0000000001299463

AUTHOR

Mikhail A. Kinzhalov

showing 43 related works from this author

PdII-mediated integration of isocyanides and azide ions might proceed via formal 1,3-dipolar cycloaddition between RNC ligands and uncomplexed azide

2016

Reaction between equimolar amounts of trans-[PdCl(PPh3)2(CNR)][BF4] (R = t-Bu 1, Xyl 2) and diisopropylammonium azide 3 gives the tetrazolate trans-[PdCl(PPh3)2(N4t-Bu)] (67%, 4) or trans-[PdCl(PPh3)2(N4Xyl)] (72%, 5) complexes. 4 and 5 were characterized by elemental analyses (C, H, N), HRESI+-MS, 1H and 13C{1H} NMR spectroscopies. In addition, the structure of 4 was elucidated by a single-crystal X-ray diffraction. DFT calculations showed that the mechanism for the formal cycloaddition (CA) of N3− to trans-[PdCl(PH3)2(CNMe)]+ is stepwise. The process is both kinetically and thermodynamically favorable and occurs via the formation of an acyclic NNNCN-intermediate. The second step of the fo…

010405 organic chemistryLigandStereochemistryIsocyanidechemistry.chemical_elementGeneral Chemistrypalladium complexes010402 general chemistry01 natural sciencesMedicinal chemistryCatalysisCycloadditionazides0104 chemical sciencesIonchemistry.chemical_compoundisocyanideschemistry13-Dipolar cycloadditionPotential energy surfaceMaterials ChemistryAzideta116PalladiumNew Journal of Chemistry
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ADC-Based Palladium Catalysts for Aqueous Suzuki Miyaura Cross-Coupling Exhibit Greater Activity than the Most Advantageous Catalytic Systems

2013

The reaction between the equimolar amounts of cis-[PdCl2(CNR1)2] (R1 = cyclohexyl (Cy) (1), tBu (2)) and the carbohydrazides R2CONHNH2 (R2 = Ph (5), 4-ClC6H4 (6), 3-NO2C6H4 (7), 4-NO2C6H4 (8), 4-CH3C6H4 (9), 3,4-(MeO)2C6H3 (10), naphth-1-yl (11), fur-2-yl (12), 4-NO2C6H4CH2 (13), Cy (14), 1-(4-fluorophenyl)-5-oxopyrrolidin-3-yl (15), (pyrrolidin-1-yl)C(O) (16)) proceeds in refluxing CHCl3 for ca. 4 h. A subsequent workup provided the aminocarbene species cis-[PdCl2{C(NHNHC(O)R2)═N(H)R1}(CNR1)] (18–33) in good to excellent (80–95%) isolated yields. The coupling of equimolar amounts of cis-[PdCl2(CNR1)2] (R1 = Cy (1), tBu (2), 2,6-Me2C6H3 (Xyl) (3), 2-Cl-6-MeC6H3 (4)) and PhSO2NHNH2 (17) occu…

Inorganic ChemistryAqueous solutionchemistryStereochemistryOrganic Chemistrychemistry.chemical_elementNuclear magnetic resonance spectroscopyPhysical and Theoretical ChemistryCoupling (probability)Medicinal chemistryta116PalladiumCatalysisOrganometallics
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Studies of Nature of Uncommon Bifurcated I–I···(I–M) Metal-Involving Noncovalent Interaction in Palladium(II) and Platinum(II) Isocyanide Cocrystals

