0000000001299570

AUTHOR

Gerald Kehr

showing 62 related works from this author

Zirconocene complexes bearing novel 3-dimethylamino-1,2-dihydropentalene derived ligand systems.

2010

Coupling of the N,N-dimethylacrylamides 6a-c with cyclopentadienide resulted in the formation of the substituted 3-dimethylamino-1,2-dihydropentalnenes 2a-c. Deprotonation followed by metallation with CpZrCl(3)·DME gave the substituted zirconocenes 12a-c. The reaction of 3-dimethylamino-1-methyl-dihydropentalene 2a with ZrCl(2)(NMe(2))(2)·2THF resulted in a unique coupling between a pair of the aminodihydropentalene derivatives to yield an unsymmetrically bridged novel ansa-zirconocene framework (9a). Treatment of the 1,1-dimethyl-substituted substrate 2b with this Zr-amido reagent in contrast resulted in a clean deprotonation and formation of the unbridged bis(dimethylaminohydropentalenyl)…

Inorganic ChemistryDeprotonationChemistryLigandStereochemistryReagentYield (chemistry)Substrate (chemistry)Medicinal chemistryDalton transactions (Cambridge, England : 2003)
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Insertion Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated Lewis Pair Territory

2016

International audience; Neutral phosphidozirconocene complexes [Cp2Zr(PR2)Me] (Cp=cyclopentadienyl; 1a: R=cyclohexyl (Cy); 1b: R=mesityl (Mes); 1c: R=tBu) undergo insertion into the Zr-P bond by non-enolisable carbonyl building blocks (O=CRR), such as benzophenone, aldehydes, paraformaldehyde or CO2, to give [Cp2Zr(OCRRPR2)Me] (3-7). Depending on the steric bulk around P, complexes 3-7 react with B(C6F5)(3) to give O-bridged cationic zirconocene dimers that display typical frustrated Lewis pair (FLP)/ambiphilic ligand behaviour. Thus, the reaction of {[Cp2Zr(-OCHPhPCy2)][MeB(C6F5)(3)]}(2) (10a) with chalcone results in 1,4 addition of the Zr+/P FLP, whereas the reaction of {[Cp2Zr(-OCHFcPCy…

Steric effectsChalconeStereochemistryzirconiumc-h activation010402 general chemistry01 natural sciencesMedicinal chemistry[ CHIM ] Chemical SciencesCatalysisFrustrated Lewis pairinsertionchemistry.chemical_compoundCyclopentadienyl complexx-ray structuresphosphinidene complexesBenzophenone[CHIM]Chemical SciencesParaformaldehydezr-p bondzirconocene-phosphido complexesmolecular-structure010405 organic chemistryLigandphosphidesOrganic ChemistryCationic polymerizationcrystal-structureGeneral Chemistry0104 chemical sciencesfunctionalized ligandsbis(trimethylsilyl)phosphido complexeschemistryfrustrated Lewis pairsphosphinoaryloxide complexesambiphilic ligands
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Versatile behavior of conjugated diynes with zirconocene reactive species

2008

Thermal decomposition of Cp2ZrPh2 in the presence of the buta-1,3-diynes RC≡CC≡CR (R = Ph, SiMe3) can lead to seven- or five-membered metallacycles. In both cases a stable benzo-fused seven-membered zirconacyclocumulene arising from a 2-fold insertion of the triple bonds of the dialkyne in the in situ generated zirconocene benzyne is formed. In the case of Me3SiC≡CC≡CSiMe3 a second minor complex is isolated: a 3-alkynyl-substituted zirconaindene arising from a β monoinsertion of one acetylenic function of the conjugated diyne in the zirconocene benzyne. No stable 2-alkynyl-substituted zirconacycle was isolated. This α monoinsertion complex is an intermediate in the exchange of the metalated…

