0000000001299451

AUTHOR

Eli Zysman-colman

showing 56 related works from this author

Green phosphorescence and electroluminescence of sulfur pentafluoride-functionalized cationic iridium(III) complexes

2015

EZ-C acknowledges the University of St Andrews for financial support. We report four cationic iridium(III) complexes [Ir(C^N)2(dtBubpy)](PF6) that have sulfurpentafluoride-modified 1-phenylpyrazole and 2-phenylpyridine cyclometalating (C^N) ligands (dtBubpy = 4,4'-di-tert-butyl-2,2'-bipyridyl). Three of the complexes were characterized by single-crystal X-ray structure analysis. In cyclic voltammetry, the complexes undergo reversible oxidation of iridium(III) and irreversible reduction of the SF5 group. They emit bright green phosphorescence in acetonitrile solution and in thin films at room temperature, with emission maxima between 482–519 nm and photoluminescence quantum yields of up to 7…

Photoluminescencechemistry.chemical_elementChemistry Techniques SyntheticCrystallography X-RayIridiumLigandsPhotochemistryInorganic ChemistryFluorideschemistry.chemical_compoundOrganometallic CompoundsQDIridiumPhysical and Theoretical ChemistryAcetonitrileTrifluoromethylMolecular StructureSulfur CompoundsCationic polymerizationDASElectrochemical TechniquesEquipment DesignQD ChemistrySulfurchemistryLuminescent MeasurementsCyclic voltammetryPhosphorescence
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Wide-Bite-Angle Diphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence …

2021

We report a series of seven cationic heteroleptic copper(I) complexes of the form [Cu(P^P)(dmphen)]BF4, where dmphen is 2,9-dimethyl-1,10-phenanthroline and P^P is a diphosphine chelate, in which the effect of the bite angle of the diphosphine ligand on the photophysical properties of the complexes was studied. Several of the complexes exhibit moderately high photoluminescence quantum yields in the solid state, with ΦPL of up to 35%, and in solution, with ΦPL of up to 98%. We were able to correlate the powder photoluminescence quantum yields with the % Vbur of the P^P ligand. The most emissive complexes were used to fabricate both organic light-emitting diodes and light-emitting electrochem…

PhotoluminescenceLigandCationic polymerizationchemistry.chemical_element02 engineering and technologyBite angle010402 general chemistry021001 nanoscience & nanotechnologyElectrochemistry01 natural sciencesCopper0104 chemical sciencesInorganic ChemistryCrystallographychemistryElectrochemiluminescenceChelationPhysical and Theoretical Chemistry0210 nano-technologyInorganic chemistry
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Impact of the use of sterically congested Ir(III) complexes on the performance of light-emitting electrochemical cells

2018

International audience; The synthesis, structural and optoelectronic characterization of a family of sterically congested cyclometalated cationic Ir(iii) complexes of the form [Ir(C^N)2(dtBubpy)]PF6 (with dtBubpy = 4,4′-di-tert-butyl-2,2′-bipyridine and C^N = a cyclometalating ligand decorated at the 4-position of the pyridine ring and/or the 3-position of the phenyl ring with a range of sterically bulky substituents) are reported. This family of complexes is compared to the unsubstituted analogue complex R1 bearing 2-phenylpyridinato as cyclometalating ligand. The impact of sterically bulky substituents on the C^N ligands on both the solid state photophysics and light-emitting electrochemi…

Steric effectsPhotoluminescenceMaterials scienceSterically congested02 engineering and technology010402 general chemistryRing (chemistry)Ligands01 natural sciencesElectrochemical cellchemistry.chemical_compoundPyridineMaterials ChemistryOptoelectronic characterization[CHIM.COOR]Chemical Sciences/Coordination chemistryLight-emitting electrochemical cell[PHYS]Physics [physics]X ray powder diffractionLigandChelationYellow luminescenceCationic polymerizationDevice performancePhotoluminescence quantum yieldsGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesCyclometalating ligandCrystallographychemistrySynthesis (chemical)Iridium compounds0210 nano-technologyLuminescence[CHIM.OTHE]Chemical Sciences/OtherInternuclear distances
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Ionic multiresonant thermally activated delayed fluorescence emitters for light emitting electrochemical cells

