0000000001299380

AUTHOR

Simon Aldridge

showing 94 related works from this author

Arene C−H Activation at Aluminium(I): meta Selectivity Driven by the Electronics of S N Ar Chemistry

2020

The reactivity of the electron-rich anionic Al(I) ('aluminyl') compound K 2 [(NON)Al] 2 (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di- tert -butyl-9,9-dimethylxanthene) towards mono- and disubstituted arenes is reported. C-H activation chemistry with n -butylbenzene gives exclusively the product of activation at the arene meta position. Mechanistically, this transformation proceeds in a single step via a concerted Meisenheimer-type transition state. Selectivity is therefore based on similar electronic factors to classical S N Ar chemistry, which implies the destabilization of transition states featuring electron-donating groups in either the ortho or the para positions. In the cases of tolu…

010405 organic chemistryChemistryXyleneSubstituentGeneral Chemistry010402 general chemistry01 natural sciencesMedicinal chemistryTolueneCatalysisTransition state0104 chemical sciences3. Good healthchemistry.chemical_compoundMeta-Nucleophilic aromatic substitutionReactivity (chemistry)SelectivityAngewandte Chemie International Edition
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The Aluminyl Anion : A New Generation of Aluminium Nucleophile

2020

Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and laboratory-based reactions. Recently, a series of isolable aluminium(I) anions ('aluminyls') have been reported, which offer an alternative to this textbook description: these reagents behave as aluminium nucleophiles. This minireview covers the synthesis, structure and reactivity of aluminyl species reported to date, together with their associated metal complexes. The frontier orbitals of each of these species have been investigated using a common methodology to allow for a like-for-like comparison of their electronic structure a…

chemistry.chemical_elementElectronic structureorganometalliyhdisteet010402 general chemistryreaktiivisuus01 natural sciencesCatalysisMetalmain groupNucleophileAluminiumnucleophile organometallicReactivity (chemistry)Lewis acids and basesalumiini010405 organic chemistryaluminiumGeneral MedicineGeneral ChemistrykompleksiyhdisteetCombinatorial chemistry0104 chemical scienceschemistryReagentvisual_artElectrophilevisual_art.visual_art_mediumaluminylalumiiniyhdisteet
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Cooperative N–H bond activation by amido-Ge(ii) cations

2020

N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N-H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N…

010405 organic chemistryCarbazoleHydrogen bondCationic polymerizationchemistry.chemical_elementGermaniumSubstrate (electronics)010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryAmideAmine gas treatingCarbeneDalton Transactions
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Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation

2020

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl) structural characterization by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to the low coordinate nature of the nitrogen centre. The Al-N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of the substrate…

010405 organic chemistrySubstrate (chemistry)General Chemistry010402 general chemistry01 natural sciencesIsocyanateCatalysis3. Good health0104 chemical scienceschemistry.chemical_compoundchemistryChemical bondReagentPolymer chemistryMoleculeImideBond cleavageCarbon monoxide
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A nucleophilic gold complex.

2019

Solid-state auride salts featuring the negatively charged Au– ion are known to be stable in the presence of alkali metal counterions. While such electron-rich species might be expected to be nucleophilic (in the same manner as I–, for example), their instability in solution means that this has not been verified experimentally. Here we report a two-coordinate gold complex (NON)AlAuPtBu3 (where NON is the chelating tridentate ligand 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) that features a strongly polarized bond, Auδ––Alδ+. This is synthesized by reaction of the potassium aluminyl compound [K{Al(NON)}]2 with tBu3PAuI. Computational studies of the complex, includ…

chemistry.chemical_classification010405 organic chemistryChemistryLigandGeneral Chemical EngineeringAtoms in moleculesGeneral Chemistrykompleksiyhdisteetgold010402 general chemistryAlkali metal01 natural scienceskulta0104 chemical sciencesIonElectronegativityCrystallographyNucleophileCovalent bondcoordination complexesCounterionNature chemistry
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Probing the Extremes of Covalency in M-Al bonds: Lithium and Zinc Aluminyl Compounds.