010405 organic chemistryChemistrycycloaddition reactionOrganic ChemistryThermal decomposition[ CHIM.COOR ] Chemical Sciences/Coordination chemistrychemistry.chemical_elementmetalationConjugated system010402 general chemistryTriple bond01 natural sciencesAryne0104 chemical sciencesInorganic ChemistrycyclometalationAntimonyReagentAtomPolymer chemistryMoiety[CHIM.COOR]Chemical Sciences/Coordination chemistryzirconocene- benzyn intermediatePhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUS
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Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry

2015

Methyl abstraction from neutral [Cp2ZrMe(ERR')] complexes 1 (E = N, P; R, R' = alkyl, aryl) with either B(C6F5)3 or [Ph3C][B(C6F5)4] results in the formation of [Cp2Zr(ERR')][X] complexes 2 (X(-) = MeB(C6F5)3(-), B(C6F5)4(-)). The X-ray structure of amido complexes [Cp2Zr(NPh2)][MeB(C6F5)3] (2d) and [Cp2Zr(N(t)BuAr)][B(C6F5)4] (2e', Ar = 3,5-C6H3(CH3)2) is reported, showing a sterically dependent Zr/N-π interaction. Complexes 2 catalyze the hydrogenation of electron-rich olefins and alkynes under mild conditions (room temperature, 1.5 bar H2). Complex 2e binds CO2, giving [Cp2Zr(CO2)(N(t)BuAr)]2[MeB(C6F5)3]2 (3e). Amido complex 2d reacts with benzaldehyde yielding [Cp2Zr(OCH2Ph)((OC)PhNPh2)…

chemistry.chemical_classificationSteric effectsStereochemistryArylGeneral ChemistryBiochemistryMedicinal chemistryCatalysisFrustrated Lewis pairBenzaldehydechemistry.chemical_compoundColloid and Surface ChemistrychemistryDiphenylacetyleneAlkylJournal of the American Chemical Society
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A Route toward (Aminomethyl)cyclopentadienide Ligands and Their Group 4 Metal Complexes

2018

International audience

Zirconium010405 organic chemistryChemistrychemistry.chemical_element010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic ChemistryMetalGroup (periodic table)visual_artPolymer chemistryvisual_art.visual_art_medium[CHIM.COOR]Chemical Sciences/Coordination chemistryComputingMilieux_MISCELLANEOUSTitanium
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ChemInform Abstract: Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry.

2016

Methyl abstraction from neutral [Cp2ZrMe(ERR′)] complexes 1 (E = N, P; R, R′ = alkyl, aryl) with either B(C6F5)3 or [Ph3C][B(C6F5)4] results in the formation of [Cp2Zr(ERR′)][X] complexes 2 (X– = MeB(C6F5)3–, B(C6F5)4–). The X-ray structure of amido complexes [Cp2Zr(NPh2)][MeB(C6F5)3] (2d) and [Cp2Zr(NtBuAr)][B(C6F5)4] (2e′, Ar = 3,5-C6H3(CH3)2) is reported, showing a sterically dependent Zr/N−π interaction. Complexes 2 catalyze the hydrogenation of electron-rich olefins and alkynes under mild conditions (room temperature, 1.5 bar H2). Complex 2e binds CO2, giving [Cp2Zr(CO2)(NtBuAr)]2[MeB(C6F5)3]2 (3e). Amido complex 2d reacts with benzaldehyde yielding [Cp2Zr(OCH2Ph)((OC)PhNPh2)][MeB(C6F5…

chemistry.chemical_classificationBenzaldehydeSteric effectschemistry.chemical_compoundchemistryArylGeneral MedicineDiphenylacetyleneMedicinal chemistryAlkylFrustrated Lewis pairChemInform
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Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and Alkynes

2010

ChemistryIntramolecular forceOrganic ChemistryOrganic chemistryGeneral ChemistryLewis acids and basesMedicinal chemistryCatalysisFrustrated Lewis pairChemistry - A European Journal
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Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex.