2022

Funding: M. K. would like to thank 2214-A International Research Fellowship Programme for Ph.D. students (1059B141900585). This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska Curie grant agreement No 838885 (NarrowbandSSL). S.M.S. acknowledges support from the Marie Skłodowska-Curie Individual Fellowship (grant agreement No 838885 NarrowbandSSL). A. K. G. is grateful to the Royal Society for Newton International Fellowship NF171163. L.M acknowledges that the project who gave rise to these results received support from the European Research Council (ERC) under the European Union’s Horizon 2020 research and inno…

ElectroquímicaMultiresonancePurely organic emittersMCCThermally activated delayed fluorescenceElectroluminescenceLight-emitting electrochemical cellsOrganic ChemistryDASQDQD ChemistryQuímica orgànica
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Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(iii) complexes bearing bisphosphine ligands

2016

EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and AKB acknowledge support from EPSRC (EP/J01771X). This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) MAT2014-55200. Herein we present a structure-property relationship study of thirteen cationic iridium (III) complexes of the form of [Ir(C^N)2(P^P)]PF6 in both solution and the solid state through systematic evaluation of six bisphosphine (P^P) ligands (xantphos, dpephos, dppe, Dppe, nixantphos and is…

PhotoluminescenceXantphosLigandNDASCationic polymerizationchemistry.chemical_element02 engineering and technologyBite angleQD Chemistry010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistryElectrochemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryQDIridium0210 nano-technologyLuminescenceInorganic Chemistry Frontiers
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Fluorine-free blue-green emitters for light-emitting electrochemical cells

2014

Date of Acceptance: 29/05/2014 There is presently a lack of efficient and stable blue emitters for light-emitting electrochemical cells (LEECs), which limits the development of white light emitting systems for lighting. Cyclometalated iridium complexes as blue emitters tend to show low photoluminescence efficiency due to significant ligand-centred character of the radiative transition. The most common strategy to blue-shift the emission is to use fluorine substituents on the cyclometalating ligand, such as 2,4-difluorophenylpyridine, dFppy, which has been shown to decrease the stability of the emitter in operating devices. Herein we report a series of four new charged cyclometalated iridium…

PhotoluminescenceMaterials scienceLigandchemistry.chemical_elementGeneral ChemistryTime-dependent density functional theoryQD ChemistryPhotochemistryElectrochemistryElectrochemical cellchemistry.chemical_compoundchemistryPyridineMaterials ChemistryFluorineQDIridiumJ. Mater. Chem. C
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Deep-blue thermally activated delayed fluorescence (TADF) emitters for light-emitting electrochemical cells (LEECs)

2017

The authors acknowledge the University of St Andrews for financial support. The authors also acknowledge financial support from the European Union H2020 project INFORM (grant 675867), the Spanish Ministry of Economy and Competitiveness (MINECO) via the Unidad de Excelencia María de Maeztu MDM-2015-0538, MAT2014-55200 and the Generalitat Valenciana (Prometeo/2016/135). MLP acknowledges support from a Grisolia grant (GRISOLIA/2015/A/146). Two deep blue thermally activated delayed fluorescence (TADF) emitters ( imCzDPS and imDPADPS ) that contain charged imidazolium groups tethered to the central luminophore were designed and synthesized as small molecule organic emitters for light-emitting e…

PhotoluminescenceMaterials scienceDopingNanotechnologyDAS02 engineering and technologyGeneral ChemistryElectroluminescenceNanosecond010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistryQD Chemistry01 natural sciences7. Clean energyFluorescence0104 chemical sciencesFull width at half maximumchemistry.chemical_compoundMicrosecondchemistryMaterials ChemistryLuminophoreQD0210 nano-technology
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Efficient light-emitting electrochemical cells using small molecular weight, ionic, host-guest systems

2015

This work has been supported by the Spanish Ministry of Economy and Competitiveness (MAT2014-55200). Light-emitting electrochemical cells (LECs) based on fluorescent host-guest small molecules system are reported. The LECs show electroluminescence coming solely from the guest, with an external quantum efficiency (EQE) of 2.0%, which is very close to the theoretical maximum EQE (2.2%) for this particular system. This work demonstrates the possibility to obtain high efficiency devices employing low-cost materials, making host-guest systems a real alternative to more traditional semiconducting polymer or transition metal compounds. Postprint Peer reviewed

