More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

Ruthenium and iron sandwich complexes incorporating cyclopentadienyl analogs with CB(2)N(2)(-) skeletons were characterized. Electrochemical measurements supported by computational studies revealed that in combination with larger metal ions such as Ru the CB(2)N(2)(-) ligand can be more electron-rich than its organic counterpart.

ChemInform Abstract: Weak Interactions Between Trivalent Pnictogen Centers: Computational Analysis of Bonding in Dimers X3E···EX3(E: Pnictogen, X: Halogen).

The nature of weak interactions in dimers X3E···EX3 (E = N−Bi, X = F−I) was investigated by wave function and density functional theory (DFT)-based methods. Out of the 20 systems studied, 10 are found to be bound at the CP-MP2 and LMP2 levels of theory. Detailed partition of the interaction energy into different components revealed that dispersion is the primary force holding the dimers together but there also exists an important ionic component whose contribution increases with increasing halogen size. As expected, standard density functionals fail to describe bonding in the studied systems. However, the performance of DFT methods can be easily improved via empirical dispersion correction …

Anion-driven encapsulation of cationic guests inside pyridine[4]arene dimers

Pyridine[4]arenes have previously been considered as anion binding hosts due to the electron-poor nature of the pyridine ring. Herein, we demonstrate the encapsulation of Me4N+ cations inside a dimeric hydrogen-bonded pyridine[4]arene capsule, which contradicts with earlier assumptions. The complexation of a cationic guest inside the pyridine[4]arene dimer has been detected and studied by multiple gas-phase techniques, ESI-QTOF-MS, IRMPD, and DT-IMMS experiments, as well as DFT calculations. The comparison of classical resorcinarenes with pyridinearenes by MS and NMR experiments reveals clear differences in their host–guest chemistry and implies that cation encapsulation in pyridine[4]arene…

A Simple Complex on the Verge of Breakdown: Isolation of the Elusive Cyanoformate Ion

Cyanide Hitches a Ride Cyanide is a by-product of the biosynthesis of ethylene in plants and it has been somewhat puzzling how the ion is safely removed before it can shut down enzymatic pathways by coordination to catalytic iron centers. A proposed mechanism has implicated the cyanoformate ion—essentially, a weak adduct of cyanide and carbon dioxide—as the initial product, although its lifetime was uncertain. Murphy et al. (p. 75 ; see the Perspective by Alabugin and Mohamed ) crystallized this previously elusive adduct and found that its solution-phase stability varies inversely with the dielectric properties of the medium. The results bolster a picture in which the adduct shuttles the cy…

A diamagnetic iron complex and its twisted sister – structural evidence on partial spin state change in a crystalline iron complex

We report here the syntheses of a diamagnetic Fe complex [Fe(HL)2] (1), prepared by reacting a redox non-innocent ligand precursor N,N′-bis(3,5-di-tert-butyl-2-hydroxy-phenyl)-1,2-phenylenediamine (H4L) with FeCl3, and its phenoxazine derivative [Fe(L′)2] (2), which was obtained via intra-ligand cyclisation of the parent complex. Magnetic measurements, accompanied by spectroscopic, structural and computational analyses show that 1 can be viewed as a rather unusual Fe(III) complex with a diamagnetic ground state in the studied temperature range due to a strong antiferromagnetic coupling between the low-spin Fe(III) ion and a radical ligand. For a paramagnetic high-spin Fe(II) complex 2 it wa…

Alkyl-Substituted Aminobis(phosphonates) : Efficient Precipitating Agents for Rare Earth Elements, Thorium, and Uranium in Aqueous Solutions

The efficient and environmentally sustainable separation process for rare earth elements (REE), especially for adjacent lanthanoids, remains a challenge due to the chemical similarity of REEs. Tetravalent actinoids, thorium, and traces of uranium are also present in concentrates of REEs, making their separation relevant. This study reports six simple water-soluble aminobis(phosphonate) ligands, RN[CH2P(O)(OH)2]2 (1 R = CH2CH3, 2 R = (CH2)2CH3, 3 R = (CH2)3CH3, 4 R = (CH2)4CH3, 5 R = (CH2)5CH3, 6 R = CH2CH(C2H5)(CH2)3CH3) as precipitating agents for REEs, Th, and U, as well as gives insight into the coordination modes of the utilized ligands with REEs at the molecular level. Aminobis(phospho…

Paramagnetic aluminium β-diketiminate

The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.

