Author: Heikki Laakkonen

0000000001299200

AUTHOR

Heikki Laakkonen

Aromaattiset amidifoldameerit

Pro gradu -tutkielman kirjallinen osa keskittyy aromaattisiin, amidisidoksellisiin foldameereihin ja erityisesti amidi-, imidi- ja hydratsidifoldameereihin. Synteesien ja menetelmien sijaan osuudessa on paneuduttu foldameerien laskostumiseen vaikuttaviin tekijöihin, kuten vetysidoksiin, kiraaliseen induktioon ja kompleksoitumiseen. Tämän lisäksi myös foldameerien solubiologista vuorovaikutusta on tuotu esiin. Kokeellinen osa keskittyy kahden aromaattisen amidifoldameerin synteeseihin ja niistä saatujen tuotteiden kiteyttämisiin ja kiderakenteisiin. Foldameerit laskostuivat testatuissa, polaarisissa liuottimissa ja muodostivat sekä intramolekulaarisia että intermolekulaarisia vetysidoksia. L…

research product

Structural Tuning and Conformational Stability of Aromatic Oligoamide Foldamers

A series of aromatic oligoamide foldamers with two or three pyridine-2,6-dicarboxamide units as their main folding motifs and varying aromatic building blocks as linkers have been synthetized to study the effects of the structural variation on the folding properties and conformational stability. Crystallographic studies showed that in the solid state the central linker unit either elongates the helices and more open S-shaped conformations, compresses the helices to more compact conformations or acts as a rigid spacer separating the pyridine-2,6-dicarboxamide units, which for their part add the predictability of the conformational properties. Multidimensional NMR studies showed that, even in…

research product

CCDC 1555247: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555255: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555258: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555253: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555260: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555245: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555251: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555256: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555244: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555248: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555250: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555259: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555249: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555254: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555252: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555257: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

CCDC 1555246: Experimental Crystal Structure Determination

Related Article: Riia Annala, Aku Suhonen, Heikki Laakkonen, Perttu Permi, Maija Nissinen|2017|Chem.-Eur.J.|23|16671|doi:10.1002/chem.201703985

research product

PEPhysical Sciences and Engineering
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  - SH7_1Human, economic and social geography
  - SH7_3Population dynamics: households, family and fertility
  - SH7_5Sustainability sciences, environment and resources, ecosystem services
  - SH7_4Social aspects of health, ageing and society
  - SH7_6Environmental and climate change, societal impact and policy
  - SH7_7Cities; urban, regional and rural studies
  - SH7_8Land use and planning
  - SH7_10GIS, spatial analysis; digital geography
  - SH7_9Energy, transportation and mobility
- SH8Studies of Cultures and Arts
  - SH8_1Kinship; diversity and identities, gender, interethnic relations
  - SH8_2Religious studies, ritual; symbolic representation
  - SH8_3Cultural studies and theory, cultural identities and memories, cultural heritage
  - SH8_4Museums, exhibitions, conservation and restoration
  - SH8_5History of art and of architecture
  - SH8_6Architecture, design, craft, creative industries
  - SH8_7Music and musicology; history of music
  - SH8_8Visual and performing arts, screen, arts-based research
  - SH8_9Digital approaches to anthropology, cultural studies and art