0000000001299704
AUTHOR
J. Suarez-varela
Electronic properties and crystal structure of aqua (mepirizole-oxalato)copper(II)monohydrate: [Cu(C11H14N4O2)C2O4·H2O]H2O
Abstract A Cu(ll) complex with mepirizole: 4-methoxy-2-(5-methoxy-3-methyl-pyrazoll-yl)-6-methylpyrimidine (L) and oxalate as ligands with the formula [CuL(C2O4)(H2O)]·H2O has been synthesized. The crystal structure has been determined by X-ray diffraction analysis: monoclinic, space group P21/n, Z = 4, a = 7.707(1), b = 14.951(3), c = 14.986(2) A,β = 92.40(2)°, V = 1725.2(8) A3, Dm = 1.61(1) g cm−3, Dc = 1.62 g cm−3, R = 0.032 and Rw = 0.035 for 2016 observed reflections. The CuN2O2O′chromophore can be described as square pyramidal strongly distorted towards trigonal bipyramidal. The basal coordination positions are occupied by the two oxygen atoms of the bidentate oxalate group, the coord…
CCDC 197426: Experimental Crystal Structure Determination
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CCDC 197425: Experimental Crystal Structure Determination
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CCDC 265840: Experimental Crystal Structure Determination
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CCDC 230756: Experimental Crystal Structure Determination
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CCDC 694344: Experimental Crystal Structure Determination
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CCDC 197427: Experimental Crystal Structure Determination
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CCDC 694345: Experimental Crystal Structure Determination
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CCDC 261533: Experimental Crystal Structure Determination
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CCDC 197428: Experimental Crystal Structure Determination
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CCDC 230755: Experimental Crystal Structure Determination
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CCDC 173686: Experimental Crystal Structure Determination
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CCDC 265841: Experimental Crystal Structure Determination
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