The Nature of Transannular Interactions in E4N4 and E82+ (E = S, Se)

The electronic structures of tetrachalcogen tetranitrides, E4N4, and octachalcogen dications, E8(2+), and the nature of their intramolecular E···E interactions (E = S, Se) was studied with high-level theoretical methods. The results reveal that the singlet ground states of both systems have a surprisingly large correlation contribution which functions to weaken and therefore lengthen the cross-ring E-E bond. The observed correlation effects are primarily static in E4N4, whereas in E8(2+) the dynamic part largely governs the total correlation contribution. The presented description of bonding is the first that gives an all-inclusive picture of the origin of cross-ring interactions in E4N4 an…

Alkyl-Substituted Aminobis(phosphonates)Efficient Precipitating Agents for Rare Earth Elements, Thorium, and Uranium in Aqueous Solutions

The efficient and environmentally sustainable separation process for rare earth elements (REE), especially for adjacent lanthanoids, remains a challenge due to the chemical similarity of REEs. Tetravalent actinoids, thorium, and traces of uranium are also present in concentrates of REEs, making their separation relevant. This study reports six simple water-soluble aminobis(phosphonate) ligands, RN[CH2P(O)(OH)2]2 (1 R = CH2CH3, 2 R = (CH2)2CH3, 3 R = (CH2)3CH3, 4 R = (CH2)4CH3, 5 R = (CH2)5CH3, 6 R = CH2CH(C2H5)(CH2)3CH3) as precipitating agents for REEs, Th, and U, as well as gives insight into the coordination modes of the utilized ligands with REEs at the molecular level. Aminobis(phospho…

Simultane endo - und exo -Komplexbildung von Pyridin[4]aren-Dimeren mit neutralen und anionischen Gästen

Synthesis, Stability and Relaxivity of TEEPO-Met: An Organic Radical as a Potential Tumour Targeting Contrast Agent for Magnetic Resonance Imaging

Cancer is a widespread and life-threatening disease and its early-stage diagnosis is vital. One of the most effective, non-invasive tools in medical diagnostics is magnetic resonance imaging (MRI) with the aid of contrast agents. Contrast agents that are currently in clinical use contain metals, causing some restrictions in their use. Also, these contrast agents are mainly non-specific without any tissue targeting capabilities. Subsequently, the interest has notably increased in the research of organic, metal-free contrast agents. This study presents a new, stable organic radical, TEEPO-Met, where a radical moiety 2,2,6,6-tetraethylpiperidinoxide (TEEPO) is attached to an amino acid, methio…

Halogen and Hydrogen Bonded Complexes of 5-Iodouracil

Three derivatives of 5-iodouracil were prepared, and their complexation properties, supplemented by 5-iodouracil under the same conditions, were studied with and without halogen bond acceptors in N,N-dimethylformamide, N,N-diethylformamide, N-methylformamide, formamide, dimethylsulfoxide, and water. The intermolecular halogen and hydrogen bonding interactions observed in the solid state were investigated using single crystal X-ray diffraction and quantum chemical calculations, and the acquired data were contrasted with bonding interactions previously reported for 5-iodouracil in the Cambridge Structural Database. It was found that the polarized iodine atom and the amidic NH functionality ac…

Unprecedented intramolecular pancake bonding in a {Dy2} single-molecule magnet

The first example of unique coordination induced intramolecular pancake bonding was achieved through the reduction of two bis(pyrazolyl)-tetrazine ligands, affording [MIII2(μ-(bpytz)2)(THMD)4](M = Dy, Y; bpytz = 3,6-bis(3,5-dimethyl-pyrazolyl)-1,2,4,5-tetrazine; TMHD = 2,2,6,6-tetramethyl-3,5-heptanedionate). To provide a cohesive magneto-structural correlation, the mono bis(pyrazolyl)-tetrazine bridged congener [DyIII2(μ-bpytz)(THMD)6]·4(C6H6) was also isolated. Both metal complexes exhibit single-molecule magnet behaviour under an applied dc field.