2021

Two isostructural trans-[MI2(CNXyl)2]·I2 (M = Pd or Pt; CNXyl = 2,6-dimethylphenyl isocyanide) metallopolymeric cocrystals containing uncommon bifurcated iodine···(metal–iodide) contact were obtained. In addition to classical halogen bonding, single-crystal X-ray diffraction analysis revealed a rare type of metal-involved stabilizing contact in both cocrystals. The nature of the noncovalent contact was studied computationally (via DFT, electrostatic surface potential, electron localization function, quantum theory of atoms in molecules, and noncovalent interactions plot methods). Studies confirmed that the I···I halogen bond is the strongest noncovalent interaction in the systems, followed …

chemistry.chemical_classificationplatinaHalogen bondhalogeenit010405 organic chemistryChemistryIsocyanideAtoms in moleculeskompleksiyhdisteet010402 general chemistrypalladium01 natural sciencesCocrystalElectron localization function0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographykemialliset sidoksetNucleophileNon-covalent interactionsPhysical and Theoretical ChemistryIsostructuralmetallit
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The H2C(X)–X•••X– (X = Cl, Br) Halogen Bonding of Dihalomethanes

2017

The dihalomethane–halide H2C(X)–X···X– (X = Cl, Br) halogen bonding was detected in a series of the cis-[PdX(CNCy){C(NHCy)═NHC6H2Me2NH2}]X•CH2X2 (X = Cl, Br) associates by single-crystal XRD followed by DFT calculations. Although ESP calculations demonstrated that the σ-hole of dichloromethane is the smallest among all halomethane solvents (the maximum electrostatic potential is only 2.6 kcal/mol), the theoretical DFT calculations followed by Bader’s QTAIM analysis (M06/DZP-DKH level of theory) confirmed the H2C(X)–X···X– halogen bond in both the solid-state and gas-phase optimized geometries. The estimated bonding energy in H2C(X)–X···X– is in the 1.9–2.8 kcal/mol range. peerReviewed

halogen bondingdihalomethanes
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Intermolecular hydrogen bonding H···Cl− in the solid palladium(II)-diaminocarbene complexes

2017

Abstract Weak intermolecular non-covalent H···Cl− interactions in the solid chelated palladium(II)-diaminocarbene complex cis-[PdCl(CNXyl){C(NHXyl)=NHC6H2Me2 NH2}]Cl (3; Xyl=2,6-Me2C6H3) were studied by XRD followed by appropriate DFT calculations. The N–H···Cl contacts for both NH groups in the carbene moiety are different (N1–H···Cl2 3.5258(19), N2–H···Cl2 3.0797(17) Å). The DFT calculations and topological analysis of the electron density distribution within the formalism of Bader’s theory (QTAIM method) were performed for a model cluster of the carbene complex 3. The theoretical data confirmed that the strength of intermolecular HB H···Cl− is different for two NH-protons of the carbene …

Materials science010405 organic chemistryHydrogen bondIntermolecular forcechemistry.chemical_element010402 general chemistryCondensed Matter PhysicsPhotochemistry01 natural sciences0104 chemical sciencesInorganic ChemistrychemistryGeneral Materials SciencePalladiumZeitschrift für Kristallographie - Crystalline Materials
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Palladium-ADC complexes as efficient catalysts in copper-free and room temperature Sonogashira coupling

2014

Abstract The metal-mediated coupling between cis-[PdCl2(CNR1)2] [R1 = cyclohexyl (Cy) 1, t-Bu 2, 2,6-Me2C6H3 (Xyl) 3, 2-Cl-6-MeC6H3 4] and hydrazones H2NN CR2R3 [R2, R3 = Ph 5; R2, R3 = C6H4(OMe-4) 6; R2/R3 = 9-fluorenyl 7; R2 = H, R3 = C6H4(OH-2) 8] provided carbene complexes cis-[PdCl2{C(N(H)N CR2R3) N(H)R1}(CNR1)] (9–24) in good (80–85%) yields. Complexes 9–24 showed high activity [yields up to 99%, and turnover numbers (TONs) up to 3.7 × 104] in the Sonogashira coupling of various aryl iodides with a range of substituted aromatic alkynes without the need of copper co-catalyst. The catalytic procedure runs at 80 °C for 1 h in EtOH using K2CO3 as a base. No formation of homocoupling or ac…