2016

International audience; We report that the cationic phosphidozirconocene complex [(eta(5)-C5H5)(2)Zr(PCy2)][CH3B(C6F5)(3)] (II) reacts with azobenzene, resulting in the expedient formation of Zr complex (2) bound to a tridentate PNN ligand. This reaction proceeds by a mechanism of cooperative nucleophilic substitution of hydrogen. The intermediate sigma(H) adduct (1) has been characterized by NMR spectroscopy.

ortho-acylationHydrogenaromatic azo-compoundschemistry.chemical_element[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryBioinformatics01 natural sciences[ CHIM ] Chemical SciencesAdductalcoholsInorganic Chemistrychemistry.chemical_compoundc-h functionalizationPolymer chemistryNucleophilic substitution[CHIM]Chemical Sciences010405 organic chemistryChemistryLigandCationic polymerizationcinnolinium salts[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryNuclear magnetic resonance spectroscopy0104 chemical sciences3. Good healthAzobenzeneazoxybenzenesalpha-oxocarboxylic acidsazoareneshydrogennucleophilic-substitutionSurface modificationDalton transactions (Cambridge, England : 2003)
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Synthetic Endeavors toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and Steric Properties

2015

A new family of cationic Ti complexes 4′ with a pendant phosphine of general formula [CpCpPTiOAr][BPh4] (Cp = η5-C5H5; CpP = η5-C5H4(CMe2)PR2) has been prepared in four steps from 6,6-dimethylfulvene. These complexes were designed to behave as Ti based frustrated Lewis pairs (FLPs). The key synthetic step is a reduction–oxidation sequence from [CpCpPTiClOAr] complexes 3 using lithium phosphide salts as the reductants and ferricinium tetraphenylborate as the oxidant. Four complexes have been structurally characterized by X-ray diffraction and show elongated Ti–P bonds, above 2.60 A. One complex (4b′: OAr = 2,6-Me2C6H3; PR2 = PCy2) reacted with benzaldehyde to form a typical FLP activation pr…

Steric effectsTetraphenylboratePhosphideStereochemistryOrganic ChemistryCationic polymerizationFrustrated Lewis pairInorganic ChemistryBenzaldehydechemistry.chemical_compoundchemistryPolymer chemistryPhosphoniumPhysical and Theoretical ChemistryPhosphineOrganometallics
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The Taming of Redox‐Labile Phosphidotitanocene Cations

2019

International audience; Tame d0 phosphidotitanocene cations stabilized with a pendant tertiary phosphane arm are reported. These compounds were obtained by one-electron oxidation of d1 precursors with [Cp2Fe][BPh4]. The electronic structure of these compounds was studied experimentally (EPR, UV/Vis, and NMR spectroscopy, X-ray diffraction analysis) and through DFT calculations. The theoretical analysis of the bonding situation by using the electron localization function (ELF) shows the presence of π-interactions between the phosphido ligand and Ti in the d0 complexes, whereas dπ–pπ repulsion prevents such interactions in the d1 complexes. In addition, CH–π interactions were observed in seve…

010402 general chemistry01 natural sciencesRedoxTransition metal phosphidesCatalysisFrustrated Lewis pairlaw.inventionchemistry.chemical_compoundFrustrated Lewis Pair (FLP)[CHIM.ANAL]Chemical Sciences/Analytical chemistrylaw[CHIM.COOR]Chemical Sciences/Coordination chemistryPhosphorus LigandsElectron paramagnetic resonanceDiphenylacetyleneComputingMilieux_MISCELLANEOUSTitanium[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryLigandOrganic Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryGeneral ChemistryNuclear magnetic resonance spectroscopyElectron localization function0104 chemical sciencesHomolysis[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryDensity Functional Theory (DFT)Crystallographychemistry[CHIM.CHEM]Chemical Sciences/CheminformaticsChemistry – A European Journal
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Cover Feature: A Route toward (Aminomethyl)cyclopentadienide Ligands and Their Group 4 Metal Complexes (Eur. J. Inorg. Chem. 34/2018)