Asymmetric Ring Opening in Tetrazine‐based Ligand Affording a Tetranuclear Opto‐Magnetic Ytterbium Complex

We report the formation of a tetranuclear lanthanide cluster, [Yb 4 (bpzch) 2 (fod) 10 ] ( 1 ), which occurs from a serendipitous ring opening of the functionalized tetrazine bridging ligand, bpztz (3,6‐dipyrazin‐2‐yl‐1,2,4,5‐tetrazine) upon reacting with Yb(fod) 3 (fod ‐ = 6,6,7,7,8,8,8‐heptafluoro‐2,2‐dimethyl‐3,5‐octandionate). Compound 1 was structurally elucidated via single‐crystal X‐ray crystallography and subsequently magnetically and spectroscopically characterized to analyse its magnetisation dynamics and its luminescence behaviour. Computational studies validate the observed M J energy levels attained by spectroscopy and provides a clearer picture of the slow relaxation of the ma…

Nature of Bonding in Group 13 Dimetallenes: a Delicate Balance between Singlet Diradical Character and Closed Shell Interactions

The nature of metal-metal bonding in group 13 dimetallenes REER (E = Al, Ga, In, Tl; R = H, Me, (t)Bu, Ph) was investigated by use of quantum chemical methods that include HF, second order Møller-Plesset perturbation theory (MP2), coupled cluster (CCSD(T)), complete active space with (CASPT2) and without (CAS) second order perturbation theory, and two density functionals, namely, B3LYP and M06-2X. The results show that the metal-metal interaction in group 13 dimetallenes stems almost exclusively from static and dynamic electron correlation effects: both dialuminenes and digallenes have an important singlet diradical component in their wave function, whereas the bonding in the heavier diinde…

A Luminescent Thermometer Exhibiting Slow Relaxation of the Magnetization: Toward Self-Monitored Building Blocks for Next-Generation Optomagnetic Devices

The development and integration of Single-Molecule Magnets (SMMs) into molecular electronic devices continue to be an exciting challenge. In such potential devices, heat generation due to the electric current is a critical issue that has to be considered upon device fabrication. To read out accurately the temperature at the submicrometer spatial range, new multifunctional SMMs need to be developed. Herein, we present the first self-calibrated molecular thermometer with SMM properties, which provides an elegant avenue to address these issues. The employment of 2,2′-bipyrimidine and 1,1,1-trifluoroacetylacetonate ligands results in a dinuclear compound, [Dy2(bpm)(tfaa)6], which exhibits slow …

Thermodynamically driven self-assembly of pyridinearene to hexameric capsules

Pyridinearene macrocycles have previously shown unique host–guest properties in their capsular dimers including endo complexation of neutral molecules and exo complexation of anions. Here, we demonstrate for the first time the formation of hydrogen bonded hexamer of tetraisobutyl-octahydroxypyridinearene in all three states of matter – gas phase, solution and solid-state. Cationic tris(bipyridine)ruthenium(II) template was found to stabilize the hexamer in gas phase, whereas solvent molecules do this in condensed phases. In solution, the capsular hexamer was found to be the thermodynamically favoured self-assembly product and transition from dimer to hexamer occurred in course of time. The …

Probing optical and magnetic properties via subtle stereoelectronic effects in mononuclear DyIII-complexes

Tapping into the secondary coordination environment of mononuclear DyIII-complexes leads to drastic changes in luminescence and magnetism. Visualization of effects induced by stereoelectronics on the opto-magnetic properties was achieved through subtle modifications in the ligand framework.

Weak interactions between trivalent pnictogen centers: computational analysis of bonding in dimers X3E...EX3 (E = pnictogen, X = halogen).

The nature of weak interactions in dimers X(3)E...EX(3) (E = N-Bi, X = F-I) was investigated by wave function and density functional theory (DFT)-based methods. Out of the 20 systems studied, 10 are found to be bound at the CP-MP2 and LMP2 levels of theory. Detailed partition of the interaction energy into different components revealed that dispersion is the primary force holding the dimers together but there also exists an important ionic component whose contribution increases with increasing halogen size. As expected, standard density functionals fail to describe bonding in the studied systems. However, the performance of DFT methods can be easily improved via empirical dispersion correct…

Open-shell doublet character in a hexaazatrinaphthylene trianion complex

Three-electron reduction of hexaazatrinaphthylene (HAN) with a magnesium(I) reagent leads to [(HAN){Mg(nacnac)}3] (1), containing a [HAN]3– ligand with a spin of S = ½. Ab initio calculations reveal that the [HAN]3– ligand in 1 has a groundstate wave function with multiconfigurational properties, and can be described as a triradicaloid species with a small amount of open-shell doublet character. peerReviewed

