Author: Lorena M. Callejo

0000000001299976

AUTHOR

Lorena M. Callejo

Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal-Organic Frameworks

[Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional nanochannels (diagonal approximate to 2.2nm) in which inclusion molecules are located. The guest-loaded framework 1@guest displays complete thermal spin-crossover (SCO) behavior with the characteristic temperature T-1/2 dependent on the guest molecule, whereas the guest-free species 1 is paramagnetic whatever the temperature. For the benzene-guest derivatives, the characteristic SCO temperature T-1/2 decreases as the Hammet sigma(p) parameter increases. In general, …

research product

CCDC 1042612: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042617: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042613: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042615: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042614: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042616: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042611: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

research product

CCDC 1042610: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

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