Process Chemistry and TechnologyArylchemistry.chemical_elementSonogashira couplingDecompositionCopperMedicinal chemistryCatalysisCatalysischemistry.chemical_compoundAcetylenechemistryOrganic chemistryPhysical and Theoretical ChemistryCarbeneta116PalladiumJournal of Molecular Catalysis A: Chemical
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Application of palladium complexes bearing acyclic amino(hydrazido)carbene ligands as catalysts for copper-free Sonogashira cross-coupling

2015

Abstract Metal-mediated coupling of one isocyanide in cis-[PdCl2(CNR1)2] (R1 = C6H11 (Cy) 1, tBu 2, 2,6-Me2C6H3 (Xyl) 3, 2-Cl-6-MeC6H3 4) and various carbohydrazides R2CONHNH2 [R2 = Ph 5, 4-ClC6H4 6, 3-NO2C6H4 7, 4-NO2C6H4 8, 4-CH3C6H4 9, 3,4-(MeO)2C6H3 10, naphth-1-yl 11, fur-2-yl 12, 4-NO2C6H4CH2 13, Cy 14, 1-(4-fluorophenyl)-5-oxopyrrolidine-3-yl 15, (pyrrolidin-1-yl)C(O) 16, 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propane-1-yl 17, EtNHC(O) 18] or sulfohydrazides R3SO2NHNH2 [R3 = Ph 19, 4-MeC6H4 20] led to a series of (hydrazido)(amino)carbene complexes cis-[PdCl2{ C (NHNHX) N(H)R1}(CNR1)]; X = COR2, SO2R3 (21–48, isolated yields 60–96%). All prepared species were characterized by elemental…

StereochemistryIsocyanideArylchemistry.chemical_elementSonogashira couplingCopper-free Sonogashira couplingAcyclic diaminocarbenesNuclear magnetic resonance spectroscopyPalladium-(acyclic diminocarbene) catalystsMedicinal chemistryCatalysisCatalysischemistry.chemical_compoundchemistryCatalytic cycleMechanism of catalytic action of Pd-ADCsPhysical and Theoretical Chemistryta116CarbenePalladiumJournal of Catalysis
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Diversity of Isomerization Patterns and Protolytic Forms in Aminocarbene PdII and PtII Complexes Formed upon Addition of N,N′-Diphenylguanidine to Me…

2017

Reaction of the palladium(II) and platinum(II) isocyanide complexes cis-[MCl2(CNR)2] [M = Pd, R = C6H3(2,6-Me2) (Xyl), 2-Cl-6-MeC6H3, cyclohexyl (Cy), t-Bu, C(Me)2CH2(Me)3 (1,1,3,3-tetramethylbuth-1-yl abbreviated as tmbu); M = Pt, R = Xyl, 2-Cl-6-MeC6H3, Cy, t-Bu, and tmbu] with N,N′-diphenylguanidine (DPG) leads to DPG-derived metal-bound deprotonated acyclic diaminocarbene (ADC) species. This reaction occurs via a two-step process, involving the initial coupling of the guanidine with one of the isocyanides and leading to deprotonated monocarbene monochelated species, while the next addition grants the deprotonated bis-carbene bis-chelated metal compounds. DPG behaves as nucleophile, depr…

protolytic forms010405 organic chemistryStereochemistryIsocyanideOrganic ChemistrySubstituentchemistry.chemical_elementRegioselectivityaminocarbene complexes010402 general chemistry01 natural sciencesMedicinal chemistry0104 chemical sciencesdiversityInorganic Chemistrychemistry.chemical_compoundDeprotonationchemistryNucleophileisomerization patternsPhysical and Theoretical ChemistryGuanidineIsomerizationta116PalladiumOrganometallics
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Reaction mechanism of regioisomerization in binuclear (diaminocarbene)PdII complexes