2022

Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing for the first structural characterization of an unsupported lithium-aluminium bond. Crystallographic and quantum-chemical studies are consistent with the presence of a highly polar Li-Al interaction, characterized by a low bond order and relatively little charge transfer from Al to Li. Comparison with magnesium and zinc aluminyl systems reveals changes to both the M-Al bond and the (NON)Al fragment (where NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene), consistent with a more covalent character, with the latter complex being shown to react with CO<sub>2</sub> vi…

low valent compoundssinkki (metallit)ChemistryMagnesiumaluminiumzincchemistry.chemical_elementkompleksiyhdisteetGeneral ChemistryZincGeneral MedicineBond orderCatalysiskemialliset sidoksetCrystallographylitiumNucleophilelithiumCovalent bondAluminiumaluminylPolarLithiumalumiiniAngewandte Chemie (International ed. in English)
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Trapping and Reactivity of a Molecular Aluminium Oxide Ion

2019

Aluminium oxides constitute an important class of inorganic compound that are widely exploited in the chemical industry as catalysts and catalyst supports. Due to the tendency for such systems to aggregate via Al‐O‐Al bridges, the synthesis of well‐defined, soluble, molecular models for these materials is challenging. Here we show that reactions of the potassium aluminyl complex K 2 [( NON )Al] 2 ( NON = 4,5‐bis(2,6‐diiso‐propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethylxanthene) with CO 2 , PhNCO and N 2 O all proceed via a common aluminium oxide intermediate. This highly reactive species can be trapped by coordination of a THF molecule as the anionic oxide complex [( NON )AlO(THF)] ‐ , which …

small molecule activationOxidereduction010402 general chemistry01 natural sciencesHeterolysisCatalysischemistry.chemical_compoundPolymer chemistryMoleculeReactivity (chemistry)alumiiniBond cleavageAluminium oxides010405 organic chemistryaluminiumpelkistysGeneral MedicineGeneral Chemistrykompleksiyhdisteet0104 chemical sciencesHyponitritechemistryoksiditAluminium oxidealuminyloxide
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A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V

2021

Thiele’s hydrocarbon occupies a central role as an open-shell platform for new organic materials, however little is known about its redox behaviour. While recent synthetic approaches involving symmetrical carbene substitution of the CPh2 termini yield isolable neutral/dicationic analogues, the intervening radical cations are much more difficult to isolate, due to narrow compatible redox ranges (typically  1 V), permitting its isolation in crystalline form. Further single-electron oxidation affords borenium dication 12+, thereby establishing an organoboron redox system fully characterized in all three redox states. We perceive that this strategy can be extended to other transient organic rad…

Electronic materialsRadicalScienceGeneral Physics and Astronomy010402 general chemistryPhotochemistryvapaat radikaalit01 natural sciencesRedoxArticleGeneral Biochemistry Genetics and Molecular Biologychemistry.chemical_compoundhapetus-pelkistysreaktiochemistry.chemical_classificationRange (particle radiation)kemiallinen synteesiMultidisciplinary010405 organic chemistryQkationitfood and beveragesGeneral Chemistryhiilivedyt0104 chemical sciencesDicationHydrocarbonRadical ionchemistryYield (chemistry)CarbeneInorganic chemistry
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Carbon Monoxide Activation by a Molecular Aluminium Imide: C−O Bond Cleavage and C−C Bond Formation

2020

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K 2 [( NON )Al(NDipp)] 2 ( NON = 4,5‐bis(2,6‐di iso propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethyl‐xanthene; Dipp = 2,6‐di iso propylphenyl) structural characterization by X‐ray crystallography reveals a short Al‐N distance, which is thought to be due primarily to the low coordinate nature of the nitrogen centre. The Al‐N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of …

small molecule activation010405 organic chemistryaluminiumkompleksiyhdisteetGeneral Medicine010402 general chemistry01 natural sciencescarbon monoxide3. Good health0104 chemical sciencesaktivointiimidealuminylalumiinihiilimonoksidiAngewandte Chemie
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Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi-Lability.