Halogen-Bonded Mono-, Di-, and Tritopic N-Alkyl-3-iodopyridinium Salts

Halogen bonding interactions of 15 crystalline 3-iodopyridinium systems were investigated. These systems were derived from four N-alkylated 3-iodopyridinium salts prepared in this study. The experimental results in the solid state show that halogen bonding acts as a secondary intermolecular force in these charged systems but sustains the high directionality of interaction in the presence of other intermolecular forces. Halogen bonds donated by polytopic 3-iodopyridinium cations are also sufficient to enclose guest molecules inside the formed supramolecular cavities. The experimental data were supplemented by computational gas-phase and solid-state studies for selected halogen-bonded systems…

Group 13 complexes of dipyridylmethane, a forgotten ligand in coordination chemistry.

The reactions of dipyridylmethane (dpma) with group 13 trichlorides were investigated in 1 : 1 and 1 : 2 molar ratios using NMR spectroscopy and X-ray crystallography. With 1 : 1 stoichiometry and Et2O as solvent, reactions employing AlCl3 or GaCl3 gave mixtures of products with the salt [(dpma)2MCl2](+)[MCl4](-) (M = Al, Ga) as the main species. The corresponding reactions in 1 : 2 molar ratio gave similar mixtures but with [(dpma)MCl2](+)[MCl4](-) as the primary product. Pure salts [(dpma)AlCl2](+)[Cl](-) and [(dpma)AlCl2](+)[AlCl4](-) could be obtained by performing the reactions in CH3CN. In the case of InCl3, a neutral monoadduct (dpma)InCl3 formed regardless of the stoichiometry emplo…

Reaction Mechanism of an Intramolecular Oxime Transfer Reaction: A Computational Study

Density functional theory (PBE0/def2-TZVPP) calculations in conjunction with a polarizable continuum model were used to assess the mechanism of the intramolecular oxime transfer reaction that leads to the formation of isoxazolines. Different diastereomers of the intermediates as well as different oximes (formaldehyde and acetone oxime) were considered. The computed reaction profile predicts the water-addition and -expulsion steps as the highest barriers along the pathway, a conclusion that is in line with the experimental evidence obtained previously for these reactions.

Counterintuitive Mechanisms of the Addition of Hydrogen and Simple Olefins to Heavy Group 13 Alkene Analogues

The mechanism of the reaction of olefins and hydrogen with dimetallenes ArMMAr (Ar = aromatic group; M = Al or Ga) was studied by density functional theory calculations and experimental methods. The digallenes, for which the most experimental data are available, are extensively dissociated to gallanediyl monomers, :GaAr, in hydrocarbon solution, but the calculations and experimental data showed also that they react with simple olefins, such as ethylene, as intact ArGaGaAr dimers via stepwise [2 + 2 + 2] cycloadditions due to their considerably lower activation barriers vis-à-vis the gallanediyl monomers, :GaAr. This pathway was preferred over the [2 + 2] cycloaddition of olefin to monomeric…

Triplet‐State Position and Crystal‐Field Tuning in Opto‐Magnetic Lanthanide Complexes: Two Sides of the Same Coin

Lanthanide-complex-based luminescence thermometry and single-molecule magnetism are two effervescent fields of research, owing to the great promise they hold from an application standpoint. The high thermal sensitivity achievable, their contactless nature, along with sub-micrometric spatial resolution make these luminescent thermometers appealing for accurate temperature probing in miniaturised electronics. To that end, single-molecule magnets (SMMs) are expected to revolutionise the field of spintronics, thanks to the improvements made in terms of their working temperature-now surpassing that of liquid nitrogen-and manipulation of their spin state. Hence, the combination of such opto-magne…

Asymmetric Ring Opening in a Tetrazine-Based Ligand Affords a Tetranuclear Opto-Magnetic Ytterbium Complex.