2018

Inorganic ChemistryMetalFeature (computer vision)ChemistryStereochemistryGroup (periodic table)visual_artvisual_art.visual_art_mediumCover (algebra)European Journal of Inorganic Chemistry
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CCDC 1421130: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(di-t-butylphospheanyl)-methyl-zirconiumExperimental 3D Coordinates
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CCDC 1424182: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal System((Dicyclohexylphosphino)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871410: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iv) tetraphenylborateExperimental 3D Coordinates
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CCDC 1871415: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(diphenylphosphanyl)-(diphenylphosphine)-titanium(iv) tetrakis(pentafluorophenyl)borateExperimental 3D Coordinates
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CCDC 1871416: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iv) tetraphenylborate tetrahydrofuran solvateExperimental 3D Coordinates
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CCDC 1871408: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal System(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825467: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographyCrystal SystemCrystal Structuretrichloro-((2266-tetramethylpiperidinylmethyl)-cyclopentadienyl)-titaniumCell ParametersExperimental 3D Coordinates
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CCDC 1053357: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal Structure(1-((2-(bis(2-methylphenyl)phosphino)-1-methyl)ethyl)cyclopentadienyl)-(cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborateCell ParametersExperimental 3D Coordinates
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CCDC 1825466: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographydichloro-bis((dibenzylamino)-cyclopentadienyl)-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424183: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-(Dicyclohexylphosphino)methanolato)-tetrakis(eta5-cyclopentadienyl)-di-zirconium tetrakis(pentafluorophenyl)borate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1424177: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographybis(eta5-Cyclopentadienyl)-((dimesitylphosphino)(phenyl)methanolato)-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825460: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

dichloro-cyclopentadienyl-((2266-tetramethylpiperidinylmethyl)-cyclopentadienyl)-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052598: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallography(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-titanium tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421134: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(tert-butyl(35-dimethylphenyl)amido)-zirconium tetrakis(pentafluorophenyl)borate unknown solvateExperimental 3D Coordinates
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CCDC 1825463: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographydichloro-cyclopentadienyl-((di-isopropylammoniomethyl)-cyclopentadienyl)-titanium chlorideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052596: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(eta5-cyclopentadienyl)-phenolato-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-titanium tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871418: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(3-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-diphenylphosphanyl-(eta5-cyclopentadienyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1871412: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(2-(dicyclohexylphosphanyl)-12-diphenylethenyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1421135: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-t-butyl(35-dimethylphenyl)carbamato)-tetrakis(eta5-cyclopentadienyl)-di-zirconium bis(methyl(tris(pentafluorophenyl))borate) unknown solvateExperimental 3D Coordinates
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CCDC 1825459: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-((dibenzylaminomethyl)-cyclopentadienyl)-cyclopentadienyl-titaniumExperimental 3D Coordinates
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CCDC 1052597: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1871414: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographybis(eta5-cyclopentadienyl)-bis(tetrahydrofuran)-titanium(iii) tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052593: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-phenolato-chloro-titaniumExperimental 3D Coordinates
researchProduct

CCDC 1421138: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(3-(dicyclohexyl[12-diphenylethenyl]phosphonio)-13-diphenylprop-1-en-1-olato)-zirconium tetrakis(35-bis(trifluoromethyl)phenyl)borate unknown solvateExperimental 3D Coordinates
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CCDC 1053358: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(cyclopentadienyl)-([dicyclohexyl(2-cyclopentadienylpropan-2-yl)phosphaniumyl](phenyl)methoxy)-(26-dimethylphenolato)-titanium tetraphenylborate tetrahydrofuran solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1825465: Experimental Crystal Structure Determination

