Author: Simon Steike

0000000001299040

AUTHOR

Simon Steike

Di-, Tri-, and Tetra(pentafluorophenyl) Derivatives for Oligotopic Anion−π Interactions

The present study describes a series of pentafluorobenzyl ammonium salts with two, three, or four C6F5 units in order to investigate simultaneous interactions of several perfluorinated arenes with anions in the crystalline state. Most of the structures show multiple anion-π contacts. However, only 6·2HI reveals an effective encapsulation of the iodide ion by the aromatic units. For comparison, the structure of 4b is investigated because it offers two π-systems with inverse charge distribution to a bromide anion. Only the electron-deficient π-system of the pentafluorophenyl group interacts with the anion.

research product

CCDC 967090: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967091: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967092: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967093: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967097: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K

research product

CCDC 967088: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967089: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K

research product

CCDC 967095: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967096: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

CCDC 967094: Experimental Crystal Structure Determination

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

research product

PEPhysical Sciences and Engineering
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