2021

We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. peerReviewed

oxidative additionchemistry.chemical_element010402 general chemistry01 natural sciencesCatalysisDissociation (chemistry)Reductive eliminationreversibilityNucleophilic aromatic substitutiontinPolymer chemistryPincer ligandkemiallinen synteesiChemistry010405 organic chemistryreductive eliminationliganditkompleksiyhdisteetGeneral ChemistryGeneral MedicineAcceptorOxidative addition3. Good health0104 chemical scienceshemi-labile ligandorgaaniset tinayhdisteettinaAmine gas treatingTinAngewandte Chemie (International ed. in English)
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Probing the non-innocent nature of an amino-functionalised β-diketiminate ligand in silylene/iminosilane systems.

2020

Electron-rich β-diketiminate ligands, featuring amino groups at the backbone β positions (“N-nacnac” ligands) have been employed in the synthesis of a range of silylene (SiII) complexes of the type (N-nacnac)SiX (where X = H, Cl, N(SiMe3)2, P(SiMe3)2 and Si(SiMe3)3). A combination of experimental and quantum chemical approaches reveals (i) that in all cases rearrangement to give an aza-butadienyl SiIV imide featuring a contracted five-membered heterocycle is thermodynamically favourable (and experimentally viable); (ii) that the kinetic lability of systems of the type (N-nacnac)SiX varies markedly as a function of X, such that compounds of this type can be isolated under ambient conditions …

Steric effectsMolecular Structure010405 organic chemistryLabilityLigandSilicon CompoundsSilylene010402 general chemistryRing (chemistry)Ligands01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographyKineticschemistryNucleophileIntramolecular forceThermodynamicsIminesImideDensity Functional TheoryDalton transactions (Cambridge, England : 2003)
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Reversible O–H bond activation by an intramolecular frustrated Lewis pair

2019

The interactions of the O-H bonds in alcohols, water and phenol with dimethylxanthene-derived frustrated Lewis pairs (FLPs) have been probed. Within the constraints of this backbone framework, the preference for adduct formation or O-H bond cleavage to give the corresponding zwitterion is largely determined by pKa considerations. In the case of the PPh2/B(C6F5)2 system and p-tBuC6H4OH, an equilibrium is established between the two isomeric forms which allows the thermodynamic parameters associated with zwitterion formation via O-H bond cleavage to be probed.

010405 organic chemistryHydrogen bondintramolecular frustrated Lewis pair010402 general chemistry01 natural sciencesFrustrated Lewis pair0104 chemical sciencesAdductInorganic Chemistrykemialliset sidoksetCrystallographychemistry.chemical_compoundchemistryreversible O-H bond activationZwitterionIntramolecular forceta116Bond cleavageDalton Transactions
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Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion.

2018

The reactivity of aluminium compounds is dominated by their electron deficiency and consequent electrophilicity; these compounds are archetypal Lewis acids (electron-pair acceptors). The main industrial roles of aluminium, and classical methods of synthesizing aluminium–element bonds (for example, hydroalumination and metathesis), draw on the electron deficiency of species of the type AlR3 and AlCl31,2. Whereas aluminates, [AlR4]−, are well known, the idea of reversing polarity and using an aluminium reagent as the nucleophilic partner in bond-forming substitution reactions is unprecedented, owing to the fact that low-valent aluminium anions analogous to nitrogen-, carbon- and boron-centred…

Substitution reactionkemiallinen synteesiMultidisciplinaryanionit010405 organic chemistryaluminiumNacNacElectron deficiencyorganometalliyhdisteet010402 general chemistry01 natural sciencesOxidative additionMedicinal chemistry0104 chemical scienceschemistry.chemical_compoundNucleophilechemistryElectrophileorganometallic compoundsReactivity (chemistry)Lewis acids and basesalumiinianionschemical synthesisNature
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Reversible, room-temperature C—C bond activation of benzene by an isolable metal complex