2021

Abstract A series of binuclear PdII carbene complexes were synthesized via the treatment of cis-[PdCl2(CNXyl)2] (1) with benzo-1,3-thiazol-2-amines (2–6) and structurally characterized. In every case the reaction leads to the mixture of two regioisomers, which are able to interconvert. The study of the regioisomerization of the binuclear diaminocarbene species showed that it is a first-order reaction, that is, it occurs intramolecularly, and was analyzed with the Hammett function. Electron-withdrawing substituents in the benzothiazole moiety of the complexes as well as increasing the solvent polarity accelerate the reaction. The solvent donor strength correlates less well with the isomeriza…

Reaction mechanismMedicinal chemistryInorganic ChemistrySolventchemistry.chemical_compoundchemistryBenzothiazoleMaterials ChemistrySolvent polarityStructural isomerMoietyPhysical and Theoretical ChemistryCarbeneIsomerizationInorganica Chimica Acta
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The H2C(X)–X•••X– (X = Cl, Br) Halogen Bonding of Dihalomethanes

2017

The dihalomethane–halide H2C(X)–X···X– (X = Cl, Br) halogen bonding was detected in a series of the cis-[PdX(CNCy){C(NHCy)═NHC6H2Me2NH2}]X•CH2X2 (X = Cl, Br) associates by single-crystal XRD followed by DFT calculations. Although ESP calculations demonstrated that the σ-hole of dichloromethane is the smallest among all halomethane solvents (the maximum electrostatic potential is only 2.6 kcal/mol), the theoretical DFT calculations followed by Bader’s QTAIM analysis (M06/DZP-DKH level of theory) confirmed the H2C(X)–X···X– halogen bond in both the solid-state and gas-phase optimized geometries. The estimated bonding energy in H2C(X)–X···X– is in the 1.9–2.8 kcal/mol range.

Halogen bond010405 organic chemistryHalomethaneGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesdihalomethanes0104 chemical scienceschemistry.chemical_compoundCrystallographychemistryComputational chemistryhalogen bondingGeneral Materials ScienceBond energyta116DichloromethaneCrystal Growth and Design
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Intermolecular hydrogen bonding H···Cl in crystal structure of palladium(II)-bis(diaminocarbene) complex

2018

Abstract The reaction of bis(isocyanide)palladium complex cis-[PdCl2(CNXyl)2] (Xyl=2,6-Me2C6H3) with excess of 4,5-dichlorobenzene-1,2-amine in a C2H4Cl2/MeOH mixture affords monocationic bis(diaminocarbene) complex cis-[PdClC{(NHXyl)=NHC6H2Cl2 NH2}{C(NHXyl)=NHC6H2Cl2NH2}]Cl (3) in moderate yield (42%). Complex 3 exists in the solid phase in the H-bonded dimeric associate of two single charged organometallic cations and two chloride anions according to X-ray diffraction data. The Hirshfeld surface analysis for the X-ray structure of 3 reveals that the crystal packing is determined primarily by intermolecular contacts H–Cl, H–H, and H–C. The intermolecular hydrogen bonds N–H···Cl and C–H···C…

chemistry.chemical_classificationMaterials science010405 organic chemistryHydrogen bondIntermolecular forcechemistry.chemical_elementCrystal structure010402 general chemistryCondensed Matter Physics01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographychemistryNon-covalent interactionsGeneral Materials SciencePalladiumZeitschrift für Kristallographie - Crystalline Materials
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Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Stru…

2016

Coupling of the palladium-bis(isocyanide) complexes cis-[PdCl2(CNR)2] (R = 2,6-Me2C6H3 1, 2-Cl-6-MeC6H3 2) with benzene-1,3-diamine (BDA1) leads to the diaminocarbene species cis-[PdCl2(CNR){C(NHR)═NH(1,3-C6H4NH2)}] (5 and 6, respectively). In this reaction, BDA1 behaves as a monofunctional nucleophile that adds to one of the RNC ligands by one amino group. By contrast, the reaction of 1 and 2 with benzene-1,4-diamine (BDA2) involves both amino functionalities of the diamine and leads to the binuclear species [cis-PdCl2(CNR){μ-C(NHR)═NH(1,4-C6H4)NH═C(NHR)}-(cis)-PdCl2(CNR)] (6 and 7) featuring two 1,4-bifunctional diaminocarbene ligands. The reaction of cis-[PdCl2(CNR)2] (R = cyclohexyl 3) …

benzenediamines010405 organic chemistryStereochemistryIsocyanideOrganic Chemistrychemistry.chemical_elementdiaminocarbenespalladium complexes010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryNucleophileDiamineisomersPhysical and Theoretical ChemistryCarbeneta116PalladiumOrganometallics
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CCDC 2054859: Experimental Crystal Structure Determination