We report the formation of a tetranuclear lanthanide cluster, [Yb4 (bpzch)2 (fod)10 ] (1), which occurs from a serendipitous ring opening of the functionalised tetrazine bridging ligand, bpztz (3,6-dipyrazin-2-yl-1,2,4,5-tetrazine) upon reacting with Yb(fod)3 (fod- =6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octandionate). Compound 1 was structurally elucidated via single-crystal X-ray crystallography and subsequently magnetically and spectroscopically characterised to analyse its magnetisation dynamics and its luminescence behaviour. Computational studies validate the observed MJ energy levels attained by spectroscopy and provides a clearer picture of the slow relaxation of the magnetisati…

Role of Weak Hydrogen Bonds and Halogen Bonds in 5-Halo-1,3-dimethyluracils and Their Cocrystals—A Combined Experimental and Computational Study

Seven single crystals containing either N,N-dimethyluracil (DMHU) or one of its 5-halogenated derivatives (DMXU; X = F, Cl, Br, I) were prepared using N,N-dimethylformamide as the crystallization solvent. Single crystal X-ray diffraction and quantum chemical calculations carried out at the spin component scaled local MP2 level of theory were then used to study the intramolecular halogen and nonconventional hydrogen bonds present in the structures. The results were compared to and contrasted with the previously reported data for uracil and its halogenated derivatives. In particular, the intermolecular interactions in DMIU were compared to the halogen and hydrogen bonds in 5-iodouracil that, …

Simultaneous endo and exo  Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests

The formation of complexes between hexafluorophosphate (PF6- ) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (1 H, 19 F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6- anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.

Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes.

The synthesis and structural characterization of two benzoquinone-bridged dinuclear rare-earth complexes [BQ(MCl2·THF3)2] (BQ = 2,5-bisoxide-1,4-benzoquinone; M = Y (1), Dy (2)) are described. Of these reported metal complexes, the dysprosium analogue 2 is the first discrete bridged dinuclear lanthanide complex in which both metal centres reside in pentagonal bipyramidal environments. Interestingly, both complexes undergo significant thermal expansion upon heating from 120 K to 293 K as illustrated by single-crystal X-ray and powder diffraction experiments. AC magnetic susceptibility measurements reveal that 2 does not show the slow relation of magnetization in zero dc field. The absent of …

CCDC 1414953: Experimental Crystal Structure Determination

Related Article: Petra Vasko, Virva Kinnunen, Jani O. Moilanen, Tracey L. Roemmele, René T. Boeré, Jari Konu, Heikki M. Tuononen|2015|Dalton Trans.|44|18247|doi:10.1039/C5DT02830B

CCDC 1543476: Experimental Crystal Structure Determination

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CCDC 1414956: Experimental Crystal Structure Determination

Related Article: Petra Vasko, Virva Kinnunen, Jani O. Moilanen, Tracey L. Roemmele, René T. Boeré, Jari Konu, Heikki M. Tuononen|2015|Dalton Trans.|44|18247|doi:10.1039/C5DT02830B

CCDC 2081829: Experimental Crystal Structure Determination

Related Article: Alexandros A. Kitos, Diogo A. Gálico, Niki Mavragani, Raúl Castañeda, Jani O. Moilanen, Jaclyn L. Brusso, Muralee Murugesu|2021|Chem.Commun.|57|7818|doi:10.1039/D1CC02407H

CCDC 1426934: Experimental Crystal Structure Determination

Related Article: Gustavo Portalone, Jani O. Moilanen, Heikki M. Tuononen, Kari Rissanen|2016|Cryst.Growth Des.|16|2631|doi:10.1021/acs.cgd.5b01727

CCDC 1858840: Experimental Crystal Structure Determination

Related Article: Maykon A. Lemes, Niki Mavragani, Paul Richardson, Yixin Zhang, Bulat Gabidullin, Jaclyn L. Brusso, Jani O. Moilanen, Muralee Murugesu|2020|Inorg.Chem.Front.|7|2592|doi:10.1039/D0QI00365D

CCDC 2171093: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2171080: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 1426935: Experimental Crystal Structure Determination

Related Article: Gustavo Portalone, Jani O. Moilanen, Heikki M. Tuononen, Kari Rissanen|2016|Cryst.Growth Des.|16|2631|doi:10.1021/acs.cgd.5b01727

CCDC 1976893: Experimental Crystal Structure Determination

Related Article: Maykon A. Lemes, Niki Mavragani, Paul Richardson, Yixin Zhang, Bulat Gabidullin, Jaclyn L. Brusso, Jani O. Moilanen, Muralee Murugesu|2020|Inorg.Chem.Front.|7|2592|doi:10.1039/D0QI00365D

CCDC 2171079: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 1426933: Experimental Crystal Structure Determination