2019

The activation of C-C bonds is of fundamental interest in the construction of complex molecules from petrochemical feedstocks. In the case of the archetypal aromatic hydrocarbon benzene, C-C cleavage is thermodynamically disfavored, and is brought about only by transient highly reactive species generated in situ. Here we show that the oxidative addition of the C-C bond in benzene by an isolated metal complex is not only possible, but occurs at room temperature and reversibly at a single aluminium center in [(NON)Al]- (where NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene). Selectivity over C-H bond activation is achieved kinetically and allows for the generation…

chemistry.chemical_classificationchemistry.chemical_elementGeneral Chemistry010402 general chemistryCleavage (embryo)Photochemistry01 natural sciencesBiochemistryOxidative additionCatalysis3. Good health0104 chemical sciencesMetalchemistry.chemical_compoundColloid and Surface ChemistrychemistryAluminiumvisual_artvisual_art.visual_art_mediumMoleculeBenzeneSelectivityAromatic hydrocarbon
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Approaching a “naked” boryl anion: amide metathesis as a route to calcium, strontium, and potassium boryl complexes

2020

Abstract Amide metathesis has been used to generate the first structurally characterized boryl complexes of calcium and strontium, {(Me3Si)2N}M{B(NDippCH)2}(thf)n (M=Ca, n=2; M=Sr, n=3), through the reactions of the corresponding bis(amides), M{N(SiMe3)2}2(thf)2, with (thf)2Li‐ {B(NDippCH)2}. Most notably, this approach can also be applied to the analogous potassium amide K{N(SiMe3)2}, leading to the formation of the solvent‐free borylpotassium dimer [K{B(NDippCH)2}]2, which is stable in the solid state at room temperature for extended periods (48 h). A dimeric structure has been determined crystallographically in which the K+ cations interact weakly with both the ipso‐carbons of the flanki…

DimerPotassiumchemistry.chemical_elementBoron Chemistry010402 general chemistryMetathesis01 natural sciencesCatalysischemistry.chemical_compoundAmidestructural studiesbooriBoronStrontiumPotassium amide010405 organic chemistryChemistryCommunicationAtoms in moleculesborylkompleksiyhdisteetGeneral MedicineGeneral ChemistryCommunications0104 chemical sciencesCrystallographys-block chemistryamiditatoms in moleculesboron
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Reversible O-H bond activation by an intramolecular frustrated Lewis pair

2019

The interactions of the O–H bonds in alcohols, water and phenol with dimethylxanthene-derived frustrated Lewis pairs (FLPs) have been probed. Within the constraints of this backbone framework, the preference for adduct formation or O–H bond cleavage to give the corresponding zwitterion is largely determined by pKa considerations. In the case of the PPh2/B(C6F5)2 system and p-tBuC6H4OH, an equilibrium is established between the two isomeric forms which allows the thermodynamic parameters associated with zwitterion formation via O–H bond cleavage to be probed. peerReviewed

kemialliset sidoksetreversible O-H bond activationintramolecular frustrated Lewis pair
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Probing the non-innocent nature of an amino-functionalised β-diketiminate ligand in silylene/iminosilane systems

2020

Electron-rich β-diketiminate ligands{,} featuring amino groups at the backbone β positions (“N-nacnac” ligands) have been employed in the synthesis of a range of silylene (SiII) complexes of the type (N-nacnac)SiX (where X = H{,} Cl{,} N(SiMe3)2{,} P(SiMe3)2 and Si(SiMe3)3). A combination of experimental and quantum chemical approaches reveals (i) that in all cases rearrangement to give an aza-butadienyl SiIV imide featuring a contracted five-membered heterocycle is thermodynamically favourable (and experimentally viable); (ii) that the kinetic lability of systems of the type (N-nacnac)SiX varies markedly as a function of X{,} such that compounds of this type can be isolated under ambient c…

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Arene C‐H activation at aluminium(I) : meta selectivity driven by the electronics of SNAr chemistry

2020

The reactivity of the electron-rich anionic Al(I) (‘aluminyl’) compound K 2 [(NON)Al] 2 (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di- tert -butyl-9,9-dimethylxanthene) towards mono- and disubstituted arenes is reported. C-H activation chemistry with n -butylbenzene gives exclusively the product of activation at the arene meta position. Mechanistically, this transformation proceeds in a single step via a concerted Meisenheimer-type transition state. Selectivity is therefore based on similar electronic factors to classical S N Ar chemistry, which implies the destabilization of transition states featuring electron-donating groups in either the ortho or the para positions. In the cases of tolu…

arenesSNAr mechanismaluminyl nucleophilealuminiumalumiiniC-H activation
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Reversible, room-temperature C-C bond activation of benzene by an isolable metal complex

