0000000001299573
AUTHOR
Alexander Yu. Mitrofanov
Front Cover: Facile Synthesis and Self‐Assembly of Zinc (2‐Diethoxyphosphorylethynyl)porphyrins (Eur. J. Inorg. Chem. 10/2019)
Immobilization of copper complexes with (1,10-phenanthrolinyl)phosphonates on titania supports for sustainable catalysis
Different strategies for the immobilization of copper complexes with 1,10-phenanthroline (phen) using the phosphonate anchoring group were investigated to prepare robust and porous heterogeneous catalysts. Homoleptic and heteroleptic copper(I) complexes with phen bearing the bis(trimethylsiloxy)phosphoryl anchoring group (Pphen-Si) at different positions of the phen backbone were prepared and covalently incorporated into titania (TiO2) xerogels by using the sol–gel process or grafted onto the surface of mesoporous TiO2 (SBET = 650 m2 g−1). Copper(I) bis(Pphen-Si) complexes were the only complexes that were successfully anchored onto the TiO2 surface because the heterogenization was often ac…
Supramolecular Architectures Based on Phosphonic Acid Diesters
The interest of phosphonic acid dialkyl esters for generation of metal-organic materials is discussed using derivatives of porphyrin and 1,10-phenanthroline series as representative examples.
Copper( ii ) complexes with phosphorylated 1,10-phenanthrolines: from molecules to infinite supramolecular arrays
International audience; The reaction of phosphorylated 1,10-phenanthrolines 3-Pphen, 3,8-Pphen and 4,7-Pphen (3-Pphen = 3-diethoxyphosphorylphenanthroline, 3,8-Pphen = 3,8-bis(diethoxyphosphoryl) phenanthroline, 4,7-Pphen = 4,7-bis(diethoxyphosphoryl) phenanthroline) and hydrated copper(II) nitrate in a 1 : 1 ratio leads to the formation of supramolecular architectures. In the 1D coordination polymer [Cu(3-Pphen)(NO3)(2)](n) (2) the copper atom is coordinated to only one phenanthroline ligand and the coordination sphere is completed by two oxygen atoms of nitrate anions and the oxygen atom of the phosphoryl group from the neighbouring phenanthroline ligand. Complex Cu(3,8-Pphen)(NO3)(2) (3)…
Facile Synthesis and Self‐Assembly of Zinc (2‐Diethoxyphosphorylethynyl)porphyrins
CCDC 960835: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Roger Guilard, Stéphane Brandès, Alla G. Bessmertnykh-Lemeune, Marina A. Uvarova, Sergey E. Nefedov|2016|New J.Chem.|40|5896|doi:10.1039/C5NJ03572D
CCDC 1049575: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Roger Guilard, Stéphane Brandès, Alla G. Bessmertnykh-Lemeune, Marina A. Uvarova, Sergey E. Nefedov|2016|New J.Chem.|40|5896|doi:10.1039/C5NJ03572D
CCDC 1850850: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004
CCDC 1822340: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004
CCDC 1567139: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004
CCDC 1009948: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Roger Guilard, Stéphane Brandès, Alla G. Bessmertnykh-Lemeune, Marina A. Uvarova, Sergey E. Nefedov|2016|New J.Chem.|40|5896|doi:10.1039/C5NJ03572D
CCDC 960834: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Roger Guilard, Stéphane Brandès, Alla G. Bessmertnykh-Lemeune, Marina A. Uvarova, Sergey E. Nefedov|2016|New J.Chem.|40|5896|doi:10.1039/C5NJ03572D
CCDC 1009991: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Roger Guilard, Stéphane Brandès, Alla G. Bessmertnykh-Lemeune, Marina A. Uvarova, Sergey E. Nefedov|2016|New J.Chem.|40|5896|doi:10.1039/C5NJ03572D
CCDC 1819713: Experimental Crystal Structure Determination
Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004