0000000001299872

AUTHOR

A. Hasu

showing 5 related works from this author

Modification of the supramolecular structure of [(thione)IY] (Y = Cl, Br) systems by cooperation of strong halogen bonds and hydrogen bonds

2015

Four interhalogen complexes of heterocyclic thione ligands N-methylbenzothiazole-2-thione (mbtt) and 2(3)H-benzothiazole-thione (btt) with strong and tunable S⋯I halogen bonds were synthesized and characterized by X-ray single crystal diffraction. The study of the strength and nature of the interactions was supported by computational analysis using the Quantum Theory of Atoms in Molecules (QTAIM). Halogen bond and hydrogen bond directed self-assemblies of thione compounds were efficiently modified by the changes in the halogen bond donor and acceptor structures. In structures [(mbtt)ICl] (1) and [(mbtt)IBr] (2) the interplay of halogen bonds and hydrogen bonds between the thione hydrogens a…

Halogen bondsynthesisHydrogenHydrogen bondhalogen bondsInorganic chemistryAtoms in moleculesSupramolecular chemistrychemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsAcceptorinterhalogen complexesCrystallographychemistryhydrogen bondsHalogenGeneral Materials Scienceta116InterhalogenCrystEngComm
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CCDC 1034603: Experimental Crystal Structure Determination

2015

Related Article: L. Koskinen, P. Hirva, A. Hasu, S. Jääskeläinen, J. Koivistoinen, M. Pettersson, M. Haukka|2015|CrystEngComm|17|2718|doi:10.1039/C4CE02449D

Space GroupCrystallographyCrystal SystemCrystal Structure[(Benzothiazole-2(3H)-thione)iodobromide]Cell ParametersExperimental 3D Coordinates
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CCDC 1034601: Experimental Crystal Structure Determination

2015

Related Article: L. Koskinen, P. Hirva, A. Hasu, S. Jääskeläinen, J. Koivistoinen, M. Pettersson, M. Haukka|2015|CrystEngComm|17|2718|doi:10.1039/C4CE02449D

[(N-Methylbenzothiazole-2-thione)iodobromide]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1034600: Experimental Crystal Structure Determination

2015

Related Article: L. Koskinen, P. Hirva, A. Hasu, S. Jääskeläinen, J. Koivistoinen, M. Pettersson, M. Haukka|2015|CrystEngComm|17|2718|doi:10.1039/C4CE02449D

Space GroupCrystallographyCrystal System[(N-methylbenzothiazole-2-thione)ICl]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1034602: Experimental Crystal Structure Determination

2015

Related Article: L. Koskinen, P. Hirva, A. Hasu, S. Jääskeläinen, J. Koivistoinen, M. Pettersson, M. Haukka|2015|CrystEngComm|17|2718|doi:10.1039/C4CE02449D

Space GroupCrystallographyCrystal SystemCrystal Structure[(Benzothiazole-2(3H)-thione)iodochloride]Cell ParametersExperimental 3D Coordinates
researchProduct