2019

The activation of C-C bonds is of fundamental interest in the construction of complex molecules from petrochemical feedstocks. In the case of the archetypal aromatic hydrocarbon benzene, C-C cleavage is thermodynamically disfavoured, and is brought about only by transient highly reactive species generated in situ. Here we show that the oxidative addition of the C-C bond in benzene by an isolated metal complex is not only possible, but occurs at room temperature and reversibly at a single aluminium centre in [(NON)Al]- (where NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene). Selectivity over C-H bond activation is achieved kinetically and allows for the generatio…

C-C bonds
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Cooperative N–H bond activation by amido-Ge(ii) cations

2020

N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N–H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N…

kemialliset sidoksetgermaniumkompleksiyhdisteet
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CCDC 2094341: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal SystemCrystal Structure(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-(formato)-tin (26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-chloro-tinCell ParametersExperimental 3D Coordinates
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CCDC 1995924: Experimental Crystal Structure Determination

2020

Related Article: Dinh Cao Huan Do, Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2020|Dalton Trans.|49|8701|doi:10.1039/D0DT01447H

2-[bis(trimethylsilyl)phosphino]-13-bis[26-di-isopropylphenyl]-N4N4N6N6-tetramethyl-12-dihydro-13lambda52-diazasiline-46-diamineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2095879: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal System[N2N4-bis(246-trimethylphenyl)pentane-24-diiminato]-{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido)}-{mu-formato}-zinc-aluminium hexane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952095: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-bromo)-bis(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-di-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumExperimental 3D Coordinates
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CCDC 2094344: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallography(mu-carbonato)-bis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-di-tinCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1899009: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal System(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium (27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido))-aluminium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1872784: Experimental Crystal Structure Determination

2019

Related Article: Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2019|Dalton Trans.|48|2896|doi:10.1039/C9DT00228F

Space GroupCrystallography{5-[bis(246-trimethylphenyl)phosphaniumyl]-99-dimethyl-9H-xanthen-4-yl}(4-t-butylphenolato)bis(pentafluorophenyl)boron dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2008538: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis(3-butylphenyl)-di-aluminium(iii)-di-potassium butylbenzene solvateExperimental 3D Coordinates
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CCDC 1995922: Experimental Crystal Structure Determination

2020

Related Article: Dinh Cao Huan Do, Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2020|Dalton Trans.|49|8701|doi:10.1039/D0DT01447H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(N-(26-di-isoopropylphenyl)-13-bis(dimethylamino)-3-iminopropenyl)-(26-di-isopropylphenylimino)-(bis(trimethylsilyl)amide)-siliconExperimental 3D Coordinates
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CCDC 1854972: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Akseli Mansikkamäki, Petra Vasko, Jose M. Goicoechea,  Simon Aldridge|2019|Nature Chemistry|11|237|doi:10.1038/s41557-018-0198-1

(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-(tris(t-butyl)phosphine)-gold-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1972056: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium [14-bis(trimethylsilyl)tetra-az-2-enato]-(27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-aluminiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1581596: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallography(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-iodo-gallium(iii) toluene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1995923: Experimental Crystal Structure Determination

2020

Related Article: Dinh Cao Huan Do, Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2020|Dalton Trans.|49|8701|doi:10.1039/D0DT01447H

(N-(26-di-isoopropylphenyl)-13-bis(dimethylamino)-3-iminopropenyl)-(26-di-isopropylphenylimino)-(bis(trimethylsilyl)phosphide)-silicon benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1581598: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-hydrido-aluminium(iii) toluene solvateExperimental 3D Coordinates
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CCDC 1872783: Experimental Crystal Structure Determination

