finding is corroborated by comparing the singly occupied molecular orbital energy levels of the corresponding phosphine radical cations obtained by density functional theory computations.

room-temperaturemolecular tripoddeactivated aryl chlorideshomogeneous catalysts010402 general chemistryDiamondoidselective preparationchemistry01 natural sciencesMedicinal chemistryChemical reaction[ CHIM ] Chemical Scienceschemistry.chemical_compoundOrganic chemistry[CHIM]Chemical SciencesarylationAlkylNanodiamonds ; Diamondoid Phosphines ; diamantane ; adamantane ; adamantylphosphinechemistry.chemical_classification010405 organic chemistryChemistryligandsArylOrganic Chemistrypalladiumphosphorylated adamantanes3. Good health0104 chemical sciencesChemical bondDensity functional theoryDiamantanePhosphine

researchProduct

Synthesis of tumor-associated MUC1-glycopeptides and their multivalent presentation by functionalized gold colloids

2014

The mucin MUC1 is a glycoprotein involved in fundamental biological processes, which can be found over-expressed and with a distinctly altered glycan pattern on epithelial tumor cells; thus it is a promising target structure in the quest for effective carbohydrate-based cancer vaccines and immunotherapeutics. Natural glycopeptide antigens indicate only a low immunogenicity and a T-cell independent immune response; however, this major drawback can be overcome by coupling of glycopeptide antigens multivalently to immunostimulating carrier platforms. In particular, gold nanoparticles are well suited as templates for the multivalent presentation of glycopeptide antigens, due to their remarkably…

Immunoassaychemistry.chemical_classificationGlycanbiologyImmunogenicityMucin-1Organic ChemistryGlycopeptidesChemistry Techniques SyntheticGold ColloidBiochemistryCombinatorial chemistryGlycopeptideImmobilized ProteinsImmune systemchemistryAntigenBiochemistryColloidal goldQuartz Crystal Microbalance Techniquesbiology.proteinPhysical and Theoretical ChemistryGlycoproteinMUC1Organic & Biomolecular Chemistry

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CCDC 1054568: Experimental Crystal Structure Determination

2016

Related Article: Oana Moncea, Maria A. Gunawan, Didier Poinsot, Hélène Cattey, Jonathan Becker, Raisa I. Yurchenko, Ekaterina D. Butova, Heike Hausmann, Marina Šekutor, Andrey A. Fokin, Jean-Cyrille Hierso, Peter R. Schreiner|2016|J.Org.Chem.|81|8759|doi:10.1021/acs.joc.6b01219

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersadamantan-1-yl(diphenyl)phosphine sulfideExperimental 3D Coordinates

researchProduct

CCDC 1054567: Experimental Crystal Structure Determination

2016

Related Article: Oana Moncea, Maria A. Gunawan, Didier Poinsot, Hélène Cattey, Jonathan Becker, Raisa I. Yurchenko, Ekaterina D. Butova, Heike Hausmann, Marina Šekutor, Andrey A. Fokin, Jean-Cyrille Hierso, Peter R. Schreiner|2016|J.Org.Chem.|81|8759|doi:10.1021/acs.joc.6b01219

Space GroupCrystallographyCrystal Systempentacyclo[7.3.1.1412.027.0611]tetradec-4-ylphosphonic dichlorideCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1054565: Experimental Crystal Structure Determination

2016

Related Article: Oana Moncea, Maria A. Gunawan, Didier Poinsot, Hélène Cattey, Jonathan Becker, Raisa I. Yurchenko, Ekaterina D. Butova, Heike Hausmann, Marina Šekutor, Andrey A. Fokin, Jean-Cyrille Hierso, Peter R. Schreiner|2016|J.Org.Chem.|81|8759|doi:10.1021/acs.joc.6b01219

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(9-chloropentacyclo[7.3.1.1412.027.0611]tetradec-4-yl)phosphonic dichlorideExperimental 3D Coordinates

researchProduct

CCDC 1054566: Experimental Crystal Structure Determination

2016

Related Article: Oana Moncea, Maria A. Gunawan, Didier Poinsot, Hélène Cattey, Jonathan Becker, Raisa I. Yurchenko, Ekaterina D. Butova, Heike Hausmann, Marina Šekutor, Andrey A. Fokin, Jean-Cyrille Hierso, Peter R. Schreiner|2016|J.Org.Chem.|81|8759|doi:10.1021/acs.joc.6b01219

Space GroupCrystallographyCrystal Systemadamantan-1-yl(diphenyl)phosphine oxideCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1054569: Experimental Crystal Structure Determination

2016

Related Article: Oana Moncea, Maria A. Gunawan, Didier Poinsot, Hélène Cattey, Jonathan Becker, Raisa I. Yurchenko, Ekaterina D. Butova, Heike Hausmann, Marina Šekutor, Andrey A. Fokin, Jean-Cyrille Hierso, Peter R. Schreiner|2016|J.Org.Chem.|81|8759|doi:10.1021/acs.joc.6b01219

Space GroupCrystallographyCrystal Systemtribenzyl(9-hydroxypentacyclo[7.3.1.1412.027.0611]tetradec-4-yl)phosphonium bromideCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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