Author: Aparup Paul

0000000001299386

AUTHOR

Aparup Paul

Field-induced slow magnetic relaxation in mixed valence di- and tri-nuclear CoII–CoIII complexes

Two novel mixed valence CoII–CoIII complexes, namely [CoIICoIII(L1)(ab)(mb)2(H2O)]·dmf (1) and [CoIII2CoII(L2)4(H2O)4]·2H2O (2) [H2L1 = (E)-2-((1-hydroxybutan-2-ylimino)methyl)-6-methoxyphenol, ab = 2-amino-butan-1-ol anion, mb = p-methyl benzoate, H2L2 = 3-((2-hydroxy-3-methoxy-benzylidene)-amino)-propionic acid, and dmf = N,N-dimethyl-formamide], were synthesized and characterized by single crystal X-ray diffraction and magnetic studies at low temperature. The structure determination reveals that both complexes belong to the monoclinic system with P21/c (1) and I2/a (2) space groups. Complex 1 is a dinuclear CoIIICoII compound with distorted octahedral cobalt centers showing different coo…

research product

CCDC 1536659: Experimental Crystal Structure Determination

Related Article: Aparup Paul, Marta Viciano-Chumillas, Horst Puschmann, Joan Cano, Subal Chandra Manna|2020|Dalton Trans.|49|9516|doi:10.1039/D0DT00588F

research product

CCDC 1977640: Experimental Crystal Structure Determination

Related Article: Aparup Paul, Marta Viciano-Chumillas, Horst Puschmann, Joan Cano, Subal Chandra Manna|2020|Dalton Trans.|49|9516|doi:10.1039/D0DT00588F

research product

PEPhysical Sciences and Engineering
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