Related Article: Gustavo Portalone, Jani O. Moilanen, Heikki M. Tuononen, Kari Rissanen|2016|Cryst.Growth Des.|16|2631|doi:10.1021/acs.cgd.5b01727

CCDC 2171088: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2171091: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2171089: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 1414952: Experimental Crystal Structure Determination

Related Article: Petra Vasko, Virva Kinnunen, Jani O. Moilanen, Tracey L. Roemmele, René T. Boeré, Jari Konu, Heikki M. Tuononen|2015|Dalton Trans.|44|18247|doi:10.1039/C5DT02830B

CCDC 2171092: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2171084: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 1047819: Experimental Crystal Structure Determination

Related Article: Jani O. Moilanen, Benjamin M. Day, Thomas Pugh, Richard A. Layfield|2015|Chem.Commun.|51|11478|doi:10.1039/C5CC04004C

CCDC 2171081: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2171090: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2171087: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 1414955: Experimental Crystal Structure Determination

Related Article: Petra Vasko, Virva Kinnunen, Jani O. Moilanen, Tracey L. Roemmele, René T. Boeré, Jari Konu, Heikki M. Tuononen|2015|Dalton Trans.|44|18247|doi:10.1039/C5DT02830B

CCDC 1426930: Experimental Crystal Structure Determination

Related Article: Gustavo Portalone, Jani O. Moilanen, Heikki M. Tuononen, Kari Rissanen|2016|Cryst.Growth Des.|16|2631|doi:10.1021/acs.cgd.5b01727

CCDC 2171086: Experimental Crystal Structure Determination

Related Article: J. Mikko Rautiainen, Maryna Green, Minna Mähönen, Jani O. Moilanen, Manu Lahtinen, Arto Valkonen|2023|Cryst.Growth Des.|23|2361|doi:10.1021/acs.cgd.2c01351

CCDC 2026744: Experimental Crystal Structure Determination

Related Article: Paul Richardson, Riccardo Marin, Yixin Zhang, Bulat Gabidullin, Jeffrey Ovens, Jani O. Moilanen, Muralee Murugesu|2020|Chem.-Eur.J.|27|2361|doi:10.1002/chem.202003556

CCDC 1426936: Experimental Crystal Structure Determination

Related Article: Gustavo Portalone, Jani O. Moilanen, Heikki M. Tuononen, Kari Rissanen|2016|Cryst.Growth Des.|16|2631|doi:10.1021/acs.cgd.5b01727

CCDC 1557625: Experimental Crystal Structure Determination

Related Article: Jani O. Moilanen, Akseli Mansikkamäki, Manu Lahtinen, Fu-Sheng Guo, Elina Kalenius, Richard A. Layfield, Liviu F. Chibotaru|2017|Dalton Trans.|46|13582|doi:10.1039/C7DT02565C

CCDC 1899745: Experimental Crystal Structure Determination

Related Article: Anniina Kiesilä, Ngong Kodiah Beyeh, Jani O. Moilanen, Rakesh Puttreddy, Sven Götz, Kari Rissanen, Perdita Barran, Arne Lützen, Elina Kalenius|2019|Org.Biomol.Chem.|17|6980|doi:10.1039/C9OB01383K

CCDC 1557624: Experimental Crystal Structure Determination

Related Article: Jani O. Moilanen, Akseli Mansikkamäki, Manu Lahtinen, Fu-Sheng Guo, Elina Kalenius, Richard A. Layfield, Liviu F. Chibotaru|2017|Dalton Trans.|46|13582|doi:10.1039/C7DT02565C

CCDC 1414954: Experimental Crystal Structure Determination

Related Article: Petra Vasko, Virva Kinnunen, Jani O. Moilanen, Tracey L. Roemmele, René T. Boeré, Jari Konu, Heikki M. Tuononen|2015|Dalton Trans.|44|18247|doi:10.1039/C5DT02830B

CCDC 1858838: Experimental Crystal Structure Determination

Related Article: Maykon A. Lemes, Niki Mavragani, Paul Richardson, Yixin Zhang, Bulat Gabidullin, Jaclyn L. Brusso, Jani O. Moilanen, Muralee Murugesu|2020|Inorg.Chem.Front.|7|2592|doi:10.1039/D0QI00365D

CCDC 1859276: Experimental Crystal Structure Determination

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