Materials scienceLECNDASIonic bondingLight emitting electrochemical cellNanotechnology02 engineering and technologyElectroluminescence010402 general chemistry021001 nanoscience & nanotechnologyQD Chemistry01 natural sciences0104 chemical sciencesElectronic Optical and Magnetic MaterialsElectrochemical cellElectroluminescenceChristian ministryQDLight-emitting electrochemical cell0210 nano-technologyHost (network)
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Tuning the Emission of Cationic Iridium (III) Complexes Towards the Red Through Methoxy Substitution of the Cyclometalating Ligand

2015

The synthesis, characterization and evaluation in solid-state devices of a series of 8 cationic iridium complexes bearing different numbers of methoxy groups on the cyclometallating ligands are reported. The optoelectronic characterization showed a dramatic red shift in the absorption and the emission and a reduction of the electrochemical gap of the complexes when a methoxy group was introduced para to the Ir-C bond. The addition of a second or third methoxy group did not lead to a significant further red shift in these spectra. Emission maxima over the series ranged from 595 to 730 nm. All complexes possessing a motif with a methoxy group at the 3-position of the cyclometalating ligands s…

ArticleScientific Reports
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Light-emitting electrochemical cells and solution-processed organic light-emitting diodes using small molecule organic thermally activated delayed fl…

2015

EZ-C thanks the University of St Andrews for support. The authors are grateful to the EPSRC for financial support (grants EP/J01771X and EP/J00916). IDWS is a Royal Society Wolfson Research Merit Award Holder. Two novel charged organic thermally activated delayed fluorescence (TADF) emitters, 1 and 2, have been synthesized. Their TADF behavior is well-supported by the multiexponential decay of their emission (nanosecond and microsecond components) and the oxygen dependence of the photoluminescence quantum yields. Spin-coated electroluminescent devices have been fabricated to make light-emitting electrochemical cells (LEECs) and organic light-emitting diodes (OLEDs). The first example of a n…

NDASQDQD ChemistryBDC
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CCDC 1490702: Experimental Crystal Structure Determination

2017

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

Space GroupCrystallography(44'-di-t-butyl-22'-bipyridine)-bis(2-(2-pyridyl)phenyl)-iridium hexafluorophosphateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1423252: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal System(bis(2-(Diphenylphosphino)phenyl) ether)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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Ionic Multi-Resonant Thermally Activated Delayed Fluorescence Emitters for Light Emitting Electrochemical Cells (dataset)

2022

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CCDC 1546695: Experimental Crystal Structure Determination

2017

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

Space GroupCrystallographyCrystal SystemCrystal Structure(44'-di-t-butyl-22'-bipyridine)-bis(26-dimethoxy-5-(4-methylpyridin-2-yl)pyrimidin-4-yl)-iridium hexafluorophosphate diethyl ether solvateCell ParametersExperimental 3D Coordinates
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Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligands (dataset)

2017

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CCDC 1490703: Experimental Crystal Structure Determination

2017

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

Space GroupCrystallographyCrystal SystemCrystal StructureΛ-(44'-di-t-butyl-22'-bipyridine)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1423251: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters((99-Dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvate hemihydrateExperimental 3D Coordinates
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CCDC 2061123: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallography[(benzo[kl]xanthene-68-diyl)bis(diphenylphosphine)]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1490707: Experimental Crystal Structure Determination

2017

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

Space GroupCrystallographyCrystal SystemCrystal StructureΔΔ-bis(mu-chloro)-tetrakis(2-(4-mesitylpyridin-2-yl)phenyl)-di-iridium dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1546696: Experimental Crystal Structure Determination

2017

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

Space GroupCrystallographyCrystal System(44'-di-t-butyl-22'-bipyridine)-bis(26-dimethoxy-5-[5-(trifluoromethyl)pyridin-2-yl]pyrimidin-4-yl)-iridium hexafluorophosphateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1423253: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographyCrystal SystemCrystal Structure(Ethene-12-diylbis(diphenylphosphine))-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 2061124: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(29-dimethyl-110-phenanthroline)-((ethene-12-diyl)-bis(diphenylphosphine))-copper tetrafluoroborate dichloromethane solvate
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CCDC 2061121: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallography[46-bis(diphenylphosphanyl)-10H-phenoxazine]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1053872: Experimental Crystal Structure Determination