2021

Related Article: Margarita Bulatova, Daniil M. Ivanov, J. Mikko Rautiainen, Mikhail A. Kinzhalov, Khai-Nghi Truong, Manu Lahtinen, Matti Haukka|2021|Inorg.Chem.|60|13200|doi:10.1021/acs.inorgchem.1c01591

Space GroupCrystallographyCrystal Systembis{[(26-dimethylphenyl)azanylidyne]methyl}-bis(iodo)-palladium iodineCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1966338: Experimental Crystal Structure Determination

2020

Related Article: Alexander S. Mikherdov, Roman A. Popov, Mikhail A. Kinzhalov, Matti Haukka, Valeriy A. Polukeev, Vadim P. Boyarskiy, Andreas Roodt|2021|Inorg.Chim.Acta|514|120012|doi:10.1016/j.ica.2020.120012

[mu-[(6-methyl-13-benzothiazol-2-yl){[(26-dimethylphenyl)imino]methanidyl}amino][(26-dimethylphenyl)imino]methyl]-dichloro-bis(N-(26-dimethylphenyl)cyano)-di-palladium(ii) unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825193: Experimental Crystal Structure Determination

2019

Related Article: Mikhail A. Kinzhalov, Sergey V. Baykov, Alexander S. Novikov, Matti Haukka, Vadim P. Boyarskiy|2019|Z.Krist.Cryst.Mater.|234|155|doi:10.1515/zkri-2018-2100

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis{[(2-amino-45-dichlorophenyl)amino][(26-dimethylphenyl)amino]methylidene}-(chloro)-palladium(ii) chlorideExperimental 3D Coordinates
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CCDC 1513981: Experimental Crystal Structure Determination

2018

Related Article: Mikhail A. Kinzhalov, Alexander S. Novikov, Alexander N. Chernyshev and Vitalii V. Suslonov|2017|Z.Kristallogr.|232|299|doi:10.1515/zkri-2016-2018

Space GroupCrystallographyCrystal System((2-amino-45-dimethylanilino)(26-dimethylanilino)methylidene)-(2-isocyano-13-dimethylbenzene)-chloro-palladium(ii) chloride dichloromethane solvate monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 912875: Experimental Crystal Structure Determination

2013

Related Article: Mikhail A. Kinzhalov, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Matti Haukka, and Vadim Yu. Kukushkin|2013|Organometallics|32|5212|doi:10.1021/om4007592

Space GroupCrystallographydichloro-((cyclohexylamino)(2-(phenylsulfonyl)hydrazino)methylene)-(cyclohexylisocyanido)-palladiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1501943: Experimental Crystal Structure Determination

2016

Related Article: Elena A. Valishina, M. Fátima C. Guedes da Silva, Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Tatyana M. Buslaeva, Matti Haukka, Armando J.L. Pombeiro , Vadim P. Boyarskiy, Vadim Yu. Kukushkin, Konstantin V. Luzyanin|2014|J.Mol.Catal.A:Chem.|395|162|doi:10.1016/j.molcata.2014.08.018

Space GroupCrystallography((2-(bis(4-methoxyphenyl)methylene)hydrazino)((26-dimethylphenyl)amino)methylene)-dichloro-(N-(26-dimethylphenyl)cyano)-palladiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1541823: Experimental Crystal Structure Determination