2019

Related Article: Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2019|Dalton Trans.|48|2896|doi:10.1039/C9DT00228F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4-t-butylphenolato)[5-(diphenylphosphaniumyl)-99-dimethyl-9H-xanthen-4-yl]bis(pentafluorophenyl)boron dichloromethane solvateExperimental 3D Coordinates
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CCDC 2005219: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[N-{[2-(diphenylphosphanyl)phenyl]methyl}-26-bis(propan-2-yl)anilinato]-germanium tetrakis[111333-hexafluoro-2-(trifluoromethyl)propan-2-olato]-aluminiumExperimental 3D Coordinates
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CCDC 1972053: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-hydrido-(12-bis(26-dimethylphenylimino)-2-oxyethyl)-aluminium tetrahydrofuran solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2094340: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal Systembis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-C)-bis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-CN)-tetra-tin diethyl ether solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2063254: Experimental Crystal Structure Determination

2021

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Space GroupCrystallography2-(1-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-132-diazaborol-2-yl}pyridin-1-ium-4-yl)-13-bis[26-bis(propan-2-yl)phenyl]-23-dihydro-1H-imidazol-2-ylium bis(hexakis(fluoro)-antimony) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899011: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium (hexa-135-triene-16-diyl)-(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido))-aluminium(iii) benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1972057: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-(26-di-isopropylphenylimine)-aluminium toluene solvateExperimental 3D Coordinates
researchProduct

CCDC 1899006: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal System(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium dichloro-{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-aluminium(iii) benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943804: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systembis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-bis(mu-hydrazine-12-diolato)-di-aluminium-di-potassium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943806: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal Structurepotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(hydrido)-(hydroxy)-aluminium benzene solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2094342: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-hydrido-tri-tin pentane solvateExperimental 3D Coordinates
researchProduct

CCDC 1972054: Experimental Crystal Structure Determination

2020

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potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-benzyl-(trimethylsilylamide)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2063252: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal System{N1N2-bis[26-bis(propan-2-yl)phenyl]ethene-12-diaminato}{4-[13-bis(246-trimethylphenyl)imidazol-2-ylidene]-14-dihydropyridin-1-ium-1-ylidene}boronCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1972052: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-hydrido-(26-dimethylanilide)-aluminium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1952092: Experimental Crystal Structure Determination

2020

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(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-bromo-germaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1952094: Experimental Crystal Structure Determination

2020

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(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943805: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-oxo-(tetrahydrofuran)-aluminium benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1854971: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-[(propan-2-yl)azanidyl][(propan-2-yl)imino]methyl)-(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-(tris(t-butyl)phosphine)-aluminium-gold benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 2095878: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(N2N4-bis(246-trimethylphenyl)pentane-24-diiminato)-aluminium-zincExperimental 3D Coordinates
researchProduct

CCDC 2095877: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-bis(diethyl ether)-lithium-aluminium diethyl ether solvateExperimental 3D Coordinates
researchProduct

CCDC 1581594: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-di-gallium(i)-di-potassium(i) toluene solvateExperimental 3D Coordinates
researchProduct

CCDC 1854973: Experimental Crystal Structure Determination

2019

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Space GroupCrystallography(mu-iodo)-bis(triphenylphosphine)-(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-di-gold-aluminium diethyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899010: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallography(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium (27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido))-phenyl-hydrido-aluminium(iii) benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581591: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal System{27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato}-iodo-aluminium toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2063253: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-132-diazaborol-2-yl}-4-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-imidazol-2-ylidene}-14-dihydropyridin-1-ium radical hexakis(fluoro)-antimonyExperimental 3D Coordinates
researchProduct

CCDC 1872782: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[5-(diphenylphosphanyl)-99-dimethyl-9H-xanthen-4-yl][bis(pentafluorophenyl)](propan-2-ol)boron n-hexane dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1943808: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systempotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(phenylcarbamato)-aluminium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581600: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal Systembis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-bis(mu-hydrido)-dihydrido-di-aluminium-di-potassium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2021078: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(13-bis[26-diisopropylphenyl]-13-dihydro-2H-132-diazaborol-2-yl)-(bis(trimethylsilyl)amido)-tris(tetrahydrofuran)-strontium
researchProduct