2015

Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717

(44'-di-t-butyl-22'-bipyridine)-bis(4-(pentafluorosulfanyl)-2-(1H-pyrazol-1-yl)phenyl)-iridium(iii) hexafluorophosphate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1053870: Experimental Crystal Structure Determination

2015

Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(44'-di-t-butyl-22'-bipyridine)-bis(5-(pentafluorosulfanyl)-2-(pyridin-2-yl)phenyl)-iridium(iii) hexafluorophosphateExperimental 3D Coordinates
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CCDC 2061118: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal System[(99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine)]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborate dichloromethane diethyl ether solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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Blue-Emitting Cationic Iridium(III) Complexes Featuring Pyridylpyrimidine Cyclometalating Ligands and their Use in Sky-Blue and Blue-Green Light-Emit…

2017

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CCDC 1423259: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographybis(35-difluoro-2-(4-mesitylpyridin-2-yl)phenyl)-(ethene-12-diylbis(diphenylphosphine))-iridium hexafluorophosphate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2061119: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal Structure([1011-dihydrodibenzo[bf]oxepine-46-diyl)bis(diphenylphosphine)]-(29-dimethyl-110-phenanthroline)-copper(i) tetrafluoroborate dichloromethane solvateCell ParametersExperimental 3D Coordinates
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CCDC 1490708: Experimental Crystal Structure Determination

2017

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

Space GroupCrystallographyCrystal SystemΛΛ-bis(mu-chloro)-tetrakis(2-(4-mesitylpyridin-2-yl)phenyl)-di-iridium dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1490705: Experimental Crystal Structure Determination

2017

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

Space GroupCrystallographyΛ-(44'-di-t-butyl-22'-bipyridine)-bis(2-(4-mesitylpyridin-2-yl)phenyl)-iridium hexafluorophosphate diethyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1546698: Experimental Crystal Structure Determination

2017

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(510-dihydrodiimidazo[12-b:2'1'-d][25]benzodiazocine)-(26-dimethoxy-5-[5-(trifluoromethyl)pyridin-2-yl]pyrimidin-3-ium-4-yl)-(26-dimethoxy-5-[5-(trifluoromethyl)pyridin-2-yl]pyrimidin-4-yl)-iridium (510-dihydrodiimidazo[12-b:2'1'-d][25]benzodiazocine)-bis(26-dimethoxy-5-[5-(trifluoromethyl)pyridin-2-yl]pyrimidin-4-yl)-iridium tris(hexafluorophosphate) acetonitrile diethyl ether solvate
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CCDC 1490429: Experimental Crystal Structure Determination

2016

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602

Space GroupCrystallographyCrystal SystemCrystal Structure(44'-di-t-butyl-22'-bipyridine)-bis(2-(pyridin-2-yl)-5-(trifluoromethoxy)phenyl)-iridium hexafluorophosphate diethyl ether solvateCell ParametersExperimental 3D Coordinates
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CCDC 1423255: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

Space GroupCrystallographybis(2-(4-Mesitylpyridyl)phenyl-CN)-((99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-iridium hexafluorophosphate dichloromethane diethyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Data Underpinning - Tuning the emission of cationic iridium (III) complexes towards the red through methoxy substitution of the cyclometalating ligand

2015

EZ-C acknowledges CFI (Canadian Foundation for Innovation), NSERC (the Natural Sciences and Engineering Research Council of Canada), FQRNT (Le Fonds québécois de la recherche sur la nature et les technologies) and the University of St Andrews for financial support. C. R-C. would like to thank the MINECO for the financial support of this research in the framework of project CTQ2010-17481, the Junta de Andalucía (CICyE) for special financial support (P08-FQM-4011 and P10-FQM-6703) and the MECD (Spanish Ministry of Education, Culture, and Sport) for an FPU grant. This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) (MAT2014-55200), the Generalitat Valenc…