2017

Related Article: Svetlana A. Katkova, Mikhail A. Kinzhalov, Peter M. Tolstoy, Alexander S. Novikov, Vadim P. Boyarskiy, Anastasiia Yu. Ananyan, Pavel V. Gushchin, Matti Haukka, Andrey A. Zolotarev, Alexander Yu. Ivanov, Semen S. Zlotsky, Vadim Yu. Kukushkin|2017|Organometallics|36|4145|doi:10.1021/acs.organomet.7b00569

bis{(t-butylamino)[(NN'-diphenylcarbamimidoyl)imino]methyl}-palladium(ii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1501944: Experimental Crystal Structure Determination

2016

Related Article: Elena A. Valishina, M. Fátima C. Guedes da Silva, Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Tatyana M. Buslaeva, Matti Haukka, Armando J.L. Pombeiro , Vadim P. Boyarskiy, Vadim Yu. Kukushkin, Konstantin V. Luzyanin|2014|J.Mol.Catal.A:Chem.|395|162|doi:10.1016/j.molcata.2014.08.018

Space GroupCrystallographyCrystal SystemCrystal Structuredichloro-(((26-dimethylphenyl)amino)(2-(9H-fluoren-9-ylidene)hydrazino)methylene)-((26-dimethylphenyl)cyano)-palladium chloroform solvateCell ParametersExperimental 3D Coordinates
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CCDC 1966337: Experimental Crystal Structure Determination

2020

Related Article: Alexander S. Mikherdov, Roman A. Popov, Mikhail A. Kinzhalov, Matti Haukka, Valeriy A. Polukeev, Vadim P. Boyarskiy, Andreas Roodt|2021|Inorg.Chim.Acta|514|120012|doi:10.1016/j.ica.2020.120012

Space GroupCrystallographyCrystal SystemCrystal Structure[mu-[(13-benzothiazol-2-yl){[(26-dimethylphenyl)imino]methanidyl}amino][(26-dimethylphenyl)imino]methyl]-dichloro-bis(N-(26-dimethylphenyl)cyano)-di-palladium(ii) unknown solvateCell ParametersExperimental 3D Coordinates
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CCDC 1542914: Experimental Crystal Structure Determination

2017

Related Article: Svetlana A. Katkova, Mikhail A. Kinzhalov, Peter M. Tolstoy, Alexander S. Novikov, Vadim P. Boyarskiy, Anastasiia Yu. Ananyan, Pavel V. Gushchin, Matti Haukka, Andrey A. Zolotarev, Alexander Yu. Ivanov, Semen S. Zlotsky, Vadim Yu. Kukushkin|2017|Organometallics|36|4145|doi:10.1021/acs.organomet.7b00569

Space GroupCrystallographyCrystal SystemCrystal Structurechloro-{(cyclohexylamino)[(NN'-diphenylcarbamimidoyl)imino]methyl}-[cyclohexyl isocyanadide]-platinumCell ParametersExperimental 3D Coordinates
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CCDC 1435501: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis((2-Amino-45-dimethylphenylamino)(2-chloro-6-methylphenylamino)methylidene-CN)-palladium(ii) dichloride acetonitrile solvateExperimental 3D Coordinates
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CCDC 1435504: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates((2-Amino-45-dimethylphenylamino)(2-chloro-6-methylphenylamino)methylidene-CN)-chloro-(N-(2-chloro-6-methylphenyl)cyano)-palladium(ii) chloride dichloromethane solvate
researchProduct

CCDC 1435506: Experimental Crystal Structure Determination

2016

Related Article: Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Anton A. Yakimanskiy, Matti Haukka, Vadim Yu. Kukushkin|2016|Organometallics|35|218|doi:10.1021/acs.organomet.5b00936

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-((3-aminophenyl)(26-dimethylphenylamino)methylidene)-(N-(26-dimethylphenyl)cyano)-palladium(ii)Experimental 3D Coordinates
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CCDC 912877: Experimental Crystal Structure Determination

