0000000001299455
AUTHOR
Amit Adhikary
Syntheses, crystal structures, and magnetic properties of metal-organic hybrid materials of Mn(II)/Co(II): three-fold interpenetrated alpha-polonium-like network in one of them
Three new 1,4-phenylenediacrylate bridged Mn(II) and Co(II) complexes of molecular formulas {[Mn2(ppda)(phen)4(H2O)2](ppda)2(H2O)} (1), {[Co(ppda)- (dpyo)(H2O)3]·4(H2O)}n (2), and {[Co(ppda)(bpe)]·(0.5H2O)}n (3) [ppda = 1,4- phenylenediacrylate; phen = 1,10-phenanthroline; dpyo = 4,4′-dipyridyl N,N′-dioxide; bpe = 1,2-bis(4-pyridyl)ethane] have been synthesized and characterized by elemental analysis, IR spectra, single-crystal X-ray diffraction studies, and low-temperature magnetic measurements. The structural determination reveals that complex 1 is a discrete dinuclear species, 2 is a 1D polymeric chain, while 3 is a three-fold interpenetrated α-polonium network. Hydrogen-bonding interact…
CCDC 1020482: Experimental Crystal Structure Determination
Related Article: Soumen Mistri, Ennio Zangrando, Albert Figuerola, Amit Adhikary, Sanjit Konar, Joan Cano, and Subal Chandra Manna|2014|Cryst.Growth Des.|14|3276|doi:10.1021/cg500162x
CCDC 1020481: Experimental Crystal Structure Determination
Related Article: Soumen Mistri, Ennio Zangrando, Albert Figuerola, Amit Adhikary, Sanjit Konar, Joan Cano, and Subal Chandra Manna|2014|Cryst.Growth Des.|14|3276|doi:10.1021/cg500162x
CCDC 1020480: Experimental Crystal Structure Determination
Related Article: Soumen Mistri, Ennio Zangrando, Albert Figuerola, Amit Adhikary, Sanjit Konar, Joan Cano, and Subal Chandra Manna|2014|Cryst.Growth Des.|14|3276|doi:10.1021/cg500162x