CCDC 1581593: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(N2N4-bis(246-trimethylphenyl)pentane-24-diiminato)-(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-aluminium(i)-magnesium(ii)Experimental 3D Coordinates
researchProduct

CCDC 1581592: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

bis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-di-aluminium(i)-di-potassium(i) benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1872780: Experimental Crystal Structure Determination

2019

Related Article: Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2019|Dalton Trans.|48|2896|doi:10.1039/C9DT00228F

Space GroupCrystallographyCrystal Systemaqua[5-(diphenylphosphanyl)-99-dimethyl-9H-xanthen-4-yl]bis(pentafluorophenyl)boron dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581599: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographybis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-bis(mu-hydrido)-diphenyl-di-aluminium-di-potassium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2005217: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal Structurechloro-[N-{[2-(diphenylphosphanyl)phenyl]methyl}-26-bis(propan-2-yl)anilinato]-germaniumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2021077: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspotassium 1-[26-diisopropylphenyl]-99-dimethyl-5-isopropyl-1H9H-[132]diazaborolo[12-a][12]benzazaborolide methylcyclohexaneExperimental 3D Coordinates
researchProduct

CCDC 1952093: Experimental Crystal Structure Determination

2020

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(1-(2-(t-butylamido)ethyl)-3-t-butylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1952097: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(9H-carbazol-9-yl)-(1-(2-(t-butylamino)ethyl)-3-mesitylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminium fluorobenzene solvate
researchProduct

CCDC 2094346: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal Structure(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-iodo-tinCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943807: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographybis(mu-carbonato)-bis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-di-aluminium-di-potassium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2021075: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(13-bis[26-diisopropylphenyl]-13-dihydro-2H-132-diazaborol-2-yl)-(bis(trimethylsilylamido))-bis(tetrahydrofuran)-calciumExperimental 3D Coordinates
researchProduct

CCDC 1899005: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal SystemCrystal Structurebis(chloro)-(mu-hexa-135-triene-16-diyl)-tetramethyl-di-tin(iv)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2094343: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-CN)-bis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-C)-dihydrido-tetra-tin hexane solvateExperimental 3D Coordinates
researchProduct

CCDC 1581595: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal Structurebis(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-di-aluminium(ii) hexane pentane solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008540: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

bis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-(4-methylphenyl)methyl-hydrido-di-aluminium(iii)-di-potassium n-hexane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1854974: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Akseli Mansikkamäki, Petra Vasko, Jose M. Goicoechea,  Simon Aldridge|2019|Nature Chemistry|11|237|doi:10.1038/s41557-018-0198-1

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-formato)-(tris(t-butyl)phosphine)-(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-gold-aluminium benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 2021076: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-13-bis[26-diisopropylphenyl]-13-dihydro-2H-132-diazaborol-2-yl)-di-potassiumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1995925: Experimental Crystal Structure Determination

2020

Related Article: Dinh Cao Huan Do, Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2020|Dalton Trans.|49|8701|doi:10.1039/D0DT01447H

Space GroupCrystallographyCrystal System(N-(26-di-isoopropylphenyl)-13-bis(dimethylamino)-3-iminopropenyl)-(26-di-isopropylphenylimino)-(tris(trimethylsilyl)silyl)-siliconCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1872781: Experimental Crystal Structure Determination

2019

Related Article: Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Simon Aldridge|2019|Dalton Trans.|48|2896|doi:10.1039/C9DT00228F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[5-(diphenylphosphanyl)-99-dimethyl-9H-xanthen-4-yl](methanol)bis(pentafluorophenyl)boronExperimental 3D Coordinates
researchProduct

CCDC 2008537: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal Systembis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((3-methylphenyl)methyl)-di-aluminium(iii)-di-potassium toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2094345: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-bromo-tinSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899008: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium {27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-(hydrido)-(naphthalen-2-yl)-aluminium benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1972055: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-({[26-di-isopropylphenyl]imino}acetato)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581597: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal Structure(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-methyl-aluminium(iii) toluene solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008536: Experimental Crystal Structure Determination

2020

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