2013

Related Article: Mikhail A. Kinzhalov, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Matti Haukka, and Vadim Yu. Kukushkin|2013|Organometallics|32|5212|doi:10.1021/om4007592

chloro-((cyclohexylamino)(2-(3-nitrobenzoyl)hydrazino)methylene)-(cyclohexylisocyanido)-(triphenylphosphine)-palladium chlorideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2054860: Experimental Crystal Structure Determination

2021

Related Article: Margarita Bulatova, Daniil M. Ivanov, J. Mikko Rautiainen, Mikhail A. Kinzhalov, Khai-Nghi Truong, Manu Lahtinen, Matti Haukka|2021|Inorg.Chem.|60|13200|doi:10.1021/acs.inorgchem.1c01591

Space GroupCrystallographyCrystal SystemCrystal Structurebis{N-(26-dimethylphenyl)cyano}-bis(iodo)-platinumCell ParametersExperimental 3D Coordinates
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CCDC 912876: Experimental Crystal Structure Determination

2013

Related Article: Mikhail A. Kinzhalov, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Matti Haukka, and Vadim Yu. Kukushkin|2013|Organometallics|32|5212|doi:10.1021/om4007592

Space GroupCrystallographydichloro-(((2-chloro-6-methylphenyl)amino)(2-(phenylsulfonyl)hydrazino)methylene)-((2-chloro-6-methylphenyl)isocyanido)-palladium dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1414621: Experimental Crystal Structure Determination

2015

Related Article: Mikhail A. Kinzhalov, Alexander S. Novikov, Konstantin V. Luzyanin, Matti Haukka, Armando J. L. Pombeiro, Vadim Yu. Kukushkin|2016|New J.Chem.|40|521|doi:10.1039/C5NJ02564H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(1-t-butyl-1H-tetrazol-5-yl)-chloro-bis(triphenylphosphine)-palladium(ii) 2-isopropoxypropane solvateExperimental 3D Coordinates
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CCDC 1501945: Experimental Crystal Structure Determination

2016

Related Article: Elena A. Valishina, M. Fátima C. Guedes da Silva, Mikhail A. Kinzhalov, Svetlana A. Timofeeva, Tatyana M. Buslaeva, Matti Haukka, Armando J.L. Pombeiro , Vadim P. Boyarskiy, Vadim Yu. Kukushkin, Konstantin V. Luzyanin|2014|J.Mol.Catal.A:Chem.|395|162|doi:10.1016/j.molcata.2014.08.018

Space GroupCrystallographydichloro-(((2-chloro-6-methylphenyl)amino)(2-(2-hydroxybenzylidene)hydrazino)methylene)-((2-chloro-6-methylphenyl)cyano)-palladiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1541822: Experimental Crystal Structure Determination

2017

Related Article: Svetlana A. Katkova, Mikhail A. Kinzhalov, Peter M. Tolstoy, Alexander S. Novikov, Vadim P. Boyarskiy, Anastasiia Yu. Ananyan, Pavel V. Gushchin, Matti Haukka, Andrey A. Zolotarev, Alexander Yu. Ivanov, Semen S. Zlotsky, Vadim Yu. Kukushkin|2017|Organometallics|36|4145|doi:10.1021/acs.organomet.7b00569

Space GroupCrystallographyCrystal System{(t-butylamino)[(NN'-diphenylcarbamimidoyl)imino]methyl}-[t-butyl isocyanide]-chloro-palladium(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2054861: Experimental Crystal Structure Determination

2021

Related Article: Margarita Bulatova, Daniil M. Ivanov, J. Mikko Rautiainen, Mikhail A. Kinzhalov, Khai-Nghi Truong, Manu Lahtinen, Matti Haukka|2021|Inorg.Chem.|60|13200|doi:10.1021/acs.inorgchem.1c01591

Space GroupCrystallographyCrystal SystemCrystal Structurebis{N-(26-dimethylphenyl)cyano}-bis(iodo)-palladiumCell ParametersExperimental 3D Coordinates
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CCDC 1542913: Experimental Crystal Structure Determination

2017

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