2018

Related Article: Quentin Bonnin, Sook-Yen Wong, Cedric Balan, Virginie Comte, Raluca Malacea, Marie-Jose Penouilh, Philippe Richard, Gerald Kehr, Adrien T. Normand, Gerhard Erker, Pierre Le Gendre|2018|Eur.J.Inorg.Chem.|2018|3813|doi:10.1002/ejic.201800636

dichloro-bis((dibenzylaminomethyl)-cyclopentadienyl)-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871411: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

bis(eta5-cyclopentadienyl)-(2-(dicyclohexylphosphanyl)-12-diphenylethenyl)-titanium(iv) tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421133: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal Systembis(eta5-cyclopentadienyl)-(diphenylamido)-zirconium methyl(tris(pentafluorophenyl))borateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424181: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallography(Dicyclohexylphosphinecarboxylato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1052592: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-dimethyl-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871409: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal Structure(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Cell ParametersExperimental 3D Coordinates
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CCDC 1421131: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographybis(eta5-cyclopentadienyl)-diphenylamido-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052595: Experimental Crystal Structure Determination

2015

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Space GroupCrystallography(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-(eta5-cyclopentadienyl)-chloro-titaniumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052594: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-chloro-(26-dimethylphenolato)-titaniumExperimental 3D Coordinates
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CCDC 1825462: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-cyclopentadienyl-((pyrrolidinium-1-ylmethyl)-cyclopentadienyl)-titanium chloride chloroform solvateExperimental 3D Coordinates
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CCDC 1421128: Experimental Crystal Structure Determination

2015

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bis(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-methyl-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421129: Experimental Crystal Structure Determination

2015

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bis(eta5-cyclopentadienyl)-dimesitylphosphanyl-methyl-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871417: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(dicyclohexylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1825461: Experimental Crystal Structure Determination

2018

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dichloro-cyclopentadienyl-((2266-tetramethylpiperidinylmethyl)-cyclopentadienyl)-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421132: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systembis(eta5-cyclopentadienyl)-(tert-butyl(35-dimethylphenyl)amido)-methyl-zirconiumCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825458: Experimental Crystal Structure Determination

2018

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dichloro-((di-isopropylaminomethyl)-cyclopentadienyl)-(pentamethyl-cyclopentadienyl)-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424178: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters((Di-t-butylphosphino)(phenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumExperimental 3D Coordinates
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CCDC 1440373: Experimental Crystal Structure Determination

2016

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bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenyldiazanediido)-zirconium(iv)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825464: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesdichloro-cyclopentadienyl-((2266-tetramethylpiperidiniomethyl)-cyclopentadienyl)-titanium chloride
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CCDC 1424179: Experimental Crystal Structure Determination

2016

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Space GroupCrystallography((Dicyclohexylphosphino)(diphenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconium n-pentane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1440372: Experimental Crystal Structure Determination

2016

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bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenylhydrazin-1-ido)-zirconium(iv) tetrakis(pentafluorophenyl)borateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421136: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(NN-diphenylbenzamide)-(phenylmethanolato)-zirconium tetrakis(35-bis(trifluoromethyl)phenyl)borateExperimental 3D Coordinates
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CCDC 1871413: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-{[ferrocenyl(oxido)methyl](dicyclohexyl)phosphaniumyl}-12-diphenylethenyl)-bis(eta5-pentamethylcyclopentadienyl)-titanium(iv) tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1424180: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal Structure((Di-t-butylphosphino)(diphenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCell ParametersExperimental 3D Coordinates
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CCDC 1424184: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal System(mu2-Chloro)-(mu2-(dicyclohexylphosphino)ferrocenylmethanolato-OP)-(eta3-allyl)-bis(eta5-cyclopentadienyl)-palladium-zirconium tetrakis(pentafluorophenyl)borateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421137: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(ferrocenyl(dicyclohexyl[12-diphenylethenyl]phosphonio)oxidomethyl)-zirconium tetrakis(pentafluorophenyl)borate unknown solvateExperimental 3D Coordinates
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