QDQD Chemistry
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CCDC 1538393: Experimental Crystal Structure Determination

2017

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Eli Zysman-Colman|2017|RSC Advances|7|31833|doi:10.1039/C7RA06347D

Space GroupCrystallographyCrystal System(22'-bi-13-thiazole)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1538394: Experimental Crystal Structure Determination

2017

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Eli Zysman-Colman|2017|RSC Advances|7|31833|doi:10.1039/C7RA06347D

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(22'-bi-13-benzothiazole)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate acetonitrile solvateExperimental 3D Coordinates
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Impact of the Use of Sterically Congested Cyclometalated Ligands on the Optoelectronic Properties and Device Performances In Light-Emitting Electroch…

2018

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CCDC 1423254: Experimental Crystal Structure Determination

2015

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

(46-bis(Diphenylphosphino)-10H-phenoxazine)-bis(2-(pyridin-2-yl)phenyl)-iridium hexafluorophosphate dichloromethane solvate hemihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2061120: Experimental Crystal Structure Determination

2021

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

Space GroupCrystallographyCrystal SystemCrystal Structure(29-dimethyl-110-phenanthroline)-{[9-(propan-2-ylidene)-9H-xanthene-45-diyl]bis(diphenylphosphine)}-copper(i) tetrafluoroborateCell ParametersExperimental 3D Coordinates
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CCDC 1490428: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(44'-di-t-butyl-22'-bipyridine)-bis(2-(pyridin-2-yl)-5-(trifluoromethyl)phenyl)-iridium hexafluorophosphateExperimental 3D Coordinates
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Data underpinning - Chiral Iridium(III) Complexes in Light-Emitting Electrochemical Cells: Exploring The Impact of Stereochemistry on The Photophysic…

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CCDC 1546697: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(510-dihydrodiimidazo[12-b:2'1'-d][25]benzodiazocine)-(26-dimethoxy-5-[4-methylpyridin-2-yl]pyrimidin-4-yl)-(26-dimethoxy-5-[4-methylpyridin-2-yl]pyrimidin-3-ium-4-yl)-iridium bis(hexafluorophosphate) acetonitrile diethyl ether solvateExperimental 3D Coordinates
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CCDC 2061122: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(29-dimethyl-110-phenanthroline)-[(phenoxathiine-46-diyl)bis(diphenylphosphine)]-copper(i) tetrafluoroborateExperimental 3D Coordinates
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CCDC 1423258: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(35-difluoro-2-(4-mesitylpyridin-2-yl)phenyl)-((oxydi-21-phenylene)bis(diphenylphosphine))-iridium hexafluorophosphate diethyl ether solvateExperimental 3D Coordinates
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CCDC 1490430: Experimental Crystal Structure Determination

2016

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CCDC 1423257: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(35-difluoro-2-(4-mesitylpyridin-2-yl)phenyl)-((99-dimethyl-9H-xanthene-45-diyl)bis(diphenylphosphine))-iridium hexafluorophosphateCell ParametersExperimental 3D Coordinates
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Simple Design to Achieve Red-to-Near-infrared Emissive Cationic Ir(III) Emitters and their use in Light Emitting Electrochemical Cells (dataset)

2017

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CCDC 1490706: Experimental Crystal Structure Determination

2017

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CCDC 1490704: Experimental Crystal Structure Determination

2017

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CCDC 1053871: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(44'-di-t-butyl-22'-bipyridine)-bis(5-(pentafluorosulfanyl)-2-(1H-pyrazol-1-yl)phenyl)-iridium(iii) hexafluorophosphate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1423256: Experimental Crystal Structure Determination

2015

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Data underpinning - Synthesis, Properties and Light-Emitting Electrochemical Cell (LEEC) Device Fabrication of Cationic Ir(III) Complexes Bearing Ele…

2016

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CCDC 1490431: Experimental Crystal Structure Determination

2016

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(44'-di-t-butyl-22'-bipyridine)-bis(2-(pyridin-2-yl)-5-((trifluoromethyl)sulfonyl)phenyl)-iridium hexafluorophosphateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Deep-Blue Thermally Activated Delayed Fluorescence (TADF) Emitters for Light-Emitting Electrochemical Cells (LEECs) (dataset)

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